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Crystal Structure Problems and Solutions

The document provides a 10 question assignment on crystal structures and properties of materials. It includes questions testing knowledge of crystal systems, unit cells, Miller indices, planar densities, and volume calculations for FCC and BCC crystal structures. Detailed solutions are provided for each question involving calculations to determine lattice parameters, planar densities, volumes, and theoretical density and linear density values.

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Faryal Batool
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0% found this document useful (0 votes)
632 views8 pages

Crystal Structure Problems and Solutions

The document provides a 10 question assignment on crystal structures and properties of materials. It includes questions testing knowledge of crystal systems, unit cells, Miller indices, planar densities, and volume calculations for FCC and BCC crystal structures. Detailed solutions are provided for each question involving calculations to determine lattice parameters, planar densities, volumes, and theoretical density and linear density values.

Uploaded by

Faryal Batool
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Introduction to crystal elasticity and crystal plasticity

WEEK 1 Assignment
Module 1: Structure and properties of materials

1. The close packed direction of a BCC crystal is 1 Mark


(a)〈1 1 1〉 (b)〈1 1 0〉 (c)〈1 0 0〉 (d) 〈1 0 1〉
Ans :(a)

2. The stacking arrangement of FCC crystal structure is 1 Mark


(a) ABCABCABC… (b) ABABAB… (c) ABABCABA… (d) ABCABABC……
Ans :(a)

3. Sufficient ductility is observed in which of the following type of atomic bond?1 Mark
(a) metallic bond (b) covalent bond (c) ionic bond (d) van der Walls bond
Ans :(a)

4. What is the crystal system of Gypsum 1 Mark

(a) Cubic (b) Triclinic (c) Orthorhombic (d) Rhombohedral

Ans: (c)

[Link] is the Miller indices of a plane whose intercepts are at /2, , 2


in a simple cubic
unit cell.

(a) (4 2 1) (b) (2 2 4) (c) (1 2 1) (d) (2 1 2) 1 Mark

Ans: (a)

Detailed solution:

The given parameters are a/2, b, 2c

Its numeral parameters are ½, 1, 2


Miller indices are  ()


6.. Identify the miller indices for the corresponding directions
directions OA, OC, OD and OF from Figure
Fig
given below. 2 Mark

(a) [1 1 0] , [2 0 1] , [1 2 2] , [1 0 11]
(b) [1 1 1] , [2 2 1] , [1 1 2] , [1 0 11]
(c) [1 0 0] , [1 1 1] , [2 0 1]] , [1 1 2]
(d) [1 2 1] , [2 0 1] , [1 1 2] , [1 1 0]
Ans.(c)
7. The angle between [111] and112'( directions in cubic unit cell is
(a) 0° (b) 45° (c) 90° (d) 180° 2 Mark
Ans. (c)

8. An FCC structurehas
has a lattice parameter of 0.396 nm. Determine the planar density for
the (111) plane of FCC structure..2 Mark
(a) 0.1743 x 1015 points/cm2
(b)0.1473 x 1016points/cm2
(c)0.1473 x 1012 points/cm2
(d)0.2473 x 1016 points/cm2
Ans :(b)

Detailed solution:

For plane (1 1 1)
 !
!%&!# 
Planer density = =
"#$%&!#
%&!# )
√+
,-

9. Rhenium has an HCP crystal structure with atomic radius of 0.137 nm and c/a ratio as
1.615. Compute the volume of the unit cell for Rhenium. 2 Marks

(a) 0.0863 nm3 (b) 0.043 nm3 (c) 0.863 nm3 (d) 0.317 nm3

Ans: (a)

Detailed solution:

The volume of unit cell for HCP./ =


- 1232

The base area for HCP structure is6  √3

Given that,
= 1.615

And = 2


= 3.23

Again, given that  = 0.137 nm

∴./ = 3.23 × 0.137 nm × 6 × (0.137 nm) × √3 = <. <=>?@A?

10. Find the Interplanar spacing for a (1 2 1) plane in a simple cubic lattice whose lattice
constant is 0.412 nm. 2 Marks

(a) 0.01 nm (b) 0.11 nm (c) 0.14 nm (d) 0.16 nm

Ans: (d)

Detailed solution:

For a cubic lattice the interplanar distance is B = √$
C&  CD 

where, d = Interplanar distance


a = lattice parameter

(hkl) is the Miller indices of the plane

E.F GH
∴ B= = <. >=@A
√  C C 

11. How many atoms per square millimeter are there on (010) plane of lead? Assume the
interatomic distance to be 3.499×10-10 m. 2 Marks

(a) 2.04×1012 atoms/mm2 (b) 8.16×1012 atoms/mm2 (c) 16.32×1012 atoms/mm2

Ans: (b)

Detailed Solution:

Lead has FCC structure

The given interatomic distance = 3.499×10-10 m

∴ 2r = 3.499×10-10 m

If ‘a’ is the side of the square

∴√2 = 43

∴ a = 4.95×10-10 m

Now, area of (010) plane = a2 = (4.95×10-10)2 m2

For FCC, Number of atoms in (010) plane = 2


∴number of atoms per millimeter square =
([Link]× EL M ) H
= 8.16×1012 atoms/mm2
12. Molybdenum has a density of 10.2 × 103 kg/m3 with atomic weight 95.94 g/mol.
Calculate its atomic radius. 2 Marks

(a) 1.36 Å (b) 13.6 Å (c) 0.136 Å (d) 2.42 Å

Ans: (a)

Detailed solution

N-R
B2N1OPQ =
ST - U

N-R
V3U =
ST - B2N1OPQ

where, a = sides of unit cell

NY = Avogadro` s number = 6.023 × 10U

N = Nef23VgPVf1ONeNOP
2hh

R = PVfO
i2OjℎP

Molybdenum has BCC structure


Fl
∴ n = 2 anda = √U

F" U ×[Link]× EL+ op/Hqr


Thus,m n =
√U s.EU× E+× E.× E+op/H+

∴3 = 1.36 Å
13. What are the Miller indices of the plane in blue shade shown in in figure below? 2
Marks

(a) (1 0 1' 1) (b) (1' 0 1 1) (c)(0 1' 1 1) (d) (0 1 1' 1)

Ans: (a)

Solution:

a1 a2 a3 c

Intercepts 1 ∞ -1 1

Reciprocals 1/1 1/∞ -1/1 1/1

Reduction 1 0 -1 1

Miller Indices (1 0 1' 1)

What is the theoretical density (tuv ) and linear density ((twx ) along [110] of Cr. Assume
atomic weight of Cr to be 52 g/mol and atomic radius is 0.125 nm.
z
(a) tuv = 7.18 {+ ; twx = 11.28 nm}

z
(b) tuv = 3.59 {+ ; twx = 5.65nm}

z
(c) tuv = 14.36 {+ ; twx = 8nm}

z
(d) tuv = 8.17 ; twx = 16nm}
{+
Ans: (a)

Detailed solution:
~ !€! {#&& !T
Theoretical densitytuv = =
u&&€#€! {#&& ‚ƒ „

where. n = number of atoms/unit cell

A = atomic weight

VC = Volume of unit cell = a3 for cubic

NA = Avogadro’s number = 6.023×1023 atoms/mol

Cr is having BCC, thus n = 2

R = 0.125 nm

∴ = = 0.2887 nm
√U

Given, A = 52 g/mol;

×K z/&
∴tuv = (E.††‡)+ = ‹. =Œ/A?
GH+ ×s.EU× E+ ˆ‰qHŠ/Hqr

€Ž#"
Linear density twx =
! &#!z$ "#{ !#{"

2
twx = = . =@A}
√2 × 0.125 nm

15. Calculate the theoretical volume change in percentage accompanying a polymorphic


transformationin a pure metal from the FCC to BCC crystal structure. Assume the hard-
sphere atomicmodel and that there is no change in atomic volume before and after the
transformation. 2 Marks

(a) +8.8% (b) -0.88% (c) +4.42% (d) -0.44%

Ans: (a)

Detailed solution:


In FCC crystal structure unit cell =
√

In BCC crystal structure unit cell =
√U

The volume per atom of FCC crystal lattice

U
.‘// = = 5.66  U
4
The volume per atom of BCC crystal lattice

U
.’// = = 6.16  U
2
The change in volume associated with the transformation from the FCC to BCC crystal
structure, assuming no change in atomic radius, is

.’// −.‘// 6.16 U − 5.66 U


= ) , × 100% =  × 100% = +=. =%
Δ.
.‘// .‘// 5.66  U

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