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Solvent Properties and Data Table

This document provides a table of solvent properties including refractive index, UV cutoff, viscosity, Hildebrand solubility parameter, elution strength on silica and alumina, and polarity index for various solvents. It also lists the webmaster's email for updates to the solvent property tables. The tables were last updated on 20-Feb-03.

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0% found this document useful (0 votes)
88 views7 pages

Solvent Properties and Data Table

This document provides a table of solvent properties including refractive index, UV cutoff, viscosity, Hildebrand solubility parameter, elution strength on silica and alumina, and polarity index for various solvents. It also lists the webmaster's email for updates to the solvent property tables. The tables were last updated on 20-Feb-03.

Uploaded by

829255
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLS, PDF, TXT or read online on Scribd

Most up-to-date table is available from:

internet
www.sanderkok.com
e-mail
[email protected]
last update

20-Feb-03

www.sanderkok.com

solvent
acetaldehyde diethyl acetal
acetic acid
acetic anhydride
acetone
acetonitrile
benzene
benzonitrile
benzyl alcohol
benzyl ether
butanol, 1butanol, 2butanone, 2butyl acetate
butyl acetate, secbutyl ether
butyl ethyl ether
butyl formate
butylamine, 2butyraldehyde
butyric acid
butyronitrile
carbon tetrachloride
chlorobutane, 2chloroform
chloropropane, 1chloropropane, 2cyclohexane
cyclohexanone
dichloroethane
dichloromethane
diethyl carbonate
di-isopropylamine
dimethyl formamide, N,Ndimethyl sulfoxide
dimethylbutane, 2,2dimethylbutane, 2,3dimethylpentane, 2,3dimethylpentane, 2,4dioxane, 1,4dioxane, p
dodecafluoro-1-hepatanol
ethanol
ethyl acetate
ethyl ether
ethyl formate
ethyl propionate
ethylene dichloride
formamide
heptane
hexanone, 2i-butyl acetate
i-butyl alcohol
i-butyl formate
i-butylamine
i-octane
i-propyl acetate
i-propyl ether
methanol
methoxyethanol, 2methyl acetate
methyl ethyl ketone (MEK)

info: [email protected]

ri
1.379
1.372
1.389
1.359
1.344
1.501

UV
cutoff

Viscosity
(cP) at
20C

210

1.1-1.26

330
190
280

0.32
0.37
0.65
1.22
5.8
5.33

Hildebrand
solubility
parameter

E
SiO2

12.4
9.6 0.47-0.53
11.7
0.5
9.2
0.25

E
Al2O3

polarity
index
(Snyder)

large

6.2

0.56-0.58
0.55-0.65
0.32

5.4
6.2
3
4.6
5.5
3.3
3.9

1.395
1.377
1.392
1.387
0.7
1.380
1.387
1.390
1.378
1.396
1.382
1.466
1.395
1.443
1.386
1.376
1.427

1.424
1.385
1.390
1.431
1.478
1.369
1.372
1.389
1.379

1.7

265

0.97

8.6

0.12

0.18

1.7

245

0.57

9.2

0.26

0.36-0.4

3.4-4.4

200

0.98
2.24

8.2

0.04

0.04

232

0.44

9.6

0.32

0.4

0
4.5
3.7
3.4

268

0.90-0.92
2.24

11.5
12.8

0.41

0.62

6.4
6.5

4.8
4.8

1.54
1.316
1.361 205-210
1.370
256
1.352
1.358
1.382
1.445
230
1.450
210
1.385
1.395
1.388

1.2
0.46-0.47

0.79
3.3-3.76

12
0.68
9.1 0.38-0.48

0.88
0.58

5.2
4.3

9.7

0.49

3.7
7.3

0.38

3
1.383
1.395
1.404 197-210
1.375
1.368
220
1.329
205
1.401
220
1.362
260
1.379
330

3.9

0.5

0.01

0.01

0.4

0.33-0.37
0.6
1.72
0.37-0.45
0.43

7.3
13.7

0.22
0.73

9.2
9.3

0.46
0.39

0.28
0.95
0.74
0.6
0.51

2.2
6.6
5.7
4.4
4.5

www.sanderkok.com

solvent
methyl n-butyrate
methyl-1-propanol, 2methyl-2-butanone, 3methyl-2-pentanone, 4methyl-2-propanol, 2methylene chloride
methylhexane, 2methylhexane, 3methylpentane, 2methylpentane, 3n-decane
n-hexane
nitrobenzene
nitroethane
nitromethane
nitropropane, 2octafluoro-1-pentanol
octane
pentanone, 2pentanone, 3propanol, 1propanol, 2propionaldehyde
propionic acid
propionitrile
propyl ether
propyl formate
propylamine
propyl acetate
pyridine
t-butanol
t-butyl methyl ether
tetrahydrofuran
toluene
triethyl amine
trifluoroacetic acid
trifluoroethanol
trifluoropropanol
trimethylbutane, 2,2,3trimethylhexane, 2,2,5trimethylpentane, 2,2,4valeronitrile
water
xylene, pheptane

info: [email protected]

ri
1.391
1.394
1.386
1.394
1.383
1.424
1.382
1.386
1.369
1.374
1.412
1.375
1.392
1.380
1.392
1.316
1.395
1.390
1.390

UV
cutoff

Hildebrand
solubility
parameter

E
SiO2

E
Al2O3

polarity
index
(Snyder)

233

0.44

9.7

0.32

0.42

3.4

210
195

0.92
0.313
2.03
0.68

7.8
7.3

0.03

0.04
0.01

0.3
0
4.5
5.3

380

0.5

1.380
210+
1.371
1.386
1.366
1.379
1.375
1.386
1.382
1.510 305-330
1.385
1.370
210
1.408 212-230
1.496
285
1.401
1.283
1.290
1.381
1.387
1.397
1.389
1.395
1.333
180
1.385

Viscosity
(cP) at
20C

210

0.4

2.3
2.35

0.94

10.7

0.27
0.55
0.59
0.38

9.1
8.9

1
0.7

21

0.35
0.35
0.23

0.82

4.3
4.3

0.71

5.3

0.45
0.29

2.9
4.2
2.3
1.8

large

9
2.4

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BP
(C)
117.9
56.3
81.6
80.1
191.1
205.5
288.3
117.2

142.2

76.5
61.2

80.7
155.7
83.4
40

153
189

101
101.3
78.3
77.1

83.5
210.5

117.7

99.2
68.3
64.7
124.6
56.3
80

info: [email protected]

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BP
(C)

39.8

174.1
68.9
210.8
114

99.2

97.2
82.4-117.7

115.3
55.2
66
101.6
89.5

100
138
59

info: [email protected]

www.sanderkok.com

% MeOH in % MeCN in
H2O
H2O
0
0
10
6
20
14
30
22
40
32
50
40
60
50
70
60
80
73
90
86
100
100

info: [email protected]

% THF in
H2O
0
4
10
17
23
30
37
45
53
63
72

relative k'
100
40
16
6
2.5
1
0.4
0.2
0.06
0.03
0.01

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Solvent
Pentane
Hexane
Iso-octane
Cyclohexane
Carbon tetrachloride
l-Chlorobutane
Xylene
Toluene
Chlorobenzene
Benzene
Ethyl ether
Dichloromethane
Chloroform
1,2-Dichloroethane
Methyl ethyl ketone
Acetone
Dioxane
1-Pentanol
Tetrahydrofuran
Methyl t-butyl ether
Ethyl acetate
Dimethyl sulfoxide
Diethylamine
Acetonitrile
1-Butanol
Pyridine
2-Methoxyethanol
n-Propyl alcohol
Isopropyl alcohol
Ethanol
Methanol
Ethylene glycol
Dimethyl formamide
Water

info: [email protected]
E
Al2O3
0.00
0.00-0.01
0.01
0.04
0.17-0.18
0.26-0.30
0.26
0.20-0.30
0.30-0.31
0.32
0.38
0.36-0.42
0.36-0.40
0.44-0.49
0.51
0.56-0.58
0.56-0.61
0.61
0.45-0.62
0.3-0.62
0.58-0.62
0.62-0.75
0.63
0.52-0.65
0.7
0.71
0.74
0.78-0.82
0.78-0.82
0.88
0.95
1.11
-

E
SiOH
0.00
0.00-0.01
0.01
0.03
0.11
0.2
0.22
0.23
0.25
0.38-0.43
0.32-0.32
0.26
0.47-0.53
0.49-0.51
0.53
0.48
0.38-0.48
0.50-0.52
0.6
0.70-0.73
-

E
C18
8.8
11.7
3.7
3.1
10.1
8.3
3.1
1.0
7.6
-

P
0
0.1
0.1
0.2
1.6
1
2.5
2.4
2.7
_
2.8
3.1
4.1
3.5
5.7
5.1
4.8
4
2.5
4.4
7.2
5.8
3.9
5.3
5.5
4
3.9
5.1
6.4
10.2

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