" PROPERTY OF THE GOVERNMENT OF THE C OF TRINIDAD AND TOBAGO MINISTRY OF EDUCATION BOOK RENTAL PROGRAMME ) BISHOP ANSTEY HIGH SCHOOL ..- CARIBBEAN EXAMINATIONS COUNCIL ‘Test cope 002692 |MAYATUNE 2000 SECONDARY EDUCATION CERTIFICATE EXAMINATION CHEMISTRY Paper 02 - General Proficiency hours READ THE FOLLOWING DIRECTIONS CAREFULLY ‘You MUST use this answer booklet when responding tothe questions. Fo each quetin, wite your answer in the spuce provided and tur the answer booklet a the end ofthe exainaton. » Where appropriate, ALL WORKING MUST BE SHOWN inthis booklet . ‘There ae Five questions in this booklet, Atempt ALL questions Sette CODE OCFa ‘Using the graph paper provided on page 4, plot a graph of volume of hydrogen formed agtne volume of 0.2 mol dn hydrochloric acid added. (S marks) fi)_—_xplain the shape ofthe graph. (@ rks) CCaovite the number of mole of magnesium in 0.06 g of magnesium. Relative stomie mass of Mg = 24) mark) ing data from the graph, calculate the volume of 0.2 mel dn hydrochloric which would just disalve 0.06 g of magnesium. Calle: i) ‘Thenumber of moles of hydrochlsi acid used in () (i) above nnn ‘The umber of moles of hydrogen berated when all the magnesium has reacted (mole of «gas occupies 24d! a tp) marks) GO ON TO THE NEXT PAGE[No Zn proven Ph, AD" nay be preset. fodide solution were sed ‘inary Go ON TO THE NEXT PAGEaoe eo (The following report of practical exercise was seen (GEA ty a ree an aston nam School Bad Aneamen,Dileen anges cn combine frm compounds, One ich oman is Sage et nr cyl wee edn (0) Draw an appropriate diagram to show: (© Thearangement of electrons nan alom of EACH ofthe elements chlorine and fuerine marks) (i) The ype of Bonding which occurs in CIF Doyou expect CIF w have ahigh or low being ‘Analysis of sample of CIF shows that it consists of Fovml, but with efleret molar masses. Give apo potassium iodide. Gina) eee G0 ON 10 THE NEXT PAC GO ON TO THE NEXT PAGE(©) Based on he balanced equation you have writen in (d) on page 7, determine Figure 2 below shows a method fr preparing dy oxygen in the laboratory © thechangs in oxidation number tha the iodide ins undergo i) whether agusous chlorine is acting aan oxidizing or areducing agent. (i) souay ‘Ste the role of Sold Y nthe eset mmo Describe the est you could conduct to find ou ithe gas produced i oxyeen ~~ marks) GO ON TO THE NEXT PAGE© © 026227 2000 -10- ‘Give ONE reason fr collecting the oxygen as shown in Figure 20n page 9. — ‘Oxygen can react with metals and non-metals to form oxides. ac Wit bane sation a how how oygen reat with © stivm i) slp. mark) observe if water is added to atest tbe containing a sample of © wn further oberon could be made i few drops of bse Hama olan ech est ite in ) o ‘Suppose that anew meta were dtcovered with properties such ha jst below bara in Group I. In what way Would you expoct the ‘etl with oxygen to iff rom the esction beteesbarum and ox Give ONE reason for your answer. mars) ‘Total 15 marks of 56. One male of M wa ound to contin 8 (©) Catouate the number of moles of carbon atoms preset in one mole of M. mark) (i) Calle the number of moles of hydrogen aloms present in one melo of M, mark) (il) Deduce the metacuae formula of M. mark) GO ON TO THE NEXT PAGE3. ©) -M forme polymer under suit rn (@)Neanexet a diseront stractr isomers. Draw and name TWO of these isomers. (© 6 this polymer likely tobe an addition polymer or «condensation polymer? meri polymer show the sue reaction with bromine wate as M? Expl marks) ‘Total 1S marks gel (© M reacts with hydrogen in tho presence ofa suitable catalyst to give another en in the pr be catalyst o give anot ‘Wit atalanced chemical equition fr thi reaction. You should include the name ofa ‘Suitable tly in your equation. (0 Aiton ——_saatson cos) eas (We ecm ol moat of me ee da oe = (mark) © Theseuctue of M (©) Describe THREE important steps the stents should follow to obtain dy, hydated ‘ine sulphate crystal rom the ete, The aevctar of N it) The eaction between M and hydrogen (@ marks) 60 ON TO THE NEXT PAGE© Test cope 002693 FORM TP 2065 MAYIIUNE 2000 CARIBBEAN EXAMINATIONS COUNCIL ‘SECONDARY EDUCATION CERTIFICATE EXAMINATION (CHEMISTRY Paper 03 ~ General Proficeney thou In additionto thet hour, candidates are allowed a reading time ‘f10 minutes. Candidatesmay wrteduriagthe10-ninuteperiod. Candidates MUST answer THREE questlonson this paper. They MUST choose ONE trom Section I, ONE from Section Hand ONE. from Section 1. [All working MUST be shown for calculations. DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO ‘Copyright© 1999 Caribbean Examinations Coun gh reserve,ase “The largest renewable natural energy resource inthe word today ie glucose and its varius poly rer, such a starch and cellulose (@)—@_LetatactureD below cepresent the glocose molecule. D = HO—x—on ‘Show how THREE ofthese molecules canbe inked together toillusate the ype ‘of polymer linkage found in polysaccharides. Gi) Tewarsuggesed tht monomer ofthe ype below could aso be used with hose cof type D to produce plymersvinular to polysaccharides. Is hia valid sagas ‘on? Give treason for your answer B=X—0H (8) ae, tether moves is ery sob in water. Suen eon (marks) (©) Describe how yu an prepare sample of pureetana, sting from stable carbohydrate. ‘You should clue in your answer “The raw materials weed = The conditions forthe reactions A ceayng ofthe apparatus that ould be used 1 obtains puter sample of ethanol ‘om the reaction mixture marks) (©) Bthanol undergoes wide vaiety of reactions, 1) Draw structures for compounds FG and H inthe reaction scheme below. “The elaine molar mas of enol is 46) (marks) ‘Total 20 marks i G0 ON TO THE NEXT PAGE 002693 2000an ise acorn aaa si SECTION I Answer ON question fromthe eon, ‘Answer ONE question from ths section. 5. The following isan exact fom recent newspaper atl in «Caicom county. HOW MANY MORE MUST DIE? “,., Hospital have reported yet another death of six Polysaccharides canbe convert 0 une Un nthe aorwory year-old child from lead poisoning. This brings to five for the cr, the numberof deaths fom this cause. A further sx children Compare acid hy drolyas off A a be von ae ‘ih cathy date aiention I the aly (ONE sally wo + ae now hospitalized from suspected lead poisoning © [Name TWO possible source af ea pation oy (© Ieterostionl agencies onl standard for pol oar aa wy recommendation. (Ablaned olution this pro ‘int 20 marks 60 ON 10 THK NeXT PAGE GO ON TO THE NEXT PAGE. .0026931F 2000‘test cove 002692 ‘MAYUNE 2001 ‘Thr ue alg number fang senate mt oy, Soo ee ome oor esi nvr nea ee FORM TP 2165 a CARIBBEAN EXAMINATIONS COUNCIL SECONDARY EDUCATION CERTIFICATE EXAMINATION (2) Select any TWO of he following cleaning sgens (CHEMISTRY Paper 02 ~ General Proficiency 1 bows READ THE FOLLOWING DIRECTIONS CAREFULLY 1. You MUST use this answer booklet when respoading tothe questions. For each question, Veit your answer in the space provided and retur the answer booklet atthe end of the ‘where appropriate, ALL. WORKING MUST BE SHOWN in this booklet. “There ar five questions in thisbooklet, Axempt ALL questions. DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO ‘Copyright © 2000 Caribbean Examinations Coun All ights reserved. “On082/F 2001ead ‘You should NOT spend more than 30 minutes on Question 1, a 7 < oa [igure 1. pit meter readings when various volumes of sodium hydroxide are added (0 ae 1X 200 em of hydrochloric ald. GO ON TO THE NEXT PAGE ‘ooneo2i" 2001Reading Tepresnts the pH of 20.0 em? of 0.01 ml dn hydrochloric fxperiment. Readings If X represent the pH readings nydoxide were added to the bydochl Solution added ae indicated in Figure 1 on p (© —@ _ Inthespaze Below, constr ble and record ‘th te comesponding volumes of scum hydroxide ad (026920 2001 ( Saris) Ct mare GO ON TO THE NEXT PAGEeee ae Gv) Wiite« balanced equation for the reaction © Acsudent conducted » numberof tests on an aquoous solution of Compound X. The Inydochloric acid nclude stat Detwen sodium hyéronide and ‘observations made are recorded onthe table below You are requived to il in the code inferences tht could be made base onthe observations recorded. Tnferences [Brown fumes evolve, armed mai blue ima ed ro, | Whit precipitate soluble In excess | Wie pesipinte soluble in exces | [The potassium manganate(VID | eoution was not cecolourzed(© Incorect statement 3: xHSO, 50, © > ‘Compounds C and D are both normal alte Reason: 6) Write an equation forthe reaction betwen strontium and oxygen “(2maris) GO ON TO THE NEXT PAGEew eae ©) How wouldtbereacton between strontium adie Be al sweetener, is the methyl exter ofa compound formed from two Soiree ae desta seisconpare 4 Te aun Natasoneet. isthe methyl eter of » compo (On the structure of Nutra-sweet, clrle and label the amide and the ester fonction groups. (2marks) i) Draw'the stractares ofthe TWO produets formed when te amide bond youhave ‘ented in (2 (above is hydrolysed.<4 sticcnenanl HOW In Nutrweweet Based on ese poe postiolechemal mostly occur wien wate ig auido cake ingredient con lum hydrogen carbonate and Nuee ‘see. Give a reason foryoun Sma) ted eee! scare comtaing fa guose and fucone Using HOO torres raw a stuetre forthe otc and HO-Y-OH torepresentructoce, lecule. CCrmacis) Sr etecton in which sucrose is formed fom glucose and vctsesnexampe “sconicsaton ow edition eacdce? Gia ratonte pon on Cimasis) ‘Total 14 marks % rmbt ions rong heed it deompotst eck trop dori nd oxygen © Witten esto forte ston fen ad tran Tanks) 9 How would you know tt trogen die gen off in te reacton? CTmant GO ON TO THE NEXT PAGE 026021 2001 on page 14, determine the change in oxidation Cree ‘Show how you srvedt yur answer. number of nitrogen d — a ay Cate value of nsopen ois that wold be give off com \empersure and pessore when 31 go ‘no more esetion took place cleo gas ose soe 0f 240 de? [Peirce arent Smarts) Hw do the products obisned upon heating lead nitrate differ from those obtained upon heating sot ite (Fmarig) (© @ _Bxplain why meta aifoys are oflen used in place of he pre meas, 2a) (i) Nome amet alloy of esd and state its use. Tara) ‘Total marks 20927 2001test cope 002693 FORM TP 2166 MAY AUNE 2001 CARIBBEAN EXAMINATIONS COUNCIL SECONDARY EDUCATION CERTIFICATE, EXAMINATION CHEMISTRY Paper 03 General Proficiency 1 hour 30 MAY 2001 (am) 48 addtionto the hour, candidates are allowed & Fendi ine ‘9F10 minutes. Writing may begin during th HOsminule pariod, Candidates MUST answer THREE auetonson he paper, Tey MUST choise ONE rom Senn A ONE alo a ONE etn All working MUST be shown for calcula, ae SECTION A. Answer ONE question from this section. Hygogen peroxide slowly decomposes on standing according tthe following equation: 2H0, > 2,040, “The reaction i catalysed inthe presence of Fe" ons. [A stodent is euized tocar out sn experiment o determine the heat change which takes place when hydrogen peroxides decomposed inthe presence of Fens. Sheis provided ‘wih the following mateials and equipment = 50m? ofa solution of 1.0 mold hydrogen peroxide = 10.8? oF an aqueous solaton containing FO" ton ‘A thermometer A plece of aluminum fol Atnarks) “The following temperatures were recorded when the experiment in above was ing the volumes of solutions specified. (Caentate he beat change (Heat change = beat capacity ofthe solution x mas ofthe solution x change in temperature) ‘Assun tht the hat capacity ofthe solution is 425g" C*. State alloter assumptions youray have madein yourcalolaionsin eth eat change forthe decomposition From your answerin(b) above calculate the e rst of I mole af hydrogen peroxide ‘marks) GO ON TO THE NEXT PAGEa 4s “The renal obteined bythe students forthe experimantin(b)on page 3 are shown om the ‘raph below. The volumes ofthe gas piven were measured at room temperature and pressure © © Bamdontbe noonaton . rein ( on page 2th deconpostion ftom peroxide an exothermic or end i€ process? Mlustrate your wan afl ald egypt gran o (9) Would you expect the heat chan a change forthe reaction wo be diferent inthe pressnce ‘orabeenc of he ctalyet? Give a ° fhe catalyst? Give a reason for your answer ‘Volume a, fm? heated ) Wouls ane {ettion ney fr te aon let yh ress ote lst your ansneron he nego dagram seve above. Label the catalysed resction 2 amare bee eernin (6marka) ‘Total 20 marks ‘State FOUR factors hat can influ the ate of rection (A rmarks) A post atom oo 2a ncn oieerpnmetteeesocamon andrea lag oe ie ee tmenteom eratwmntar AE owing esse ee arama Draw a flly labeled diagram of the apparatus the students may have used in thir "eee ites (Using te equaton fr te decomposition of hyogen peroxide andthe data rom the graph caealate the mass of hyérogenpevoide tht would have decomposed ster minutes (CL mole ofa ga oceupies volume of 24.0 din at tp; We 10-16) fea with time, Use he 3 inate and 6 minute date points nie gph to show whether the stden’ data soporte statment ee Comat) w (@ Mea sketch of te graph in (shove in your answer booklet, On tis skate, daw the ‘hapes ef he curve expected i this eatin Were cated ut 10°C abowe room temperature sing (0.3 mol dn? hydrogen peroxide Give ONE reason for your answer in BACH ene (Amarts) ‘Total 20 marks 002603 2001 60 ON To THE NEXT PAGE G0 ON TO THE NEXT PAGE. (0026931 2001 \ 'a 026937 2001 as SECTION B ‘Answer ONE question from this section isand fas rewsedin the manufctrof saps, They ae exes aidconsi fone chan organic acids and glycerol o Briel describe how you would prepare asa ‘Lette smctre of fa be represented by the following general formula R-C-o-R i ‘rte a balanced chemical equation o represent the formation ofa sep fom this ii) Glycerol abyproductin the manafacture of sop, ssl for this The struture of glyecro is piven below ater. Givearearon cH, — cH = cH, ea on on bn Tears) (©) A tong-ehain unsaturated fut acid ean be represented bythe following srocture. RCH = CHICH), COOH © State how you would for the presence of unsaturation inthis compound, Inelude chemical equa your answer (8) Show, by means of suitable chemical equations, how the carbon ~carbon double bond in this compound would react. = hydrogen ‘You shold sae the conditions forthe reetions in EACH esse. (Smarks) GO ON To THE NEXT PAGE @ Ce Anil or fat cam be represented by de structure shown below. R-CH=CH (CH), CO,-CH, tobe polymers. Suggest areason for this. jn ofa polymer and state the characters old possess to rng about polymerization, (mares) ‘Total 20 marks extraction of ion fom is re. Include Outing the main steps in EE chemical equations in your answer, Basedonthereartin taking plac inthe bl often that can be obtained from [Relative atomic mass: Fe = 56: (13 mares) mth ors. (mare) “ton and see However they ae Do you agree (marie) ‘Total 20 mari Go ON TO THE NEXT PAGEa SECTION € Answer ONE question from tis section. Atousowiteobsrvedhaa whit compound, Xs formed onth lecre Kettle. Her son sud that he would remove te whe lore wid, ran of ONE stance at caves ero aries n wate then and formula for Compound X.. 4 = plain how the whitecompound, X. Was probably formed, (Include an equation sth tate symbols) Ci marks) ch sodium carbonate can be use 6 remove permanent hazdees from Write te chemical femal or elude a onic equation to (omarks) 60 ON TO THE NEXT PAGE © a6 “Two packets of soupless detergents were examined athe supermarket, One label sa “enzymes adda” the other suid, "with bleach.” Define the tern ‘soupless detergent and explain its leaning action, ‘Suggest the function ofan enzyme ina deerpen ‘What advice would you give 10 householder about the use of detergents with bleach added? (8maris) ‘The following label was een on a shi. Give te name ofa dy cleaning solvent. What do you understand by the term ‘dry cleaning”? o “Many brands of toothpaste consi sodium bicarbonate. pes of ngs found in tothpaste, lnctudng sodium bicarbonate a componentin some beads your reton with Blance oni uation ialuding state Tarts) ‘Total 20 marks END OF TEST 269372001Test cope 00265 FORM TP 2270 CARIBBEAN EXAMINATIONS COUNCIL MAYAUNE: ‘SECONDARY EDUCATION CERTIFICATE EXAMINATION CHEMISTRY Paper 02 ~ General Proficieney hours READ THE FOLLOWING DIRECTIONS CAREFULLY Fou MUST se this answer bookie wheneqonding 1th questions. For EACH aueson write owt anwerin te space provided and ren the answer booklet ae end of ene ere ‘Mere sppropcst, ALL WORKING MUST BE SHOWN in this ookle. ‘The ws of non-programmabl calculators is permite, ‘Thee are Five questions inthis booklet, Attempt ALL questions DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO po so Copytigh © 1997 Caribbean Examinations Counc, ‘Allright reserved. 026520 2002 ae on this question. ‘You should NOT spend more than 30 mliutes on this que eseton taking pace inthe ask Wilt an onic equation forthe a ‘What is the volume of hydrogen collects in the syringe? colle tp? any mes of hyogen were collected at nol of ty ge ac iphar ven of 24) (2a) How many moles of magacsium were used up? (Cmane) GO ON TO THE NEXT PAGE o2arar 2002ow wo dew peat collec ajar of hydrogen. Selec om the agrams ‘slow by ccing X. Yor Z th appara Jou ould oe To dying the as ite sulphur eid y (CLmark ) Select from the digrams below by cies ‘seo collet the gus after twas dae tf (mark ) PQ Or, the spparatus you would mM idem M 3em!M ru dent [Bema 8ewM Ee Atel Ew Shen oon aon Soon Eo 02 ma GO ON TO THE NEXT PAGE seus GO ON To THE NEXT PAGE —oS ‘Read ofthe height ofthe precipitate present in EA ee In hich teat ate ae the ont of nether solution M noe in excess? nillimete and recorditon the ble below thane (Cima) in Test be 6 om page 4 [Name the ions present inthe SOLUTION in Test uke 6 on page Use the informa » » Use the answer ® ‘lo the sls onthe grid below. Draw the line of best fi ‘Volume of M added en? (6 marks) 0 ON To THE NEXT PAGE, 026001 2002 (CSimarks) Figure 2 on page 4 to complet he statement below: the equation for the reaction taking place (C2marks) “Total 390 marks GO ON TO THE NEXT PAGEa = ©) Comet Table below. Yousre NOT requedto en the species, Use the symbol X, ¥ and in wing the Formule ofthe elo, Species [Atomic | ass amber of Namber of Element | Element 6 (©) Mlstraeasing an xampe, what you undestnd by the em isotope Polymer A can be represented by the forma +X -O-X-0-X and ean be converted ‘o simple sugars. Polymer A gives a blue black colour with od (@) State he name of Polymer A and te group of compounds to which belongs 2imark) © Give te name and molecular formula ofa simple suger that can be formed fom Polymer A. 2 mars) 0 ON TO THE NEXT PAGE © ® © co rer Aon asimple see State ONE difeence in physical properties botween Poymer A and a simple sug [Bepain how a simple sugar an be usd to supply energy inthe human body. clude a chemical equation o represent the ection in your answer, Chrmaci) Toaminure of Foyer Ain wat ces ey ric cid was aed andshe mince boiled, A few drops of iodine were then added, What weald you = canoes Sinpesgmarsin sts Wtvodyvepseresinttn : loride were warmed with a simple sugar and some aqueous sodi ideas Sica Wa TWO legit ear Yor ene ‘Total 1S mares‘Anunkrown mass of volume of gasevelved asshown onthe geaph ‘uonate Relaive atomic mas Ca = 40; C= 120 Tol of ny gu has a volume of 24 an Vout G coves PETE 1s0| ao] sor oo so 4d q Figures @ ‘Write aalanced cquation forthe reaton between hyrochlvie acd ani marble chips, ‘Use data fom the graph oder: (©The ttl volume of erbon dione evolved The massofcabon dione evolved (Cima) 00 ON TO THE NEXT PAGE ° © o 10- y ii) The mas of male chips used (Zama) iow would you show tht the gas produced is cabon oxi? CDrmats) ‘Beplain why niticacidand NOT culphoriealdcould be wed toreplce the hydrochloric faci bed inthe investigation, (mart) tum carbonate powder in ‘Suppose that this experiment were tobe repeated using clei carbonate powder in ple of marble chips would you expect tobe completed in x shorter or longs tme! Explain youranswer, (2manis) ‘Total 15 marks G0 ON TO THE NEXT PAGEs 7 ‘igre 40 dagram of spars tha could be oe to prepa dy ample fam X isa mixture of two compounds. Name them, (CTmaris) ‘Wele an equation to show how the compounds in X react to form anion. © Give he name ofa compoune that could be CT ma) 1) Why is itposibie to collec armonia ung the method shown? ‘Cimark ) Sate te conditions necessary forthe production of nec acid from amon, Farad (0 ON To THE NEXT PAGE sonia ga collected were bubbled change oak place. CF aria) sin which the manufactre of ammonia in indus les from in Figure don page 1. (Smarks) otal 18 marksFORM TP 2271 CARIBBEAN EXAMINATIONS COUNCIL SECONDARY EDUCATION CERTIFICATE EXAMINATION CHEMISTRY L @ Paper 03 ~ General Proficiency Thou JUNE 200 Gm) In addition to the 1 hour cand ‘of 10 minutes, Writing mey be ae allowed. reading time ing the 10-minute period, Candidates MUST answer THREE questions on this paper. ‘They ONE from Section 1 and ONE All working MUST be shown for calculations. ‘The use of non-programmabe DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD 10 DO SO —.) eof (Copyright© 1997 Cartbean Examinations Counc Alleights reseed on2s9a/e 2002 2 SECTION ONE Answer ONE. question from this sttion. ‘You were asked to prepare 4 pure dey sample of hydrated copper QD suhate “Seale nating wih copper) oxi and 100 en sulphuric aid of concentration 1 mol da sul aera apes, ou would propa hs © ree fit nena foe econ ering, Clit ma of Sper alpnne enue (C250, 5H,0) you would * fo obtain from (Relave tomic mast) Cu =G68; $= 32: O= 16 H=1) G_Thesaply of cope nu. Te teacher sugested that copper ox Copper tate (deliquessent™ compound) ‘copper carbonate (a fn “Whichof the theae two compounds ir more suitable forthe preparation feopper ‘onde? Give ONE reason for your choice ‘Write balanced equation fr the stion of heaton 3 copper I) nitrate ad 1 copper I carbonate, he atmosphere and ‘US marks) copper ana ci) few drops of sodium ‘What would you expect observe with EACH fsate? (2marks) ‘Total'20 marke Go ON TO THE NEXT PAGE.4 os te iydeony leat, glee he steps that you would ake prepare? dm" of 0.1 mol dm hydeochori 4, Fats are esters derived from long chun erganic acids and the witydroxy seal acid, saning with 8.0 mol dew” hyerochloric acid and using sandard bora CGiycera haste following suoctre: . Hc-0H CCrtsin insoluble sats are formed when test t identify anions are earied out i : the laboratory ae i HC-OH Giycerol tw represent the ation which is expected to tke following advice o how to dispose ‘Write balanced equation rep tic nr adly contaminated and no longer place when glycerol eats completely with EACH of the fliowins: it down the concrete drain leading fom the laboratory, when there isa heavy tran ar pcs ad 1b) Along chin onan a of formas, R’COOH Give your view on this advice with THREE supporting reasons Desde what you would expect oobterve when yea is eed with tassum chromate soliton. Give a reason for your answer. ‘Suggest snotber way of disposing af concentrate ulphure sd (marks) saciid pe i Total 29 marks ease ee id COOH Seat secTion Two pvctes na oe Eo “ ‘hnever ONE guint ti seta, a eer ara 7c peintof te cn pean eee a ee ee ee Deseo owen epee nom sat el cae i een Set a Nir Sr mandir, Te wan Sue TWO vay inah icing ies onsen a need equation forthe production of methane foi hy droge ‘Total 20 marks 9 wate, including the e. Writ the relovantelet | Giagram of the apparatus ued o cary out his process) GD Suggest TWO ways tha the astronauts could make use ofthe products of the ‘lectolysis to ensure their safe etn to Eath, (a marks) ‘Tae we of miclear ful for space lights has ben ued out in he past. Suggest TWO. sMdvantges and TWO disadvantages of using nuclear ful for he Mars jourty. (CAimarks) ‘Total 20 marks G0 ON TO THE NEXT PAGEoon 2002 Be SECTION THREE, Answer ONE question from this retin, Paints fibre, lass and ys are some ofthe common mails fund in and sound sae generally composed ofa slid and a quid, Give the ame and chemical formula of sold used in paint. (Give the name of ONE chemical used as aig an oil-based pint anc used in a emulsion, (Amarks) {iv th name of ONE vegeabie fe and ONE animal be used in king Draw TWO digrans net east prt of te chemi! seuce of a ‘exceed hero eps tof cme seo of ag i) State ONE important property ofthis typ its mujer use. and relate this propery to amare) ‘Total 20 marks 60 ON TO THE NEXT PAGE Pes mes that aze essential for healthy plant growih. This question ‘There ae many substan nresses some of thers, ‘Give te names and chemical symbols of FOUR important lement eset for ie plant growth. For any TWO of the elements named, idenify ONE source ONE elfoct ofits decency sow eps pct ofthe Nirgen Cycle in ate. See othe aes of © Flore NP Spans armed ave eo aed ye tes A, 8, Dans A ‘ic aid igure tsking place at A.B and E. ‘Waite the amos of he types of chemical eat ‘Write the name and chemical formula of Compoand C. ud that in Box D. [Name the typ of compound that shoud e placed ass o ded to soils to inezease the pl and reduce the problems caused bya ol, lao cause nittogen abe lst fom the sol State ONE problem associated with cid sci Explain ow the addition of time can increase the pH of an acid rom the sil ime can ease sitrogen te lost ‘Suggest ONE way in which i rose am {oelue a balanced fone equation) ‘yicoponie an alternative method of growing crop, bat here are problems linked wits eet TWO sch problems and suggest ONE Way whihanatiemt oul mae to yohve ONE ofthese problems aks) "Total 20 marks END OF TESTresr cope 0026 FORM TP 2362 cree CARIBBEAN EXAMINATIONS COUNCIL SECONDARY EDUCATION CERTIFICATE EXAMINATION ‘CHEMISTRY Paper 02~ General Proficiency READ THE FOLLOWING DIRECTIONS CAREFULLY ‘There are fve questions inthis hooklet, Answer ALL questions insner booklet when responding to the questions. For each question, your answer inthe space provided and return the ansiner booklet at the end of the examination. 3. Where appropriate, ALL WORKING MUST BE SHOWN inthis booket, Do NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO ‘Copytigh © 2002 Caribbean Examinations Counll All righs reserved on2¢921F 203 Do NOT spend more than 30 Answer ALL questions mine the heat of combustion of cand operas shown Figure | below: canto ae A Figure. Apparatus for combustion of candle wax Procedure: 0026921" 2003, weighed empty, then a known volume of water was “The conical ask with its content was clamped and then encased by can 25 sown in Figure ental temperature ofthe water i he flak was recorded x were weighed and placed direily under the enclosed bye ci “The cand “The cane ae the watchglase were allowed 10 cool and then re-weighed sults for the moses of candle and wate ed, ad the observed rapist waerare shows negra I~ V1 of Figure 2.0 ag 3 G0 ON TO THE NEXT PAGEreadings shown in Figure 2 on page 3. (@)Complece Table | below "TABLE 1: READINGS FROM FIGURE 2 ‘Mae of conieal ask and water (6) om > | » setae Padme watehglass watehpiass > Cima) Sz ° Figure 2. Results of Experiment : Comet) or {THE NEXT PAG: ‘THE NEXT PAGE ouneo2i 2003 {0 ON TO THE NEXT PAGE Eeeww 026x203 +s ‘Why was the experiment carried ut with the corical ask enclosed in aca Cart, fl ltlled every moi gran o show the beat of omuston, sande wax, asiuming that carbon dioxide and water ae the ONL are wa a the ONLY prod (2marts) G0 ON TO THE NEXT PAGE ‘The gases evolve’ bubbled into aqus calcium hydroxide, -Avwhte precipita is formed Equation required here Gy Bis divided into TWO coe ad wed Tandy ow “Thereisvigorouseftervescence Tonic equation required here ‘A green precipitate, insoluble cheess aqueous sodium hyde, formed. Tonic equation required hee ow Brown fumes are evolved formed. Ablue greens Camas) GO ON TO THE NEXT PAGE||§ Walt ih ill i I ike a Bay =: i Hy oa Me Hie | 1 a HHons92r 2008 non-metal exh ns andro ai lysical and chemical propertos. Site TW EACH of te following properties; 2) Physical propecies Gi) Chemical properties Differences in physical properties: i (marks) Differences in chemical propesties 1 (marks) ‘The elctone contigraion of Which ONE of thes to clome I, ile that ofehorine i 2, 8,7 ‘An oxidising agent. ‘A reducing agent ‘Beplain your answer (Aimar) G0 ON TO THE NEXT PAGE 0 the metal inthe -to way sian of meus decompose degends onthe postion of he mel reactivity series ‘th the use of balanced equations, lusts this statement By the NaNO, and Cu NO, section of heat on Heaton NaNO, Heaton Cu (NO,), (Ama) sect sels. Figur 4 below shows te poston of three elements in he rast Mg 8 Decrease in eatvity co ‘rigore 4. Portion of selected elements in the reativity series : would you slet usd ONLY onthe position in thereat series, whic element would Parte in making containers o sore aii fut juices ‘Expin your answer G0 ON TO THE NEXT PAGEa tot could be vied to ditingsish between compounits © re wae my changes ha coeur ad wre a (Describe and. Yo Maton forthe action eecuing Reagent Changes expected C¥marks) (eso: by mem of nom how compound Ceanbe anv See eul indicate the ety be wed ©) © Define he em ‘store ismecam' : (linac) A ee water? plain your answer (i) Draw AND name a strctral isomer of. isomer of compound C; (Amari) G0 ON TO THE NEXT PAGE Go ON TO THE NEXT PAGE‘Students were asked s mmber of questions based on thon given in Table 2. TABLE 2: PROPERTIES OF SOME METALS Reactivity with reacts vigorously with cold water ‘The following statements wer taken from one INCORRECT. ‘You should sate why the sa where required (© INCORRECT STATEMENT: G0 ON TO THE NEXT PAGE Sse (ii) INCORRECT STATEMENT: : combines with non-metal sie it Metal fms an he pe C™ whem tab 1) Explain why statement is incomes ‘Bxplain why statement is incomes: G0 ON TO THE NEXT PAGE“TADLE.3: SOME PHYSICAL PROPERTIES OF MAGNESIUM, IODINE, CHLORINE ement | Melting Point /°C | Hectreat Physical State Conduetvity Coniscor Correct statement: NO ANSWER REQUIRED eh Sungesta posible way of storing metal A, [Non eondvetor Non-conductor jer tan ha oF fod, alt Go oN To THE NEXT PAGE G0 ON TO THE NEXT PAGEae (©) Chlorine and iodine ar inthe sme group ofthe period te diferent at rom temperature. Etpain this differen (©) Magnesium combines wit chlorine to form magnestm chloride, 1 Whutgpe of bonding would you expectto combi What ype of bonding would you expect tobe onned when magesm ma (Gy wing a suine dagen, show how thse two element “Magnesium chloride. ae (3man © ‘Explain why magnesium chlovde conducts electricity when molten but NOT when sl Ciara) 60 ON TO THE NEXT PAGE te Ty combi jn alee bt ten tC 7of epee be cm a ey es nope ortondng a tne monte, Hh veers sanbe dap typeof ton Bonding diagram:Tesrcope 002693) FORM TP 2363 MAYAUNE 2008 CARIBBEAN EXAMINATIONS CoUNCIL SECONDARY EDUCATION CERTIFICATE, EXAMINATION CHEMISTRY Paper 03 ~ General Proficiency Thou ‘2 FUNB2008 fam) 0 the hour, candidates ar silomed 8 reading time es Writing may begin during the 10-minute period. READ THE FOLLOWING DIRECTIONS CAREFULLY IE questions on this paper. Chose ONE from and ONE from Section All working MUST be shown for eaeulations. ‘The use of non-programmable calculators is llowed. DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO sO. ——_—____*~*r?”;;, Coppiene B ee ny E topelymer of) Dem Figure 3. Reactions of C,H,011 (GW the fly delay sracuee fr the Compound C:H,0H shown as Ais gue (6) White the IUPAC name forthe scien (2) above (b) Witte sre of EACH oft fllowing compounds ean equation to support your answs, Equation fie (darks) (60 ON TO THE NEXT PAGE G0 ON TO THE NEXT PAGE r2ian20r 208Dest areacton net fhe presaect he fuction go ies non ope 9. ung he owing ends senna Compound C in Figure 3 undergoes pslymerzaon with othr molecsles of © (© Sethe typ of polymerization which ecu ‘Draw the pal suc of he polymer, F, show the repeats eit ‘The ection cecing in the conversion of At i appli in he ester G0 ON TO THE NEXT PAGE. 4 Figue 4 shows implied digrm of the cll wd forthe elestolys of molten soar ‘hd o prac sim ad eri. Figure Simplified cal forthe sectrlyt of molten sodiom horde ‘Why men sodium chide rae ha oid sodium cleride weed the ® dectsyte! (69 Weenie eusions fr the eactionsecurng at EACH a Cate: 7 emacs) Celt the quay of sodium wish wil be deposed when 10 amperes of crak ‘Se ped hap elect eal or 2 oer [RSS eisiaceuae » marks) (G0 ON TO THE NEXT PAGE oxar2020 2004(2) State TWO use to which be chlorine geerte jn Figure 4 cane pat ravamare 2004 ‘@maris) ow does the produ ofthe lel of mates sodium clone fom ‘ha of ce? scala : ‘imate ‘plain vty ding the clecoyss of bine, he electrolyte soliton gedually ecomes bal, marks) ‘Total 15 marks GO ON TO THE NEXT PAGE @ 2 Define EACH ofthe flowing terms: xotbemis ston: Endotermi stn marks rata 2004 Gate) raw lly aba eae pote agama ist our nsw shove marke) Ste THREE tats which fest the rt of eton, Gimart) 60 ON To THE NEXT PAGEu rest cove 01212030 FORM TP 2004060 [MAYHUNE 2008 CARIBBEAN EXAMINATIONS COUNCIL ‘SECONDARY EDUCATION CERTIFICATE EXAMINATION CHEMISTRY Paper 03 — General Proficiency how (i>) Consider the following reversible action: Naw + 3H(e) > 2NHeD CAN im) towing data ae osined by 9 sade camying out & eat of MUICL used = 50 mL 1 MN3OH med = SD peratures ofthe soltiens = 28.0°C tro slton wen te NaOH solton i aded othe HCI soluion = [READ THLE FOLLOWING DIRECTIONS CAREFULLY 1. Candidates MUST anower THREE. questions on tis paper. Choose ONE from ‘Ssctlon A ONE frm Seton B and ONE fro Section 2. Allworking MUST beshowa fr ealuations. 3 The ws of non-programmablecaoultors i permite. that lofsolaion = Ug z ‘Sma “Tota 13 mark {L YOU ARE TOLD TO DO SO Be NOT TURN THIS PAGE Ur END OF TESTSECTION A “Answer ONE question from this setion. ntich of two besker he hsp samples of an asi alt Define tho tre “di sl! ad nora « (i) Suggest simple et the technician can use 0 stings (©) Stsing wih LM H,S0, and 1M NaOH a seagent,daeribe the procedure the tetnician cn eto prepare dry samples of EACH ofthe fllowing rosin tan consist of he funder particles which [Nae the THREE fundameotl prices present in am som and state the ‘simuris) Properties of EACH parce w ich ofthese purtls the chemical propeics of G0 ON TO THE NEXT PAGE 01212030 2008 3. rss of ere een (Tre fallowing ars ction aod nix Draw Ite digrsto sow EACH ofthe following fests of he fdas nthe tro atm of len: amber Region mares Armangement “The we of Avo ‘he number mele © Relative Atomis Mass of Fe = 55 ‘Suis mde the follwing observations wile spending the weekend a her grand oer shame. Olsevalion V. Ste ors sou forthe sca of ber perfume Inca Ye made rom al these observations ismaris) (Ste TWO geverl ds She he are of mar Use yourdeduetions in) (i) above to expla Observation IV above “ marks) ‘Total 20 marks a G0 ON 0 THE NEXT PAGESECTION proces Show by mets of estab heme equains the eps iovolved reaton of methane by cleo fore monochlormutne (Ci rp etal. the heaisy of ‘him inthe reaction with aoa Ta conan, te non-talscan be ether oxand orrediced +o "Explain why the ones othe non-metal, sph, are considered ob more serous © Pollutant tan carbon dose lacie relevant guains in your answer. marie) “Total 20 marks G0 ON To THE NEXT PAGE ranapsae 20041B: Relationship awe lar Tae, eae pare aa “Tempore? ogee mas) gap stable method of Grane) "Total 20 marks END OF TEST ‘rest cove 01212020 -MAYHTUNE 2005 FORM TP 2005059 CARIBBEAN EXAMINATIONS COUNCIL ‘SECONDARY EDUCATION CERTIVICATE, EXAMINATION CHEMISTRY Paper 02 ~ General Proficiency 1 howe 45 minutes READ THE FOLLOWING DIRECTIONS CAREFULLY LWORKING MUSTBESHOWN inthis booklet, |. The use of non-programmaecakuators is allowed. DO NOT TURN THIS PAGE UNTIL. YOU ARE TOLD TO DO SO Copyright © 2004 Cs aon Come ‘all 121a0am 2005