cG3 Page 1 of 12 ‘Chemwatch Material Safe jeot (REVIEW) Version No: 2.0 (Chomwatch 8187-26 7LP PRODUCT NAME Verex Set Cunng Powder PRODUCT USE ' Used according to manufacturer’ deectons. Used according to manufacturers tections SUPPLIER Company: Vertex-Dental Adress PO Box 19, ela, 3700 AA Netherlands Telephone: +31 30 697 6749, Fax: 31 30695 5188 Ema infogverex-sental com ‘Weeste: wae vetox-denal com ‘STATEMENT OF HAZARDOUS NATURE. (CHEMWATCH HAZARD RATINGS Me Max Flanmabiy = Toxicity om ody Comet = Reactviy: = Crone 2 POISONS SCHEDULE RISK SAFETY + May cause SENSITISATION by Inhalation and skin contact + Cumulative effects may result following exposure’ + May produce discomfort of the respiratory system”. + Limited evidence of a carcinogenic, i Wear suitable gloves. + Do not breathe dust. + Avoid contact with skin + Wear suitable protective clothing + To clean the floor and all objects contaminated by this material, use water and detergent. + Keop away from food, drink and animal feeding stuffs. + If swallowed, IMMEDIATELY contact Doctor of Poisons Information Centre (show this container or label) + In case of accident by inhalation: remove casually to fresh air and keep at rest. + (imited evidence). hitps://[Link]/chemgold3/[Link]? print=¥ &NzGe=&cwno=8187-26&c... 30/01/2012G3 Page 2 of 12 Vertex Self Curing Powder el CChomwatch Material Safety Data Sheet (REVIEW) Version No: 2.0, Chemmwatch 8187-26 Issue Date: 15-Apr-2011 car7P NAME CASRN % methyl mathacrylate homopolymer 9011-147 298 dibenzoy| peroxide 94-36-0 2 colour agents 4 organic pgments ferric oxide 1309-37-1, titanium dioxide 13469-67-7 ‘SWALLOWED Immediately give 2 glass of water. {8 Firsts rot generally requred. In doubt, contact a Peisons Information Cente or a doctr. EYE ff this product comes in cantact with eyes: Wash out immesiaely wth water © iriaion cominues, seek medical attention {© Remova of contact ences ator an eye iu shoul ony be undertaken by skied pertonn ‘SKIN {nf sn contact eceurs Immediately remove al contaminated clothing incuding footwear. Flush stn ad hair with runing water (and soap i avaHabl). 1 Seck medical aenionn event fietation INHALED © ifures aerosol or combustion product ae inhaled remove fiom contaminates area 1 Other measures are usualy unnecessary NOTES TO PHYSICIAN 1 Treat sympiomateally. EXTINGUISHING MEDIA 4¢ There eno retction on the ype of extinguisher which may be used. 12 Use exhgushing media sutabe for surounding area. FIRE FIGHTING. ‘¢- Aer Fire Brigade and tl hem locaton and nature of hazard ‘© Wear breathing apparalus ps protective gloves for fire ony. 1 Prevent by any means avaiable, spilage fom eterng drains or watercourses. 1 Use fre ghing procedures suitable fr surrounding ares ‘¢ DO NOT aporoach containers suspected to be hot Cool fre exposed containers with water spray from a protected locaton. I safe te do so, remove containers rom path of re ‘© Eauioment should be thoroughly decontaminated after use, FIREIEXPLOSION HAZARD ‘Soli wrich exits dict combustion ors eiculto lgnte 1 Avoid generating dust, partculary clouds of dustin a confined or urventiated space as dusts may form an explosive mixture (oth a and any soutea af gntion, a. fame or spark, wil cause fire or explosion ‘¢ Dutt clouds genorated by the tne ringing ofthe sold area paricular hazard; accumulations of fire dust (420 micron or less) may bum rapidly and fercely i iited, once nilated larger Daricles up to 1A0D microns ameter wil contibute to the ‘ropagilion oF an expiosen. ‘¢ A dust explosion may release of large quaniies of gaceous products; tis In tum creates a subsequent pressure rise of fexplash free capable of damaging pant and bulcings and Ijin pecele ‘© Usvally he iil ar primary explosion fakes place ina confined space such as plant or machinery, and can be of suticent force fo damage or rupture the pan. I the shock wave fom the primary explosian enters the suraunding ares wil disturb ‘any salted dust layors, forming a second dust cloud. and often aise 8 much largar secondary explosion. Al large scaie ‘xpleslens have reaited fom chain eactons oF tis ype ‘¢ Ory dust cen alzo be charged elocrotatcally by trbulence, pneumatic vranepot, pouring, in exnaust ducts and during ‘© Bull-upof lecvostate charge may be prevented by bonding end grounding ‘¢ Powder handing equipment such a= cust cllectors,eryers and mils may requte addsonal protection measures such 3s lesen venting [Link] &NzGe=&cwno: 187-268&c... 30/01/2012cG3 Page 3 of 12 Vertex Self Curing Powder aa Chomwatch Material Safety Data Shest (REVIEW) Version No: 2.0 Chemwatch 8187-26 Issue Date: 15-Apr-2011 cat7LP ‘2 Almovable pars coming in contact with this mate should have a speed of less than t-meteisec. Combustion predts include: carbon monoxide (CO), carbon dioxide (C02), aldehydes, other pyrolysis products typical of burning organi materal OTE: Burns win intense heat Produces meting, flowing, burning liquid an dense sri black smoke. May emt poisonous tunes. FIRE INCOMPATIBILITY + Ae ortarraton a ong ape mes, ong aoe, cae Bleases, fel cn 8 ton may result HAZCHEM None MINOR SPILLS ‘© Clean up al spls immediately ‘Avoid Breathing dust and contact wih skin and eyes. ‘Wear protective thing, gloves, safety glasses and dust respirator Use dy clean up procedures and avold generating dust Sweep up, shovel up or Vacuum up (conederexploeon-proof machines designed tobe grounded during storage and use) Pace spilad mater nelean, dy, sealable, labeled container MAJOR SPILLS. Moderate hazare © CAUTION: Advise personnel in area. Alot Emergency Services and telthem locaton and nature of hazard Cento! personal contact by weaving protective clothing. Prevent by any means avaiable, spilage fram entering drains or water courses Recover product wnerever possible IF ORY. Use dry clean up prooadures and avoid generating dust. Collect residues and slace In sealed plaste bags or other Containers for 'sposa, IF WET. Vacuumisnovel Up an place in labelled containers for dsposel. ALWAYS: Wash area down with large amouns of water 2nd prevent runof into drains. I contamination of atains or waterways occurs, advise Emergency Services. Personal Protective Equipment advice is contained in Section 8 of the MSDS. PROCEDURE FOR HANDLING “Avo al personal comac, including inhalation, ‘Wear protecive thing when risk ef exposure ooo. Use ina wel-vontilated area Prevent concentration in halows and sumes. DO NOT enter continad spaces unblaimogphere has been checked 100 NOT alow matenal fe conse! humans, exposed food ar ood uensi ‘vod caret wit incompatible materials. ‘tien hending, DO NOT eat, drnk or smoke. Keep corlsinere securely eealed when notin use, ‘Avoid physical damage (0 containers. ‘Atay wash nands wih coap ana water after handing ‘Work clothes shoud be laundered teparatly. Launder contaminated clothing before re-use Use good cecupational work prac Observe manufacturers stor and handing recommendations. [Nimesphere should be regulatly checked against established exposure standards to ensure safe working conditions are SUITABLE CONTAINER ‘© Polyethylene or polypropylene container ‘© check all containers ae clearly labelled and free rom leaks, ‘STORAGE INCOMPATIBILITY © Avoid reaction wih oxdsing agerts STORAGE REQUIREMENTS 18 Store is erga containers. © Keep containers securely sealed Store in coal, oy area protected rom eniromental extremes, Store away rom meompatbe materials and foodstuff conainers. [Link] exe? print=Y &NzGe=&cwno=8187-26&c... 30/01/2012cG3 hittps://[Link]/chemgold3/[Link]?print=Y &NzGe Page 4 of 12 Vertex Self Curing Powder = Chemwatch Material Safety Data Sheet (REVIEW) Version No: 2.0, Chemwatch 8187-26 Issue Date: 15-Apr-2011 cat7LP 1 Pratoctcantainers agains! physiesl damage and check regularly for leaks. {© Observe manufacture’s string and handing recommendations For major quantities: ‘Consider sorage in bunded areas - ensure storage areas ar coated from sources of community water (inchding stormwater, ‘round water. lakes sno seams), © Enoure hat soodertal iecharge fo air or water the subject ofa contingency disaster management pla: his may requie concuiaton wth lal avons. SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS + x + x x + 2X Must aot be store together (0: May bs sored togomner wi specie proventions + May ba sored togomner EXPOSURE CONTROLS TWA TWA. STEL STEL Peak Peak TWA Snes, Scie) ppm mgim? ppm mgm? ppm maim? FICC Noles usa dvenzoy peroxide Exposure 5 Stcarts oreo peroxide) usta fered ron (eco Erposue me 5 Sheoter Stanaarés (P0208) (0 Fe) * pusvata tau dexico lo Eroosure —(Tarlum dose Stevie ‘Standards (a) 14) “Trey ethos hmopdror OAS 9011-147 EMERGENCY EXPOSURE LIMITS Material Revised IDLH Value (mg/m?) Revised IDLH Value (ppm) cibenzoyl peroxide|2085-1 1,500 ferric oxide|10253. 2,500 Atari doe 0671 5,000 MATERIAL DATA METHYL METHACRYLATE HOMOPOLYMER: TITANIUM DIOXIDE ‘= Sensory rans are chemicals that produce temporary and undesirable side-effects on the eyes, nese or thea. Historically ‘Sceupational exoosureslandards for tase wrlante nave bean based on observation ef workers’ responses 19 varous airborne Concentrations. Present Jay expectations eauire hat Neary evety inalidval should be protected against even minor sensory Intation ard exposure standards are esiatished using unceranly factors or slelyTaciors ofS to 10 or more. On occasion ‘animal no-cbservable-ffect-evals (NOEL) are used fo determine these nts where human results are unavaiable. An additonal ‘3pproach,ipicaly used by the TLV comvmile (USA) h determing respratery standards for tue group of enemicals, has been {o assign cling valves (TLV C) 1 rapidly acing irtanis and to assign shortierm exposure mis (TLV STELS) when the weight of fevdence fom iiaon, accumulation and other endpoints combine to warrant such a fmt. contrast the MAK Commission (Germany) ases 2 fve-ategory system based on intensive odour, local rrtabon, and einauon haltife. However this system being replased lo be consistent wth the European Union (EU) Sceniie Commitee for Desupatonal Exposure Limits (SCOEL}, {hs is moreclosely alled to that of he USA. ‘OSHA (USA) concluded tat exposure fo sensory inant can: ‘© cause inflammation Cause increased auscopiiily 10 other iritants and infectious agents lead to fermanent injury or dystunction permilg eater absorption of hazardous substances and _2cclate the worker othe tant waring propertes of these substances hus increasing the risk of overexposure -S&ewno=8187-268&e... 30/01/2012cG3 hittps://[Link]/chemgold3/[Link]? print=¥ &NzGe=&ewno=8187-26&c.. Page 5 of 12 Vertex Self Curing Powder egies Chemwatch Material Safety Data Sheet (REVIEW) Version No: 2.0 Chemwatch 8187-26 Issue Date: 18-Apr-2011 cat7LP VERTEX SELF CURING POWDER. 1 No exposure ins set by NOHSC or ACGIH, METHYL METHACRYLATE HOMOPOLYMER: fl: ie te goal ofthe ACGIH (and ether Agencies) to recommend TLV (or thelr equivalent) for al substances fr which there is {evidence of heal effects at asoine concerivalons encounleted in the workplace Btthis time no TLV nas been establshea, even though tis material may produce adverse heath effects (as evsenced in anima {xpermenis or cneal experience). Arborne concenkratone musi be manlamed as low as ls practealy possble and czcunaicnal fxposure must be Kept to a minimum, NOTE: The ACGIH oecupatoral posure standard or Paricles Not Otherwise Specified (P.N.O.S) does NOT apply. DIBENZOYL PEROXIDE: 1 For benzoyl peroxde: ‘Ihe recommendation fr the TLV-TWA fe based on the absence of subjective symplems of ination ofthe nase and throat in humans exposed to 5.28 gi, Whather tis is suticieny lw fo prevent cumulative eflecis in man is ot known, FERRIC OXIDE 1 For iron oxge (fer onde): Innalation of fon oxide dust or fume may produce 2 benign pneumaconiosis (siderosis) The TLV-TWA ls recommended 10 minirse be polenta for development of X+ay changes in the lung on longterm exposure, These changes are net considered 0 be associated with any physical impairment of lung functon. akhough more sophistisatee physblogical esting. ncluing ‘measurement of te lung's mechanical prapertes ana expatory ung fow s fequred te reach fem and final conclusions, Foramorohouscrystatine sli (prectptatea stile 3213) ‘Amorpnous erystaline se shows sie seenial for pdueing adverse effects on the ng and exposure standards should reflect ‘ partulate oon intansic toxcty. Matures of amorphous sileas! diaomaceous earth and erytaline silica should be montored asifthey comprise ony the crystaine forms, ‘The dusts tom precptated sitoa and sea gel produce ite adverse effet on pumanary functions and are not known to produce sugrcant disease of one eect IARC has classed sles, amorphous 98 Group 3 NOT classifiable as tots carcinogenicity fo humans. Evicence of earenogeniay may be inadequate or irted in anal testing {The esommendee TL ia taught to reduce the Ikelneod of fepiaiory Paton and akin ration fom exposure to aerosols and mists of subi Fon sas TITANIUM DIOXIDE: 1 Animals exposed by inhslatin to 10 mgim3 ttarium oxide show no signeant fibrosis, possibly Srontecture eftung a spaces remains nae, PERSONAL PROTECTION erable tissue reacton, The EYE 1 Seely glasses with side sheds © Chemical gogales 1 Contact lenses may pose a special hazard; soft contact lenses may absorb and concenvate ertants. A whiten policy document. describing the wearing o lens or fecticons on use, should be created for each warkolace or task. This should Include a review of foe absorption and adeorgton for the cass of chemicals n use and an account of ir experience Medics snd fretaid personnel shoud be trained in thet removal and sutable equipment should be readily availabe. Inthe event of chemical exposure, begin eye iigation immediately and remove conlact ens as soon as pracheable. Lens should be Temoved al the fst sans of eye redness er ation «lens should be removed na ce ent ony afer workers have tnashed hands thoroughly. [CDC NIOSH Curent rteligence Bullet 59) (ASINZS 1336 or natonal equivaler) HANDS/FEET 1 Sulabiily and durability of glove type is dependent on usage. Important facors in he selection cf gloves include equercy and duration of contact 1 chemical resistance of glove mater dove tidkness and © destesty Seo ores exes aleval anc Eurepe EN 374 USF, ASNZS 2161 1c ralnl eulae ‘inen prolonged or frequen repeated contact may occur a glove wih a protection cass ofS or higher (breakthrough time ‘ealr than 840 minutes according to EN 274, ASINZS 2167101 or national equivalent) 's recommended, ‘© When only bref contsct is expected, a glove wih a protection clas of 3 or higher (beaKlhvough ime greater than 60 minvies according 9 EN 974, ASINZS 2161 0.1 ornatonal aqulvalant) is recommendes. «© Contaminated aloves snould be repiaced. Gioves must only be worn on clean hands, Aer using gloves, hands should be washed and dried thoroughly Applicaton of nompertumed moistrses recommended Experience indicates thatthe following polymers are sutable as glove materials for protection against undasoWved, dry sols where abrasive parcles arent prevent © "poljehioroprne tte rer © bulvirubber 1 Moracaoutenoue 30/01/2012G3 Page 6 of 12 Vertex Self Curing Powder = Chemwatch Material Safety Data Sheet (REVIEW) Version No: 2.0 (Chemwatch 8187-26 Issue Data: 15-Apr-2011 cst7LP 1. polyviny chloe ‘Goves shouldbe examined for wear and! or degradation constantly Viear chemical protective gloves, eg, PVC. 1 Wear sletyfoctwear or safely gumicots, eg, Rubber NoTe "The material may produce skin sensation in preciposed indvduale, Care must be taken, when removing gloves and other Droiectve equipment te avait al posse skin const. ‘2 Contaminated leather tems, such a8 shoes, bells and watch-bands should be removed and destroyed OTHER © Overall © PVC. apron 2 Barrer cream, 1 Skin acansing cream. (8 Eye wath unt RESPIRATOR 12 Paricuite (ASINZS 1716 & 1715, EN 143-2000 & 149-2001, ANSIZB8 or national equvaent) w Required Minimum eee Halt Face Respirator Full-Face Respirator Powered Air Respirator up to 10xES. Pt Airstine* ee PAPR-PI - upto 50xES Airline” P2 PAPR.P2 upto 100x ES - P3 : Airline® i“ 100+ x ES : Airline™* PAPR-PS ~ Negative pressure demand “Continuous flow ‘NAY casses) = Organic vapours. B AUS or BY = Acid gasses, B2 = Add gas or hydrogen cyanide(HCN), 83 bysrogen erande(HN) € = Sur oxide S02), G= Agricultural chemicals, K= AmemonatNHS) 9 = Mercury, Ni ‘trogen, M3= Meth bromide, AX= Low boling pint organic comsounds(oaiow 65 degC). ‘Tre local concentration of mater, quantity and condone of ue determine the type of personal protective equipment requred For urthernformation consul ste specie CHEMWATCH daa if avalabl) or your Occupational Health and Safety Ads0r, ENGINEERING CONTROLS ‘= Engieerng controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designes [Sngiearing contale can be highly effecive in protecting workers and wil typlcally be independent of worker ineracions {© prove tishigh love of protector ‘The basic pes of engineering controls ae: Process cons which involve changing te way a jb actly er process i done to reduce he risk Enclosure andor lslaton of emission t2u‘ce unin keeps # selected hazard “physical” awa from the worker and ventilation {ha salegiealy “adds” aed “vamoves" air i Be work environment. Ventlaon can remove oF die an a contaminant ‘designed propel. The design of a ventilation system must match tne parbeular process and chemical ar contaminant Use Employers nay need fo use mutt types of contels to prevent employee overexposure © Local exhaust ventiaion ls requis where solds are handled as powders cr crysials: even when particulates are eatvely large set proporton wll be powdered by mutual Ficton © Ihin spe of Ital exhaust an adverse concentration of the substance in alr could occur, respatery protection should be ‘Such pratetion might consist of (al: parle dust esprators, necessery, combined with an absorption cartidge: (}: ter exprsiors win apserpton carnage ar cansier of he rahi ype: (eh: teshar heads or masks. APPEARANCE ‘Clear or prk povder wih faint exter-ke odour: not misebe with water PHYSICAL PROPERTIES Does not mx wth water. ‘Sinks in war state Divided Solid Molecular Weight Not Available ‘Metting Range (°C) >240 (decomp'n) Viscosity Not Available Bolling Range (°C) Not Available ‘Solubility in water (g/L) Immiscible Fiash Pont (°C) Not Applicable pH (1% solution) Not Applicable Decomposition Temp (°C) >240, pH (as supplied) Not Applicable Autoignition Temp (°C) Not Available ‘Vapour Pressure (kPa) Not Available Upper Explosive Limit (%) Not Available Specific Gravity (water=1) 1.04.18 [Link] &NzGe=&cwno=8 187-268c... 30/01/2012Page 7 of 12 Vertex Self Curing Powder {gai Chematcn Mato Safety Osta Sheet (REVIEW) Versione:200Chemvach 8187-28 Issue Date 15-Apr-2011 came LonerEslosneLini(%) Notavalatie live VapourDenmty Natale Volale Component (hel) Net Avaistle Evaporation ate Not Avtete CONDITIONS CONTRIBUTING TO INSTABILITY 18 Presence of incompatible materials Products conscered sabe ‘¢ Hazardous polymerisation wil not occur. For incompatible materials - refer to Section 7 - Handing and Storage, [Link] print=Y &NzGe=&ewni POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS ‘SWALLOWED "The material has NOT been class‘ied by EC Direcives or ether classification systems a¢ "harmful by Ingestion”. This is Because of he lack of eonteboratng animal or human evidence. The mail may sl be damaging f the heal ofthe indvdual folowing ingestion, especial Dre-sxistng organ (e9, iver kidney) damage is event. Present detintions of harul of tonic substances are generaly based on doses producing morlally rather than these producing merbily(cisease,i-nealy), [Gastrainestinl tract iecomfon may produce nausea and variing It en accupatonal soting however, ingestion of nsgnieart (quantis is not inought to be cauae for concer. figh meleedar weight materal on single acuis exposure would be expected to pass through gestrcntestnal tact wih ile Change |absorpon Occasionaly accumuiation ofthe sold material within fe alimentary tract may recut in formaton ef a bezoar {coneretan), proucing dlscomfort EYE 1 Athough the material is not hought to be an inant (a clasiied by EC Directives}, crac contact with the eye may cause {Tansient dleconton characterized by tearing or conjunctival redness (as with windburr). Sight abrasive damage may slo result ‘The material may produce freign body irfalionn certain indivuals. SKIN 1 The material isnot thought to produce adverse heath effects or skin ittatlon following contact (as classified by EC Directives {sing anmal models) Neverheless, good hygiene practice reques that exposure be Kepo 2 minimum and that suitable loves be used nan occupational seting Eniry nt the blood-steam, tough, for example, cis, abrasions a lestons, may produce systemic nury with harmful effects Examine the skim prorta the ues of he materia arid ensure hat any external damage fs suably proteced INHALED f Innalaton hazard i increase at higher temperatures ‘Tne materials not thought to produce adverse health effects or eration of the respiratory trac (as classified by EC Directives Usipg anmal models) Nevertheless. good hygiene practice requves that exposure be kept lo 2 mismum and that stable conto) messures be used in an seaupatonal eating, Not normally @ hazard due io hon-olale nature of product CHRONIC HEALTH EFFECTS ‘= Ths oateralcontina a substantial amount of polymer considere tobe of law concern, These are classed under having M's [St between 1000 f0 70000 with less than 25% of melecules wih MWe under 1000 and less than 10% under 500, or having = ‘molecular weght average of ever 10000. Functonsl groups contained onthe palymer are ben classed ito sk categoria, Being classtied 25a polymer of "aw concern does nol mean fat here ae no hazards associated with the chemical Long term exposure fo nigh dust concentrations may cause changes in lung function ie, pneumeconose; caused by aries less than 05 meron penetaing and temairing in the ling. ime symplom is breathlessness, lung shadows show On X13 ‘There has been some concer thai tis material ean cause cancer or mutations but there 's nol enough data to make sn assesament ‘There ls some evidence that inhaling ths product is more key lo cause @ sensitsston rescton in some persons compares othe genaral population $Suin comact withthe material i more likely fo cause a sensisaion reaction in some persons compared tothe general population. Tepeated exposure may cause sanelisaton andr allergic reactions TOXICITY AND IRRITATION Unless cthenuise spaced data extacied fom RTECS - Register of Tonic Etfects of Chemical Substances {TITANIUM DIOXIDE DIBENZOYL PEROXIDE: ‘The material may cause skin iaion after prolonged or repeated exposure and may produce on contact skin redness, sweling the production of vecieles, sealing and iickerang ob skin. DIBENZOYL PEROXIDE: VERTEX SELF CURING POWDER: Contact alergies queAly mares! themselves as conlact eczema, more rarely as urtearia or Quincke's edema, The pathogenesis af conta! cezama involves a cel-mediate (T lymphocytes) immune reaction ofthe delayed Iype. Orne alleaic Shin reantons, eg, contact urteara, Involve antibody-mediated immune teactons. The signficance of the contact allergen i not 30/01/2012G3 Page 8 of 12 Vertex Self Curing Powder pelea CChemwatsh Matera Safety Data Shoet (REVIEW) Version No: 2.0 Chemwatch 8187-26 Issue Date: 15-Apr-2011 cat7LP ‘ingly detwmined by ts senstisaion poten: the clstibuton of the substance and the opportunites for contact wih tare equal important. A weakly sensising substance which is wadly debuted can be a more imporint allergen than one wih “Stonger seveasng potent wih which few individuals come n(o coniact From a clnical pont cf wew. substances are flowortny {hey plodice an slergc test reacton in more than *%¢ ofthe persons tsi DIBENZOV_ PEROXIDE METHYL METHACRYLATE HOMOPOLYMER: “The substance is classed by IARC 35 Group 3 NOT classe ae toe careinogeniey fo Numan. Evidence otearcinogenty may be adequate of lrited in VERTEX SELF CURING POWDER: imal esting METHYL METHACRYLATE HOMOPOLYMER: No significant acue taxiesogical data identied in oratue search DIBENZOY. PEROXIDE! TOXICITY IRRITATION ral (rat) O50: 7710 mglkg Eye (rabbit): 500 mg/24n - Mild Inhalation (human} TCLo: 12 mgimn* ‘Skin effects (MAK): very weak ‘Subcutareous (Rat) LD: 40 mg/kg (@ 50%) Intraperitoneal (Mouse) LDSO: 440 mg/kg Intravancus (Rabbil) LD: 16 mg/kg ‘The material may be iratng tothe eye, with prolonged contact causing inlammation. Repeated or prolonged exposure to intants may produce cojunctvts [Benzoyl peroude ray cause doubla vison, breathing problems, excess salva ard tear formation, rdness of the skin and {changes Inmolor acid nat produce biood or Blech mical adverse eects, gene mutation or evidence of cancer. Repeated ‘rl aminisation may resulin decreased weights cf tsias andthe newborn FERRIC OXIDE: ‘Asihmavlcesympfone may continue for months or even years after exposure tothe material ceases. This may be due to anon Slergenic eandtion known ae raoive aways dyetuncion syndrome (RADS) which can cccu flowing exposure fo high levels of Figny ertatng compound. Key entra forthe dagnoale of RADS inctude the absence of preceding respratory disease, in @nor= Stop nahrdual wth abrupt enset of persistent aethmaixe symptoms withn minules fo hours of @ documented exposure tothe intant "A reversible aifow patier, on spirometry, wit the presence of moderate Io severe bronchial hypereactvty on ‘mehscheline challenge (esting and the lack of minimal Iymphocyte ifammation, without eosinophilia, have also been included in {he artenalralagress of RADS. RADS (or asthma fling an rating [Link] Is an infrequent csorder wih rates elated (2 the eoncenravon ef and duration of exposure fo the iiaing stance, Industral bronchi, on the other hand, ts a disorder that ‘ure ae tel of exposure due Io high concentrations of iiating substance (olen parteuate in nature) and is completly reversible ait exposure ceases. The ceorde'scharaciesed by dyspnea, caugh and mucus production, TOXICITY IRRITATION TITANIUM DIOXIDE: (Oral (Rat) LD50: 20000 mgikg * ‘Skin (human): 0.3 mg 3D (int)-Mild * (ral (Mouse) LD50: 10000 mg/kg * ‘The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged ‘exposure to initants may produce conjunctivitis, Exposure to titanium dioxide is via inhalation, swallowing or skin contact. When inhaled, it may deposit in lung tissue and lymph nodes causing dysfunction of the lungs and immune system. Absorption by the: ‘stomach and intestines depends on the size of the particle, It penetrated only the outermost layer of the ‘skin, suggesting thal healthy skin may be an effective barrier. There is no substantive data on genetic, «damage, though cases hrave been reported in experimental animals. Studies have differing conclusions on its cance’-causing potential. *IUCLID CARCINOGEN International Agency for Research on Cancer (IARC) - Refirnethys mesiacryate ‘Agents Reviewed by the IARC STOUP 2 Monographs International Agency for jesearch on Cancer (IARC) - Benzoyl paraxide: ‘Agents Reviewed by the ARC. STOUP 2 Monographs International Agency for hitps://[Link]/chemgold3/[Link]? print=Y &NzGe=&cwno=8187-26&c.... 30/01/2012cG3 Page 9 of 12 Vertex Self Curing Powder ‘ieee Chomnwatch Material Safety Data Sheet (REVIEW) Version No: 2.0 Chemwatch 8187-26 Issue Date: 18-Apr-2011 cat7LP Research on Cancer (IARC) - Fore oxide ‘Agents Reviowed by the IARC Group 3 ‘Monographs International Agency for Research on Cancer (IARC) - ‘Agents Reviewed by the ARC ‘Monographs: TITANIUM DIOXIDE FERRIC OXIDE sForbelal mosphere Fale - Metsl-containing inorganic eubstancee generally have neglible vapour pressure and are not expected to partion tai Ennrormentai Fate Envkonmenta processes, such as oxidation, the presence of acide or bates and microbiological processes, ‘may wransform insoluble metals fo more solic lon forms. Envionmerial processes may ennance boavasabilly ard may also be mporiat in changing slubites. [Aquat Terresinal Fate Vihen released to dy go, most metas wl exhib limit mebilty and remain nthe upper ayer some wil Teach locally info ground water andor surface water ecosyetems when soakod by fan of mel ice. A metal on 'sconsdered Inately petisent because I cannot degrade further. Once released To surface wales and moist sos ther fate deoends on ‘oUbiiy and dascestion in water A significant proportion of dissoWed! sorbed mellc mill ond up In eediments through the Setling of suepended paricles The remaining meta fons can than be taken up by aquale organisms. lnic species may bind Io Giseotved ganas of sob lo Solid partas in wator. Ecotoweiy Even though many mets's show few toxic elec at physiological pH levels, vansformation may introduce new or magnified effects DIBENZOVL PEROXIDE FERRIC OXIDE TITANIUM DIOXIDE METHYL METHACRYLATE HOMOPOLYMER 15100 NOT discharge into sewer or watery, METHYL METHACRYLATE HOMOPOLYMER Titanium dioxide Group 28 Hazardous Air Pollutant Yes Fish LCSO (96hr.) (mg/l) 480.277 Daphnia magna ECS0 (48hr.) (mg/l) 37-120 BODS ona Haltulife Soil - High (hours) er2 Half-life Soil - Low (hours) 168 Haltsife Air - High (hours) a7 Haltife Air ~ Low (hours) ut Haltsife Surface water - High (hours) 672 Haltsife Surface water - Low (hours) 168 Halfsife Ground water - High (hours) 1344 Half-life Ground water - Low (hours) 336 Aqueous biodegradation - Aerobic - High (hours) 6r2 ‘Aqueous biodegradation - Aerobic - Low (hours) 168 Aqueous biodegradation - Anaerobic - High (hours) 2688 ‘Aqueous biodegradation - Anaerobic - Low (hours) er Phoitooxidation halflife air - High (hours) 97 Photooxidation hatte air - Low (hours) 14 First order hydrolysis halflife (hours) 4YRS Base rate constant [(MOH)-HR}1 200M he DIBENZOYL PEROXIDE hittps://[Link]/chemgold3/[Link]? print=V &N2Gc=&cwno=8 187-26&c.,. 30/01/2012ca3 Page 10 of 12, Vertex Self Curing Powder a al CChemwatch Material Safety Data Sheet (REVIEW) Version No: 2.0 CChemwatch 8187-26 Issue Date: 15-Apr-2011 csi7LP [Link] Soil - High (hours) 48 Half-life Soil - Low (hours) 4 Hallie Air - High (hours) 810 Halfife Air - Low (hours) 5 Half-life Surface water - High (hours) 168 Halfife Surface water - Low (hours) 24 Half-life Ground water - High (hours) 336 Half-life Ground water - Low (hours) 48 ‘Aqueous biodegradation - Aerobic - High (hours) 168 Aqueous biodegradation - Aerobic - Low (hours) 24 ‘Aqueous biodegradation - Anaerobic - High (hours) er ‘Aqueous biodegradation - Anaerobic - Low (hours) 96 Phototysis maximum light absorption - High (nano-m) 278 Photolysis maximum light absorption - Low (nano-m) 235 Photooxidation half-life air - High (hours) 510 Photooxidation half-life air - Low (hours) st 1 For bonzzyi peroxide Benzoyl peroxide has a malting point of 104 106"C, vapor pressure of 0.00829 Pa, solubty of 2.1 [Link] water at 26 C, and log Pow of 8.42 25C. Ennonmertal Fale For indirect ahotolyie in the atmosphere, the [Link] is esimated 1o be 3 days. The substance is realy bodegradable and hyaralyses taply wale. The man hystolyss product of benzoyl perosde ls benzoic acid. The estimated BEF a Sa gente he rem ow per bencamatn. orzo pera mes ket prion wat uahere i wilreman Ecolowcty Steen algae (Selenastum caprcomutum) EBC (72.n) 0.07 mah biomass) and 0.44 mgi (growth rate), DDaphna magna ECSO (28 h) O07 mat Fish LOS0 (6 h) Oryzias latipes 0.24 igh. Mircorganssm (activated shidge)ECS0 (30 mi) 35 mal. {The lonciy sbserved 1s e2sumed to be due to Den2oyperonde father than benzole ald, which shows much lower toxeily 10 uate organisms, Ons can assume that acts cocur before hydrolysis takes place FeRgRic on1De ‘TITANIUM DIOXIDE Ecotoxicity 7 Persistence: Ingeedien een Persitence: Air ‘Bioaccumulation Mobility ‘ethyl methacrylate homopolymer tow’ Low Low HIGH Ginenzoyl paroxée Low HIGH tow Med ferme once No Data Avalable No Data Avatable ‘anum deed HIGH No Data Avaiable LOW HGH 1 Recycle wherever possito, Consult manulacturer fer recycling options or consul lea! or regional waste management authory for ssposal fro suitable ‘Weatment of esposal ‘actly ean be laenes © Dispoce of ty: burial ina landil specifically lcenced to accept chemical and / or pharmaceutical wastes 0” Incineration in & licenced apparaius (ater admisture wih suitable cornbustble matcral) ‘© Decontaminate empty containers. Observe all abel safeguards untlcontaners ae clean and destroyed. © Containers may sil presenta ehemics! hazard danger when empty. © Relum 0 supple for use! recycing possible. Otrernse: ® Ii container can ot be cleaned sufienty well to ensure that residuals do not remain or I the container eannot be used fo Store ine same produ, nen puncture contaners to prevert re-use, and bury ai an aurorsed isn ‘© Where fossbie retain abel wamings ang MSDS and obsene al noes pertarning tthe procuet [Link] print=Y &NzGc=&cwno=8187-268c..._ 30/01/2012cG3 Page 11 of 12 Vertex Self Curing Powder eee Chemwatch Material Safety Data Sheot (REVIEW) Version No: 2.0 Chemwatch 8187-26 Issue Date: 15-Apr-2011 cai7p HAZCHEM: None (ADG7) NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG POISONS SCHEDULE Nene REGULATIONS, Regulations for ingredients methy! methacrylate homopolymer (CAS: 9011-14-7) is found on the following regulatory list “Australia Inventory of Chemical Substances (AICS) Intemational Agency for Research on Cancer (ARC) Agents Reviowsd by the IARC Monographs" dibenzoyl peroxide (CAS: 94-36-0) is found on the following regulatory lists; “aver = Sou Austata Controlled Substances (Poisons) Regulations - Schoduo E: Schedule 2 poisons authorised to be sold by holéer of @ medicine sellers icence’ “Ausraia Dangerous Goods Code (ADG Code) - Uist of Curenty Assigned Organic Peraxides in Packaginge’-Ausivaa Exposure Slandards’ Austfale Hazardous Subslances",AUstrala inventory of Chemical Substances (AICS) “Ausra Siandard Tor the Un‘orm Schesulng of Medenes and Poisons (SUSMP) - Anpendix E (Part 2), Aistala Standard forthe Uniform Scheduling of Medicines and Poisone (SUSMP) » Appenchs F (Part 3) *Austraba Standard ‘av'the Untorm Scheduling of Mesicines and Potons (SUSMP)- Schedule 2 “Australia Standard forthe Uniform Scheding of Medicines and Poisons (SUSMP) - Schedule 4""Austaka Slandard for the Unform Scheduing of Wediones and Poisons (SUSMP) = ‘Schedule. S*"intematonal Agency’ for esearen on Cancer (IARC) = Agents Reviewed by the IARC Monographs" Tntematcnal'Air Transport Associaton (IATA) Dangerous Goods Reguiations'Inlersaonal Air Transport ‘Azzociaton (ATA) Dangerous Goods Regulations - Prohibied Us! ferric oxide (CAS: 1308-37-1) is found on the following regulatory lists “Australia Exposure. Slandards'-Ausvalia High Volume Indusisal Chemical Uist (HVICL}\ Substances AICS)'"Intematonal “Agency for Research on Cancer (IARC) - Agen Monographs nterational Counct of Chemical Assciations (ICCA) - High Progucion Volume Uist” titanium dioxide (CAS: 13463-67-7,1317-70-0,1317-80-2,12188-41-0,1309-63-3,100292-32-8,101239-53- 6,116788-85-2,12000-59-8,12701-76-7,12767-65-6,12789-63-8,1344-29-2,185323-71-1,185828.91- 5,188357-76-8,1 88357-79-1,195740-11-5,221548-08-7,224963-00-2,246178-32-5,252962-41-7,37230-82- 5,37230-94-7,37230-95-8,37230-96-9,39320-58-6,39360-64-0,39375-02-7,416845-43-7,494848.07- 6,494848.23-6,494851-77-3,494851-98-8,55068-84-3, 55068-B5-4,552316-51-5,62338-64-1,767341-00- 4,97928-50-5,98084-96-9) is found on the following regulatory lists; “Australia Exposure Standards'-Ausialia High Volume Industral Chemical List (HVICL)“"Australa Invenfory of Chemical Substances (AICS) “Austraia Therapeure Goods Adiministaton (TGA) Subslances that may be used as acive ingediens Usted medicines! Australia Terapauiie Geode Adminiaton (TGA) Sunsseening agents permilled ab actve ingredients In listed procucte"“CODEX Gener! Standaré for Fo0a Addiives (GSFA) - Addiives Permitea for Use in Food 1 General, Unless (Dinenvisa Spectiac, m Accordance win GMP"GESAMPIEHS Composit List - GESAMP Hazard Profles' IMO IBC Code Chapter 17: Summary of mrimum reqUrements""Iriarataral Agency lor Research on Cancer IARC) - Agents Reviewed by the TARE Monographs" “itematona! Fragrance Aseceaion (FRA) Survey. Transparency List sala Inventory of Chemis! Reviewed by the ARC No data for Vertex Self Curing Powder (CW: 8187-26) Ingredients with multiple CAS Nos Ingredient cag Name 19465-677, 1917-702, 1317-802, 12166-41.9, 130068. on29232-8, wI2veste, vie7aB-eS3, 12000-5958, stony 12TOI-T6 12767-8546, (2780-688, 1344-202, 86528-7I-, 18582%01-5, 188967-7-8, 198057~704, 195740-11- Monum — 52at gue 62-7, 224009.00-2,240170.32-5, 250962-1-7,37290-925,37230-96-7, 37290868, 3723028-8, 39520- Sb, 30360-64, 20079-02.7, s7084-48°7, 49464e-07-, e98040-25-6, 4948614779, 404861-98-, SSDbE-O4 3 55068. 85-4, 55234651 5, 82358-60-, 7o7S#i 00-4 e7e26-505, s808s.209 individval components has drawn on offesl and authontstive sources as well as f= Classfcaion ofthe preparation and erature references independent reviow by the Chemwatch Clasietion comntee using avalable (Ris! of reference resources used to sit tne comics may be ound ‘[Link] 12 The (M|SDS ts a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine Wirether the reported Hazards are Rske in te workplace of other stings. Risks may be determied by reterence to Exposures ‘Scenarios Seale of use, frequency of use aed clei or avalable engineering contols must be consicered This document is copyright. Apart from any fair dealing for the purposes of private study, research, review cr criticism, as permitted under the Copyright Act, no part may be reproduced by any process without [Link] &NzGe=&ewno=8187-26&c..._ 30/01/2012G3 Page 12 of 12 Vertex Self Curing Powder Saas ‘Chemwatch Material Safety Data Sheet (REVIEW) Version No: 2.0 ‘Chemwatch 8187-26 Issue Date: 15-Apr-2011 cest7P written permission from CHEMWATCH. TEL (+61 3) 9672 4700. www. Chemwatch. net leave Date: 15-Apr-2011 Print Date:30an-2012 hitps://[Link]/chemgold3/[Link]?print=Y¥ &NzGe=&cwno~8187-26&c... 30/01/2012