Members: Caluag, Jiana Krizia D.
Section: 5ChE-C
Dela Cruz, Marife S.
Medina, Althea Mae E.
PHYSICAL CHEMISTRY
1. Is an equation that expresses the effect of a pressure change on the
consequent temperature change for an equilibrium system containing two
phases
a. Clausius-Clapeyron Equation
b. Clapayron Equation
c. Nernst Equation
d. Raoults Law
2. Is the minimum number of chemically distinct substances necessary to
specify the composition of each phase and to prepare system
a. Number of components
b. Degree of Freedom
c. Variance
d. Number of phases
3. States that the ratio of the partial pressure of each component in the vapour
above the solution to the vapour pressure of the pure liquid component is
equal to their mole fraction in the liquid phase
a. Henrys Law
b. Van Hoffs equation
c. Raoults Law
d. Daltons Law
4. The vapour pressure of benzene is 100 Torr at 26.1 oC. Calculate the vapour
pressure of a solution containing 24.6g of camphor (C 10H16O) dissolved in
98.5g of benzene.
a. 88.6 Torr
b. 78.6 Torr
c. 80.5 Torr
d. 90.8 Torr
5. For the second-order reaction 2A P, the rate constant is 3.5x10-4 dm3 mol1-
s-1. How long (in seconds) would it take for the concentration of A to change
from 0.260 mol dm-3 to 0.011 mol dm-3?
a. 3.33 x 105
b. 2.75 x 104
c. 1.75 x 105
d. 2.5 x 105
6. The vapour pressure of ethanol of 24.1 Torr at 10 oC and 44.0 Torr at 20 oC.
What is the molar enthalpy of vaporization of ethanol over this temperature
range?
a. 26.2 KJ mol-1
b. 41.5 KJ mol-1
c. 31.5 KJ mol-1
d. 35.4 KJ mol-1
7. At the absolute temperature, the entropy of a perfect crystalline solid tends
to be zero.
a. 1st Law of Thermodynamics
b. 2nd Law of Thermodynamics
c. 3rd Law of Thermodynamics
d. None of the choices
8. The heat of any reaction can be obtained from the sum of the heats of
reaction of the steps leading to the overall reaction.
a. Kirchoffs Law
b. Joules Law
c. Gibbs Law
d. Hess Law
9. The mass percentage composition of dry air at sea level is approximately
N2:75.5; O2:23.2; Ar: 1.3. What is the partial pressure of each component
when the total pressure is 1.00 atm?
a. 0.0269 mol N2, 0.725 mol O2, 0.003 mol Ar
b. 2.69 mol N2, 0.725 mol O2, 0.045 mol Ar
c. 3.8 mol N2, 0.735 mol O2, 0.95 mol Ar
d. 2.69 mol N2, 0.725 mol O2, 0.033 mol Ar
10.In an industrial process, nitrogen is heated to 500 K in a vessel of constant
volume. If it enters the vessel at 100 atm and 300 K, what pressure would it
exert at the working temperature if is behaved as a perfect gas.
a. 167 atm
b. 260 atm
c. 55 atm
d. 230 atm
11.When carbon dioxide is taken into account, the mass percentages are 75.5
N2, 23.15 O2, 1.28 Ar, and 0.046 CO2. What are the partial pressures when the
total pressure is 0.9 atm.
a. 0.8 atm N2, 0.00005 atm O2, 12 atm Ar, and 0.07898 atm CO2
b. 0.703 atm N2, 0.189 atm O2, 0.0084 atm Ar, and 0.00027 atm
CO2
c. 5.8 atm N2 5.8 atm O2, 12 atm Ar, and 0..0097atm CO2
d. 8.9 atm N2, 1 atm O2, 9 atm Ar, and 13 atm CO2
