3- A vessel contains at 1 bar and 20C a mixture of 1 mole of CO 2 and 4 moles of air.
Calculate for the mixture : (i) The masses of CO2, O2 and N2, and the total mass ; (ii) The percentage carbon content by mass ; (iii) The apparent molecular weight and the gas constant for the mixture ; (iv) The specific volume of the mixture. The volumetric analysis of air can be taken as 21% oxygen and 79% nitrogen. Solution. The pressure in the vessel, p = 1 bar Temperature in the vessel, T = 20 + 273 = 293 K No. of moles ofCO2 = 1 mole No. of moles of air= 4 mole From equation, ( ) we have nO2 = 0.21 4 = 0.84 nN2 = 0.79 4 = 3.16 (i) From equation,mi = niMi, we have mCO2 = 1 44 = 44 kg. (Ans.) mO2 = 0.84 32 = 26.88 kg. (Ans.) and mN2 = 3.16 28 = 88.48 kg. (Ans.) The total mass, m = mCO2 + mO2 + mN2 = 44 + 26.88 + 88.48 = 159.36 kg. (Ans.) (ii) Since the molecular weight of carbon is 12, therefore, there are 12 kg of carbon present for every mole of CO2, i.e., Percentage carbon in mixture == 7.53% by mass. (Ans.) (iii) From equation n = ni, we have n = nCO2 + nO2 + nN2 = 1 + 0.84 + 3.16 = 5.0 Now using the equation M = , we have 086 8 = 8.8 + 5.376 + 17.696 = 31.872 i.e., Apparent molecular weight = 31.872. (Ans.) From equation, R = , we have R= 0.2608 kJ/kg K i.e., Gas constant for the mixture = 0.2608 kJ/kg K. (Ans.) (iv) To find specific volume of the mixture, v using the relation : pv = RT 0 0 = 0.7641 m3/kg i.e., Specific volume of the mixture = 0.7641 m3/kg. (Ans.)