GENERAL ¨ ARTICLE
Fermi–Dirac Statistics
Derivation and Consequences
S Chaturvedi and Shyamal Biswas
(left) Subhash Chaturvedi
is at University of
Hyderabad. His current
research interests include
phase space descriptions
of finite state quantum
systems and quantum
information theory.
(right) Shyamal Biswas
is at University of
Hyderabad. His research
interests include statistical
mechanics, and theoretical
condensed matter physics.
Keywords
Pauli exclusion principle, Fermi–
Dirac statistics, identical and in-
distinguishable particles, Fermi
gas.
RESONANCE ¨ January 2014 45
GENERAL ¨ ARTICLE
Particles with 1/2-
integer spin such as
electrons, protons,
neutrons, 6Li atoms
are called fermions.
They obey
Fermi–Dirac statistics.
In contrast, those with
integer spin such as
photons, mesons, 7Li
atoms are called
bosons and they obey
Bose–Einstein
statistics.
46 RESONANCE ¨January 2014
GENERAL ¨ ARTICLE
Fermi–Dirac and
Bose–Einstein
statistics brought into
play a new notion of
purely quantum
mechanical origin –
the notion of
indistinguishablity.
RESONANCE ¨ January 2014 47
GENERAL ¨ ARTICLE
Occupation number
description consists in
grouping together the
states in the set
|i1 ²
|i2 ²
...|iN² i1, i2,
..., iN = 1,2,..., M in
which 1 occurs
n1 times, 2 occurs n2
times and so on. The
occupation numbers
evidently
add up to N and the
total energy of the
system corresponding
to a given set of
occupation numbers is
¦i 1 ni H i .
M
given by
48 RESONANCE ¨January 2014
GENERAL ¨ ARTICLE
RESONANCE ¨ January 2014 49
GENERAL ¨ ARTICLE
The permutation
group SN plays a
crucial role in defining
the notion of
indistinguishability in
the context of non-
relativistic quantum
mechanics of an
assembly of non-
interacting identical
particles. F–D and
B–E statistics
correspond
respectively to the
one-dimensional
antisymmetric and
symmetric irreducible
representations of SN .
50 RESONANCE ¨January 2014
GENERAL ¨ ARTICLE
In Chapter IX of
his book, Dirac
explictly constructs
out of elements of
SN a maximal set
of mutually
commuting
operators which
commute with
Hamiltonian HN.
RESONANCE ¨ January 2014 51
GENERAL ¨ ARTICLE
Among all possible
statistics permitted by
the notion of
indistinguishability
in the permutation
group sense, F–D and
B–E statistics are the
only ones
for which the grand
canonical partition
function Z(X) has the
structure
i 1 z ( X i )
M
Z(X)=
where z(X) = (1 + X)
for F–D statistics and
z(X) =1/(1 – X) for
B–E statistics.
52 RESONANCE ¨January 2014
GENERAL ¨ ARTICLE
The –1 in the
denominator for
the expression for
ni for B–E statstics
gives rise to the
possibility of
Bose–Einstein
condensation in
bosonic systems.
RESONANCE ¨ January 2014 53
GENERAL ¨ ARTICLE
54 RESONANCE ¨January 2014
GENERAL ¨ ARTICLE
Figure 1. Solid, dotted and
dashed lines represent
Fermi–Dirac distribution for
ideal homogeneous Fermi
gas for kBT/HF= 0, 0.1 and 2
respectively.
RESONANCE ¨ January 2014 55
GENERAL ¨ ARTICLE
56 RESONANCE ¨January 2014
GENERAL ¨ ARTICLE
Historically, one of
the first
applications of
Fermi–Dirac
distribution came
from Fowler in the
context of
astrophysics.
RESONANCE ¨ January 2014 57
GENERAL ¨ ARTICLE
Thomas–Fermi
model in nuclear
physics which
nowadays is
commonly used as
an approximation
technique was
proposed as an
application of
Fermi–Dirac
statistics in 1927.
58 RESONANCE ¨January 2014
GENERAL ¨ ARTICLE
Spin-statistics
theorem was
proposed by Fierz
and Pauli around
1940 to connect spin
of particles to either
Bose–Einstein
statistics or Fermi–
Dirac statistics.
RESONANCE ¨ January 2014 59
GENERAL ¨ ARTICLE
Fermi–Dirac statistics
has played a major
role in the
development of
quantum field theory
for many-particle
systems which has
now become the
basic language for
describing
condensed matter
and particle physics.
Suggested Reading
[1] W Pauli, Z. Phys., Vol.31, p.765, 1925.
[2] E Fermi, Rend. Lincei, Vol.3, 145, 1926 [in Italian]; Z. Physik, Vol.36,
p.902, 1926.
[3] P A M Dirac, Proc. R. Soc. Lond. Ser. A, Vol.112, p.661, 1926.
[4] W Pauli, Z. Phys., Vol.31, p.373, 1925;
G E Uhlenbeck and S A Goudsmit, Naturwiss, Vol.13, p.953, 1925 (in
German);
G E Uhlenbeck and S Goudsmit, Nature, Vol.117, p.264, 1926;
L H Thomas, Nature, Vol.117, p.514, 1926;
W Pauli, Z. Physik., Vol.43, p.601, 1927.
[5] W Nernst, Z Elektrochemie, Vol.20, p.357, 1914.
[6] A Einstein, Sitzungsber. Preuss. Akad. Wiss., Phys. Math. Kl. Bericht,
Vol.22, p.261, 1924; Vol.1, p.3, 1925; Vol.3, p.18, 1925.
[7] S N Bose, Z. Phys, Vol.26, p.178, 1924.
[8] Spin of photon was observed to be 1 in 1931 by C V Raman and S
Bhagavantam, Indian J. Phys, Vol.6, 353, 1931; Nature, Vol.129, p.22,
1932.
[9] M Fierz, Helvetica Physica Acta, Vol.12, p.3, 1939 [in German];
W Pauli, Phys. Rev, Vol.58, p.716, 1940.
60 RESONANCE ¨January 2014
GENERAL ¨ ARTICLE
[10] F London, 141, 643, 1938; Vol.54, p.947, 1938.
[11] For a nice review on the same, see A Zee, Quantum Field Theory in a
Nutshell, 2nd Ed., Princeton University Press, Princeton, 2010.
[12] B DeMarco and D S Jin, Science, Vol.285, p.1703, 1999.
[13] M Massimi, Pauli’s exclusion principle: the origin and validation of a
scientific principle, Cambridge University Press, Cambridge, 2005.
[14] I G Macdonald, Symmetric Functions and Hall Polynomials, Clarendon,
Oxford, 1995.
[15] S Chaturvedi, Phys. Rev. E, Vol.54, p.1378, 1996;
A P Polychronakos, Phys. Lett. B, Vol.365, p.202, 1996;
S Chaturvedi and V Srinivasan, Phys. Lett A, Vol.224, p.249, 1997.
[16] P A M Dirac, The Principles of Quantum Mechanics, Chapter IX,
Oxford University Press, Oxford, 1967.
[17] A Sommerfeld, Z. Physik., Vol.47, p.1, 1928; F Bloch, Z. Physik.,
Vol.52, p.555, 1929.
[18] W Nernst, Nachr. Kgl. Ges. d. Wiss., Göttingen, Vol.6, p.1, 1906.
[19] J A Kok and W H Keesom, Physica, Vol.3, p.1035, 1936;
L M Roberts, Proc. Phys. Soc. Lond. B., Vol.70, p.744, 1957;
W H Lien and N E Phillips, Phys. Rev., Vol.133, A1370, 1964; see other
related (older!) articles of Keesom et al, e.g., Commun. Univ. Leiden.,
No.219(d), 1932; No.232(d), 1933, etc.
[20] The first mathematical calculation towards the justification of Nernst’s
hypothesis (which later was extended as the third law of thermody-
namics) was presented by A Einstein, Ann. Physik., Vol.22, p.180,
1907.
[21] N W Ashcroft and N D Mermin, Solid state physics, Harcourt, 1976;
C Kittel, Introduction to solid state physics, 7th Ed., John Wiley &
Sons, 1996.
[22] R H Fowler, Mon. Not. R. Astron. Soc., Vol.87, p.114, 1926. Address for Correspondence
[23] S Chandrasekhar, Astrophys. J., Vol.74, p.81, 1931; Mon. Not. R. S Chaturvedi
Astron. Soc., Vol.95, p.207, 1935. School of Physics
[24] W Pauli, Z. Physik, Vol.41, p.81, 1927. University of Hyderabad
[25] For a recent review on applications, particularly in atomic and C R Rao Road, Gachibowli
condensed matter physics, see S Giorgini, L P Pitaevskii, and S Hyderabad 500 046, India.
Stringari, Rev. Mod. Phys., Vol.80, p.1215, 2008. Email:scsp@[Link]
RESONANCE ¨ January 2014 61
