22. 12. 8.

오후 1:39 IR Spectrum Table

제품명, 제품 번호, CAS 번호 등을 입력하십시오

IR Spectrum Table & Chart

IR Spectrum Table & Chart

The IR Spectrum Table is a chart for use during infrared spectroscopy. The table lists IR spectroscopy
frequency ranges, appearance of the vibration and absorptions for functional groups. There are two
tables grouped by frequency range and compound class.

IR SPECTRUM TABLE BY FREQUENCY RANGE

Use this table when you already know the frequency of your material. Find the frequency range in the
first column on the left side of the chart and corresponding values in adjacent columns.

If you need to find the frequency of a material go to the IR table by compound.

Frequency Absorption Appearance Group Compound Class Comments

Range (cm -1 )

4000- 3700- medium, O-H alcohol free

3000 3584 sharp stretching
cm -1

3550- strong, O-H alcohol intermolecular

3200 broad stretching bonded

3500 medium N-H primary amine

stretching

3400

3400- medium N-H aliphatic primary

3300 stretching amine

3330-
3250

3350- medium N-H secondary amine

3310 stretching

3300- strong, O-H carboxylic acid usually centered

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22. 12. 8. 오후 1:39 IR Spectrum Table

2500 broad stretching on 3000 cm -1

3200- weak, O-H alcohol intramolecular

2700 broad stretching bonded

3000- strong, N-H amine salt

2800 broad stretching

3000-
2500
cm -1

3000- 3333- strong, C-H alkyne

2500 3267 sharp stretching
-1
cm

3100- medium C-H alkene

3000 stretching

3000- medium C-H alkane

2840 stretching

2830- medium C-H aldehyde doublet

2695 stretching

2600- weak S-H thiol

2550 stretching

2400-
2000
cm -1

2400- 2349 strong O=C=O carbon dioxide

2000 stretching
cm -1

2275- strong, N=C=O isocyanate

2250 broad stretching

2260- weak CΞN nitrile

2222 stretching

2260- weak CΞC alkyne disubstituted

2190 stretching

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22. 12. 8. 오후 1:39 IR Spectrum Table

2175- strong S-CΞN thiocyanate

2140 stretching

2160- strong N=N=N azide

2120 stretching

2150 C=C=O ketene

stretching

2145- strong N=C=N carbodiimide

2120 stretching

2140- weak CΞC alkyne monosubstituted

2100 stretching

2140- strong N=C=S isothiocyanate

1990 stretching

2000- medium C=C=C allene

1900 stretching

2000 C=C=N ketenimine

stretching

2000-
1650
cm -1

2000- 2000- weak C-H aromatic overtone

1650 1650 bending compound
-1
cm

1870-
1540

1818 strong C=O anhydride

stretching

1750

1815- strong C=O acid halide

1785 stretching

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22. 12. 8. 오후 1:39 IR Spectrum Table

1800- strong C=O conjugated acid

1770 stretching halide

1775 strong C=O conjugated

stretching anhydride

1720

1770- strong C=O vinyl / phenyl

1780 stretching ester

1760 strong C=O carboxylic acid monomer

stretching

1750- strong C=O esters 6-membered

1735 stretching lactone

1750- strong C=O δ-lactone γ: 1770

1735 stretching

1745 strong C=O cyclopentanone

stretching

1740- strong C=O aldehyde

1720 stretching

1730- strong C=O α,β-unsaturated or formates

1715 stretching ester

1725- strong C=O aliphatic ketone or

1705 stretching cyclohexanone
or
cyclopentenone

1720- strong C=O carboxylic acid dimer

1706 stretching

1710- strong C=O conjugated acid dimer

1680 stretching

1710- strong C=O conjugated

1685 stretching aldehyde

1690 strong C=O primary amide free (associated:

stretching 1650)

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22. 12. 8. 오후 1:39 IR Spectrum Table

1690- medium C=N imine / oxime

1640 stretching

1685- strong C=O conjugated

1666 stretching ketone

1680 strong C=O secondary amide free (associated:

stretching 1640)

1680 strong C=O tertiary amide free (associated:

stretching 1630)

1650 strong C=O δ-lactam γ: 1750-1700 β:

stretching 1760-1730

1670-
1600
cm -1

1670- 1678- weak C=C alkene disubstituted

1600 1668 stretching (trans)
-1
cm

1675- weak C=C alkene trisubstituted

1665 stretching

1675- weak C=C alkene tetrasubstituted

1665 stretching

1662- medium C=C alkene disubstituted

1626 stretching (cis)

1658- medium C=C alkene vinylidene

1648 stretching

1650- medium C=C conjugated

1600 stretching alkene

1650- medium N-H amine

1580 bending

1650- medium C=C cyclic alkene

1566 stretching

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22. 12. 8. 오후 1:39 IR Spectrum Table

1648- strong C=C alkene monosubstituted

1638 stretching

1620- strong C=C α,β-unsaturated

1610 stretching ketone

1600-
1300
-1
cm

1600- 1550- strong N-O nitro compound

1300 1500 stretching
-1
cm

1372-
1290

1465 medium C-H alkane methylene group

bending

1450 medium C-H alkane methyl group

bending

1375

1390- medium C-H aldehyde

1380 bending

1385- medium C-H alkane gem dimethyl

1380 bending

1370-
1365

1400-
1000
cm -1

1400- 1440- medium O-H carboxylic acid

1000 1395 bending
-1
cm

1420- medium O-H alcohol

1330 bending

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22. 12. 8. 오후 1:39 IR Spectrum Table

1415- strong S=O sulfate

1380 stretching

1200-
1185

1410- strong S=O sulfonyl chloride

1380 stretching

1204-
1177

1400- strong C-F fluoro compound

1000 stretching

1390- medium O-H phenol

1310 bending

1372- strong S=O sulfonate

1335 stretching

1195-
1168

1370- strong S=O sulfonamide

1335 stretching

1170-
1155

1350- strong S=O sulfonic acid anhydrous

1342 stretching

1165- hydrate: 1230-

1150 1120

1350- strong S=O sulfone

1300 stretching

1160-
1120

1342- strong C-N aromatic amine

1266 stretching

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22. 12. 8. 오후 1:39 IR Spectrum Table

1310- strong C-O aromatic ester

1250 stretching

1275- strong C-O alkyl aryl ether

1200 stretching

1075-
1020

1250- medium C-N amine

1020 stretching

1225- strong C-O vinyl ether

1200 stretching

1075-
1020

1210- strong C-O ester

1163 stretching

1205- strong C-O tertiary alcohol

1124 stretching

1150- strong C-O aliphatic ether

1085 stretching

1124- strong C-O secondary

1087 stretching alcohol

1085- strong C-O primary alcohol

1050 stretching

1070- strong S=O sulfoxide

1030 stretching

1050- strong, CO-O- anhydride

1040 broad CO
stretching

1000-
-1
650 cm

1000- 995-985 strong C=C alkene monosubstituted

-1
650 cm bending

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22. 12. 8. 오후 1:39 IR Spectrum Table

915-905

980-960 strong C=C alkene disubstituted

bending (trans)

895-885 strong C=C alkene vinylidene

bending

850-550 strong C-Cl halo compound

stretching

840-790 medium C=C alkene trisubstituted

bending

730-665 strong C=C alkene disubstituted

bending (cis)

690-515 strong C-Br halo compound

stretching

600-500 strong C-I halo compound

stretching

900-700
cm -1

900-700 880 ± 20 strong C-H 1,2,4-

cm -1 bending trisubstituted

810 ± 20

880 ± 20 strong C-H 1,3-

bending disubstituted

780 ± 20

(700 ±
20)

810 ± 20 strong C-H 1,4-

bending disubstituted or

1,2,3,4-
tetrasubstituted

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22. 12. 8. 오후 1:39 IR Spectrum Table

780 ± 20 strong C-H 1,2,3-

bending trisubstituted

(700 ±
20)

755 ± 20 strong C-H 1,2-

bending disubstituted

750 ± 20 strong C-H monosubstituted

bending

700 ± 20 benzene
derivative

Table 1

IR TABLE BY COMPOUND CLASS

If you are looking up the absorption of a particular compound class, use this IR spectrum chart. If you
already know the frequency, use the IR frequency table above.

Group Absorption Appearance Comments

Compound Class
(cm -1 )

acid halide C=O 1815-1785 strong

stretching

alcohols O-H 3700-3584 medium, free

stretching sharp

O-H 3550-3200 strong, intermolecular bonded

stretching broad

O-H 3200-2700 weak, intramolecular bonded

stretching broad

O-H bending 1420-1330 medium

aldehyde C-H 2830-2695 medium doublet

stretching

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22. 12. 8. 오후 1:39 IR Spectrum Table

C=O 1740-1720 strong

stretching

C-H bending 1390-1380 medium

aliphatic ether C-O 1150-1085 strong

stretching

aliphatic ketone C=O 1725-1705 strong or cyclohexanone or

stretching cyclopentenone

aliphatic primary N-H 3400-3300 medium

amine stretching

alkane C-H 3000-2840 medium

stretching

C-H bending 1465 medium methylene group

C-H bending 1450 medium methyl group

C-H bending 1385-1380 medium gem dimethyl

C-H 3100-3000 medium

stretching

C=C 1678-1668 weak disubstituted (trans)

stretching

C=C 1675-1665 weak trisubstituted

stretching

C=C 1675-1665 weak tetrasubstituted

stretching

C=C 1662-1626 medium disubstituted (cis)

stretching

C=C 1658-1648 medium vinylidene

stretching

C=C 1648-1638 strong monosubstituted

stretching

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22. 12. 8. 오후 1:39 IR Spectrum Table

C=C bending 995-985 strong monosubstituted

C=C bending 980-960 strong disubstituted (trans)

C=C bending 895-885 strong vinylidene

C=C bending 840-790 medium trisubstituted

C=C bending 730-665 strong disubstituted (cis)

alkyl aryl ether C-O 1275-1200 strong

stretching

alkyne C-H 3333-3267 strong,

stretching sharp

CΞC 2260-2190 weak disubstituted

stretching

CΞC 2140-2100 weak monosubstituted

stretching

allene C=C=C 2000-1900 medium

stretching

amine N-H bending 1650-1580 medium

C-N 1250-1020 medium

stretching

amine salt N-H 3000-2800 strong,

stretching broad

anhydride C=O 1818 strong

stretching

CO-O-CO 1050-1040 strong,

stretching broad

aromatic amine C-N 1342-1266 strong

stretching

aromatic C-H bending 2000-1650 weak overtone

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22. 12. 8. 오후 1:39 IR Spectrum Table

compound

aromatic ester C-O 1310-1250 strong

stretching

azide N=N=N 2160-2120 strong

stretching

benzene derivative 700 ± 20

carbodiimide N=C=N 2145-2120 strong

stretching

carbon dioxide O=C=O 2349 strong

stretching

carboxylic acid O-H 3300-2500 strong, usually centered on

stretching broad 3000 cm -1

C=O 1760 strong monomer

stretching

C=O 1720-1706 strong dimer

stretching

O-H bending 1440-1395 medium

conjugated acid C=O 1710-1680 strong dimer

stretching

conjugated acid C=O 1800-1770 strong

halide stretching

conjugated C=O 1710-1685 strong

aldehyde stretching

conjugated alkene C=C 1650-1600 medium

stretching

conjugated C=O 1775 strong

anhydride stretching

conjugated ketone C=O 1685-1666 strong

stretching

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22. 12. 8. 오후 1:39 IR Spectrum Table

cyclic alkene C=C 1650-1566 medium

stretching

cyclopentanone C=O 1745 strong

stretching

ester C-O 1210-1163 strong

stretching

esters C=O 1750-1735 strong 6-membered lactone

stretching

fluoro compound C-F 1400-1000 strong

stretching

halo compound C-Cl 850-550 strong

stretching

C-Br 690-515 strong

stretching

C-I 600-500 strong

stretching

imine / oxime C=N 1690-1640 medium

stretching

isocyanate N=C=O 2275-2250 strong,

stretching broad

isothiocyanate N=C=S 2140-1990 strong

stretching

ketene C=C=O 2150

stretching

ketenimine C=C=N 2000

stretching

monosubstituted C-H bending 750 ± 20 strong

nitrile CΞN 2260-2222 weak

stretching

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22. 12. 8. 오후 1:39 IR Spectrum Table

nitro compound N-O 1550-1500 strong

stretching

none 3330-3250

none 1870-1540

none 1750

none 1720

none 1372-1290

none 1375

none 1370-1365

none 1200-1185

none 1204-1177

none 1195-1168

none 1170-1155

none 1165-1150 hydrate: 1230-1120

none 1160-1120

none 1075-1020

none 1075-1020

none 915-905

none 810 ± 20

none 780 ± 20

none (700 ± 20)

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22. 12. 8. 오후 1:39 IR Spectrum Table

none (700 ± 20)

phenol O-H bending 1390-1310 medium

primary alcohol C-O 1085-1050 strong

stretching

primary amide C=O 1690 strong free (associated: 1650)

stretching

N-H 3500 medium

stretching

secondary alcohol C-O 1124-1087 strong

stretching

secondary amide C=O 1680 strong free (associated: 1640)

stretching

secondary amine N-H 3350-3310 medium

stretching

sulfate S=O 1415-1380 strong

stretching

sulfonamide S=O 1370-1335 strong

stretching

sulfonate S=O 1372-1335 strong

stretching

sulfone S=O 1350-1300 strong

stretching

sulfonic acid S=O 1350-1342 strong anhydrous

stretching

sulfonyl chloride S=O 1410-1380 strong

stretching

sulfoxide S=O 1070-1030 strong

stretching

tertiary alcohol C-O 1205-1124 strong

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22. 12. 8. 오후 1:39 IR Spectrum Table

stretching

tertiary amide C=O 1680 strong free (associated: 1630)

stretching

thiocyanate S-CΞN 2175-2140 strong

stretching

thiol S-H 2600-2550 weak

stretching

vinyl / phenyl ester C=O 1770-1780 strong

stretching

vinyl ether C-O 1225-1200 strong

stretching

α,β-unsaturated C=O 1730-1715 strong or formates

ester stretching

α,β-unsaturated C=C 1620-1610 strong

ketone stretching

δ-lactam C=O 1650 strong γ: 1750-1700 β: 1760-

stretching 1730

δ-lactone C=O 1750-1735 strong γ: 1770

stretching

1,2,3,4-
tetrasubstituted

1,2,3- C-H bending 780 ± 20 strong

trisubstituted

C-H bending 880 ± 20 strong

1,2-disubstituted C-H bending 755 ± 20 strong

C-H bending 880 ± 20 strong

1,4-disubstituted C-H bending 810 ± 20 strong

or

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22. 12. 8. 오후 1:39 IR Spectrum Table

Table 2

HOW TO READ AN IR SPECTRUM TABLE

To use an IR spectrum table, first find the frequency or compound in the first column, depending on which
type of chart you are using. Then find the corresponding values for absorption, appearance and other
-1
attributes. The value for absorption is usually in cm .

Note that not all frequencies have a related compound.

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