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Entropy in Isobaric Processes

1) The document analyzes a thermodynamic process involving four states. It calculates various thermodynamic properties at each state including pressure, volume, temperature and thermodynamic changes between states. 2) The document determines the polytropic index for each process and uses this to calculate specific heats and thermodynamic changes. It also calculates work, heat transfer and exergy for each process. 3) Key results are summarized in a table listing pressure, volume, temperature and other properties at each of the four states. Thermodynamic calculations are shown for each process involving changes in internal energy, entropy, enthalpy, heat, work and exergy.

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0% found this document useful (0 votes)
151 views12 pages

Entropy in Isobaric Processes

1) The document analyzes a thermodynamic process involving four states. It calculates various thermodynamic properties at each state including pressure, volume, temperature and thermodynamic changes between states. 2) The document determines the polytropic index for each process and uses this to calculate specific heats and thermodynamic changes. It also calculates work, heat transfer and exergy for each process. 3) Key results are summarized in a table listing pressure, volume, temperature and other properties at each of the four states. Thermodynamic calculations are shown for each process involving changes in internal energy, entropy, enthalpy, heat, work and exergy.

Uploaded by

Ferit
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOC, PDF, TXT or read online on Scribd

2

II.
Percaktimi i parametrave, kur dihet:

cp= 0.907 (kj/kgK)


cv= 0.672 (kj/kgK)
R = 235 (kj/kgK)

cp
 1.3 5
cv
cp – cv = R

 Per piken 1.

p1 = 0.9 (bar)= 0.9 * 105


R  T1 235  303
v1= ? p1v1  RT1  v1    0.72 (m3/kg)
p1 0.9  10 5
T1= 303 (K)

 Per piken 2.

p2 = 40 (bar)
v2 = ? - procesi (1 – 2) politropik, si i tille na jep:
T2 = ?
n = 1.3
1 1
 p n  0.9  10 5  1..3
 0.043 m 
3
p v  p 2 v  v 2  v1  1   0.972  
n n

1 1 2
 kg 
 40  10
5
 p2  

p 2 v 2 40  10 5  0.043
p 2 v 2  RT2  T2    732( K )
R 235

 Per piken 3.

p3 = 40 (bar)
R  T3 235  873
v3 = ? p 3 v3  RT3  v3    0.0.51 (m3/kg)
p3 40  10 5
t3 = 600 o C  T3=873 (K)

3
 Per piken 4.

p4 = ? - Procesi (4-1) izohorik, si i tille na jep:


v4 = ?
T4 = ? v4= v1 = 0.792 (m3?kg)
n = 1.2

procesi (3 – 4) politropik, si i tille na jep:

1. 2
 v n  0.051 
p3 v  p 4 v  p 4  p3  3   40  10 5
n
3
n
4    148824.  3467( pa )
 p4   0.792 

p 4 v 4 148824.3467  0.792
p 4 v 4  RT4  T4    502( K )
R 235

Tabela nr. 1.

Gjendia p (kpa) v (m3/kg) T (K)


1 90 0.792 303
2 4000 0.043 732
3 4000 0.051 873
4 148.8243467 0.792 502

4
- Eksergjia e rrymes per piken 1.
p
p1 1
P1 = 0.9 (bar) δq = 0

T1 = 303 (K)
ΔT = 0
Po = 1 (bar)
Px x
To = 273 (K) po o
v
e x1 = ? v1 vx vo

e x1 = lmax = l(1-x) + l(x-o)

(1-x) – process adiabatic

q = l(1-x) + Δh l(1-x) =-Δh = cp( T1 – Tx)

0
(x – 1) – process izotermik

q = l(x-o)+ Δh l(x-o) = Tx Δs Tx = To
0

p 0 .9 kj 
Δs = R ln p  0.235 ln 0.6  0.120 kgK 
1

x
k 1.35
T1k Txk  T  k 1  273  1..351
k 1
 k 1
 p x  p1  o   0.9  10 5    0.6  10 5  pa 
p1 px T
 1  303 

e x1= 0.907 (303 – 273) + 273*0.120 = 5.55 (kj/kg)

5
III.
 Procesi (1-2) politropik.

 Treguesi i politropes.

cn  c p
 n=? n
c n  cv
 n  1.3

 Nxetesia specifike.

nk 1.3  1.35


cn= ? c n  cv  0.672  0.112 ( kj / kgK )
n 1 1 .3  1

 ≠ i energjise se brendeshme.

Δu = ? Δu = cv (T2 – T1) = 0.672 (732 – 303 ) = 288.288 (kj/kg)

 ≠ i entropies.

T 732
Δs = c n ln T  0.112  ln 303  0.099(kj / kg )
2
Δs = ?
1

 ≠ i entalpise.

Δh = ? Δh = cp ( T2 – T1) = 0.907 (732 – 303 ) = 389.103 (kj/kg)]

 Sasia e nxetesis.

q=? q = cn(T2 – T3) = -0.112 (732 – 303) = -49.048 (kj/kg)

 Puna e kryer.

1 1
l ? l R (T2  T1 )  0.235(303  732)  335.65(kj / kg )
n 1 1.3  1

 Puna teknike.

lt  ? l t  n  l  1.3  ( 332.65)  436.865(kj / kg )

6
 Eksergjia e nxetsis.

exq = ? exq = q – To Δs = 48.048 – 273*0.099 = 17.472 (kj/kgK)


T
2
T2
1
T1

eksergjia

To
anergjia

S
s2 s1

 Procesi (2 – 3) izobarik.

 Treguesi i politropes.

cn  c p
 n=? n
c n  cv
n0

 Nxetesia specifike.

nk
cn= ? c n  cv  c p  0.907(kj / kgK )
n 1
 ≠ i energjise se brendeshme.

Δu = ? Δu = cv (T3 – T2) = 0.672 (873 - 732) = 94.752 (kj/kg)

 ≠ i entropies.

T 873
Δs = c p ln T  0.907  ln 732  0.160(kj / kgK )
3
Δs = ?
2

 ≠ i entalpise.

Δh = ? Δh = cp ( T3 – T2) = 0.907 (873 - 732) = 128.047 (kj/kg)

 Sasia e nxetesis.

q=? q = cp(T3 – T2) = 0.747(509 – 373) = 101592 (kj/kg)

 Puna e kryer.
3

l ? l   pdv  p(v3  v 2 )  4000(0.051  0.043)  32(kj / kg )


2

 Puna teknike.

lt  ? l t    vdp  0

 Eksergjia e nxetsis.

exq = ? exq = q – To Δs = 128.047 – 273*0.160 = 84.367 (kj/kgK)

T3
3
2
T2
eksergjia

To
anergjia

S
s2 s3

 Procesi (3 – 4) politropik.

 Treguesi i politropes.

cn  c p
n=? n  n  1.2
cn  cv
 Nxetesia specifike.

nk 1.2  1.35


cn= ? c n  cv  0.672  0.504( kj / kgK )
n 1 1.2  1

 ≠ i energjise se brendeshme.

Δu = ? Δu = cv (T4 – T3) = 0.672 (502 – 873 ) = - 249.312 (kj/kg)

 ≠ i entropies.

T 502
Δs = cn ln T  0.504  ln 873  0.279(kj / kgK )
4
Δs = ?
3

 ≠ i entalpise.

Δh = ? Δh = cp ( T4 – T3) = 0.672 (502 – 873 ) = - 335.013 (kj/kg)

 Sasia e nxetesis.

q=? q = cn(T4 – T3) = -0.504 (502 – 873) = 186.984 (kj/kg)

 Puna e kryer.

1 1
l ? l R(T3  T4 )  0.235(873  502)  436.925(kj / kg )
n 1 1.2  1

 Puna teknike.

lt  ? lt  n  l  1.2  432.925  523.43(kj / kg )

 Eksergjia e nxetsis.

exq = ? exq = q – To Δs = 186.984 – 273*0.279 = 110.817 (kj/kg)

T
3
T3
4
T4

eksergjia

To
anergjia

s3 s4 S
 Procesi (4 – 1) izohorik.

 Treguesi i politropes.

cn  c p
n=? n  n  
cn  cv

 Nxetesia specifike.

nk
cn= ? cn  cv  cv  0.672(kj / kgK )
n 1

 ≠ i energjise se brendeshme.

Δu = ? Δu = cv (T1 – T4) = 0.672 (303 – 502 ) = -133.728 (kj/kg)

 ≠ i entropies.

T 303
Δs = c p ln T  0.907  ln 502  0.339(kj / kgK )
1
Δs = ?
4

 ≠ i entalpise.

Δh = ? Δh = cp ( T1 – T4) = 0.907 (303 - 502) = -182.137 (kj/kg)

10

 Sasia e nxetesis.

q=? q = cp(T1 – T4) = 0.672(303 – 503) = -133.728 (kj/kg)

 Puna e kryer.
1

l ? l   pdv  0
4

 Puna teknike.
lt  ? lt    vdp  v( p 4  p1 )  0.792(148.8243467  90)  46.689(kj / kg

 Eksergjia e nxetsis.

exq = ? exq = q – To Δs = 133.728 – 273*0.339 = 41.181 (kj/kg)

T
T4
4
1
T1
eksergjia

To
anergjia

S
s1 s4

Tabela nr. 2

Δu Δs Δh q l lt exq
Procesi n (kj/kg) (kj/kgK) (kj/kg) (kj/kg) (kj/kg) (kj/kg) (kj/kg)
(1-2) 1.3 288.288 -0.099 389.103 -49.048 -335.65 -436.865 17.476
(2-3) 0 94.752 0.160 128.047 128.047 32 0 84.387
(3-4) 1.2 -249.312 0.279 -335.013 186.984 436.925 523.43 110.827
(4-1)  -133.728 -0.339 -182.137 133.728 0 46.689 41.181
cikli - 0 0.001 0.001 132.255 132.275 132.256 -

11

 Rendimenti termik i ciklit.

lc 132.275
 tc    0.423  42.3%
q N 315.031

IV.

 Eksergjia e dhene nga niveli i siperm

e xqN  ? e xqN    q  0  T0   s  0   315.031  273  0.439  195.184(kj / kg )


 Eksergjia e dhene nga niveli poshtem.

e xqF  ? e xqF    q  0   T0   s  0  181  273  0.438  62.202( kj / kg )

 Rendimenti eksergjitik i ciklit.

lc 132.275
 exc    0.683  68.3%
e xqN 195.184

12
V.
 Cikli Karno qe punon ne temp ekstreme dhe ai i barasvlefshem.

T3 2’ 3 3’

T 2 2
1
T bv a b

T4 4
T2bv d c

T1 1’ 1 4’

s2 s3 s1 s4 s

Cikli 1-2-3-4-1 cikli real.

Cikli 1’-2’-3’-4’-1’ cikli Karno qe punon ne temp. ekstreme.

Cikli a-b-c-d-a cikli Karno i barasvlefshem.

 Rendimenti i ciklit karno.

TN  TF 873  303
 tK    0.653  65.3%
TN 873

 Ndertimi i ciklit te barasvlefshem Karno.

Tbv1 
  q  0  2315.031  717.6( K )
  s  0 0.439

Tbv2 
  q  0  181.776  415( K )
  s  0 0.438
 Rendimenti termik i ciklit te barasvlefshem Karno.

Tbv1  Tbv2 717.6  415


 K
tbv    0.422  42.2%
Tbv1 717.6
1
I.
 Paraqitja ne diagramat <p;v>, <T;s>, <h;s>.

<p;v> p p=cost
p2=p3 2 3
pv1.2=cost

p4 4
v=cost
1.3
pv =cost
p1 1
v
v2 v3 v1=v4
T
<T;s>
T3 3
p=cost

T2 2 pv1.3=cost

T4 4

pv1.3=cost v=cost
T1 1

s2 s3 s1 s4 s

<h;s> h
h3 3
p=cost

h2 2 pv1.3=cost

h4 4

pv1.3=cost v=cost
h1 1

s2 s3 s1 s4 s

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