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This document provides safety information for Eurol Harley 20W-50 lubricating oil. It identifies the product and company details in Section 1. Section 2 notes that it is not classified as hazardous according to CLP criteria. Precautionary statements include keeping out of reach of children and potential allergic reactions. Section 3 lists the main ingredients as petroleum-based distillates and highly refined mineral oil. Section 4 provides first aid measures in case of exposure by inhalation, skin, eyes or ingestion. Firefighting instructions are given in Section 5, including using water spray, fog or dry chemical powder to extinguish.

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0% found this document useful (0 votes)
67 views7 pages

Msds

This document provides safety information for Eurol Harley 20W-50 lubricating oil. It identifies the product and company details in Section 1. Section 2 notes that it is not classified as hazardous according to CLP criteria. Precautionary statements include keeping out of reach of children and potential allergic reactions. Section 3 lists the main ingredients as petroleum-based distillates and highly refined mineral oil. Section 4 provides first aid measures in case of exposure by inhalation, skin, eyes or ingestion. Firefighting instructions are given in Section 5, including using water spray, fog or dry chemical powder to extinguish.

Uploaded by

AntonioPallone
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Eurol Harley 20W-50

Safety Data Sheet


according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Date of issue: 9-2-2014 Revision date: 22-8-2019 Supersedes: 27-3-2018 Version: 3.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Product form : Mixture
Product name : Eurol Harley 20W-50
Product code : E100390
Product group : Trade product
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Intended for general public
Main use category : industrial use,professional use,consumer use
Use of the substance/mixture : Lubricant
Function or use category : Lubricants and additives

1.2.2. Uses advised against


No additional information available
1.3. Details of the supplier of the safety data sheet
Eurol bv.
Energiestraat 12
P.O. Box P.O. Box 135
7442 DA Nijverdal - The Netherlands
T +31 548 615165
[email protected] - www.eurol.com
1.4. Emergency telephone number
Emergency number : +31 79 3467 808
EVOFENEDEX

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Mixtures/Substances: SDS EU 2015: According to Regulation (EU)
2015/830 (REACH Annex II)
Not classified

Adverse physicochemical, human health and environmental effects


No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display
Precautionary statements (CLP) : P102 - Keep out of reach of children.
EUH-statements : EUH208 - Contains Benzenesulfonic acid, methyl-, mono-C20-24-branched alkyl derivs,
calcium salts, Benzenesulfonic acid,methyl-mono-20-26-branched alkylderivates, calcium
salt. May produce an allergic reaction.
EUH210 - Safety data sheet available on request.
Child-resistant fastening : Not applicable
Tactile warning : Not applicable
2.3. Other hazards
Other hazards not contributing to the classification : This product floats on water and may affect the oxygen-balance in the water. The base oil
contains less than 3% DMSO-extract measured according IP 346, therefore it is NOT
classified as T/R45: May cause cancer" (Note L).". USED ENGINE OILS: Combustion
products resulting from the operation of internal combustion engines contaminate engine
oils during use. Used engine oil may contain hazardous components which have the
potential to cause skin cancer. Frequent or prolonged contact with all types and makes of
used engine oil must therefore be avoided and a high standard of personal hygiene
maintained.

SECTION 3: Composition/information on ingredients


3.1. Substances
Not applicable

22-8-2019 (Version: 3.0) EN (English) 1/7


Eurol Harley 20W-50
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

3.2. Mixtures
Name Product identifier % Classification according to
Regulation (EC) No.
1272/2008 [CLP]
Distillates (petroleum), hydrotreated heavy paraffinic (CAS-No.) 64742-54-7 >= 50 Asp. Tox. 1, H304
(EC-No.) 265-157-1
(EC Index-No.) 649-467-00-8
(REACH-no) 01-2119484627-25
Highly refined mineral oil (C15 -C50) (REACH-no) 01-2119471299-27, 01- 10 - 25 Not classified
substance with a Community workplace exposure limit 2119484627-25, 01-2119487077-29

Full text of H-statements: see section 16

SECTION 4: First aid measures


4.1. Description of first aid measures
First-aid measures general : Seek medical attention if ill effect develops.
First-aid measures after inhalation : Take victim to fresh air, in a quiet place, in an half laying position and if necessary take
medical advice. Allow the victim to rest.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water,
followed by warm water rinse. High-pressure injection under skin may cause serious
damage. Seek medical attention if ill effect or irritation develops.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Ensure adequate
flushing of eyes by separating eyelids with the fingers. Obtain medical attention if pain,
blinking, tears or redness persist.
First-aid measures after ingestion : Consult a doctor/medical service if you feel unwell. If vomiting occurs spontaneously, keep
head below the hips to prevent aspiration. Do not induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : At normal ambient temperatures this product will be unlikely to present an inhalation
hazard because of its low volatility. May be harmful by inhalation if exposure to vapour,
mists or fumes resulting from thermal decomposition products occurs.
Symptoms/effects after skin contact : Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated
exposure may lead to dermatitis. High pressure injection of product into the skin may lead
to local necrosis if the product is not surgically removed.
Symptoms/effects after eye contact : Unlikely to cause more than transient stinging or redness if accidental eye contact occurs.
Symptoms/effects after ingestion : Bad taste. Unlikely to cause harm if accidentally swallowed in small doses, though larger
quantities may cause nausea and diarrhoea.
Symptoms/effects upon intravenous administration : Unknown.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide (CO2), dry chemical powder, foam. Water fog.
Unsuitable extinguishing media : Do not use a heavy water stream. Use of heavy stream of water may spread fire.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Combustion generates: CO, CO2, POx, NOx, SOx, H2S. Metal oxides.
Explosion hazard : Not expected to be a fire/explosion hazard under normal conditions of use.
5.3. Advice for firefighters
Precautionary measures fire : Do not enter fire area without proper protective equipment, including respiratory protection.
Firefighting instructions : Use water spray or fog for cooling exposed containers.
Protection during firefighting : Use self-contained breathing apparatus and chemically protective clothing.
Other information : Prevent fire fighting water from entering the environment. Sweep up and remove to a
suitable, clearly marked container for disposal in accordance with local regulations.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
General measures : Spill area may be slippery. Prevent soil and water pollution. Prevent entry to sewers and
public waters.

6.1.1. For non-emergency personnel


Protective equipment : When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk
of splashing) then chemical resistant aprons and/or impervious chemical suits and boots
will be required. Use protective clothing.
Emergency procedures : Consider evacuation.

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Eurol Harley 20W-50
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
6.1.2. For emergency responders
Protective equipment : When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk
of splashing) then chemical resistant aprons and/or impervious chemical suits and boots
will be required.
Emergency procedures : No specific measures are necessary.
6.2. Environmental precautions
Dike for recovery or absorb with appropriate material. Notify authorities if product enters sewers or public waters. Prevent soil and water pollution.
Prevent liquid from entering sewers, watercourses, underground or low areas. Contain any spills with dikes or absorbents to prevent migration and
entry into sewers or streams.
6.3. Methods and material for containment and cleaning up
For containment : Large quantities: Contain large spillage with sand or earth.
Methods for cleaning up : Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders,
sawdust). Take up large spills with pump or vacuum and finish with dry chemical
absorbent.
Other information : Use suitable disposal containers. Sweep up and remove to a suitable, clearly marked
container for disposal in accordance with local regulations. On water, recover/skim from
surface and pour out in disposal container.
6.4. Reference to other sections
For further information refer to section 13.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Additional hazards when processed : Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat,
flame, sparks, static electricity, or other sources of ignition. They may explode and cause
injury or death. Empty containers should be completely drained, properly closed, and
promptly returned to a drum reconditioner or disposed of properly.
Precautions for safe handling : Avoid prolonged and repeated contact with skin. May be dangerously slippery if spilled.
Where contact with eyes or skin is likely, wear suitable protection. Do not eat, drink or
smoke during use. Remove contaminated clothing and shoes.
Hygiene measures : Take all necessary measures to avoid accidental discharge of products into drains and
waterways due to the rupture of containers or transfer systems. Handle in accordance with
good industrial hygiene and safety practice. Wash hands and other exposed areas with
mild soap and water before eating, drinking or smoking and when leaving work. Where
contact with eyes or skin is likely, wear suitable protection. Wash contaminated clothing
before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Keep container tightly closed and in well ventilated place.
Storage conditions : Store in original container.
Incompatible products : Reacts vigorously with strong oxidizers and acids.
Maximum storage period : 5 year
Storage temperature : ≤ 40 °C
Information on mixed storage : Keep away from : oxidizing materials. strong acids.
Storage area : Store at ambient temperature.
Special rules on packaging : Keep container tightly closed and dry.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection


8.1. Control parameters
Highly refined mineral oil (C15 -C50)
EU - Occupational Exposure Limits
IOELV TWA (mg/m³) 5 mg/m³
Exposure-value for oil mist : 10 mg/m3 (15 min.) or 5 mg/m3 (8 hours).
8.2. Exposure controls
Appropriate engineering controls:
Large quantities: Contain large spillage with sand or earth.
Personal protective equipment:
Gloves. In case of splash hazard: safety glasses. Eye protection should only be necessary where liquid could be splashed or sprayed.

Materials for protective clothing:


PVC gloves. Neoprene or nitrile rubber gloves

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Eurol Harley 20W-50
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Hand protection:
In case of repeated or prolonged contact wear gloves. The gloves should be replaced immediately in case of damage or signs of wear. It is
recommended to use preventative skin protection (skin cream). The protection glove should be tested for its specific suitability (e.g. mechanical
strength, product compatibility, anti-static properties).

Eye protection:
Eye protection should only be necessary where liquid could be splashed or sprayed

Skin and body protection:


No special clothing/skin protection equipment is recommended under normal conditions of use. Avoid repeated or prolonged skin contact. If
repeated skin contact or contamination of clothing is likely, protective clothing should be worn. Equipment should conform to EN 166.

Respiratory protection:
Respiratory protective equipment is not normally required where there is adequate natural or local exhaust ventilation to control exposure. Where
excessive vapour, mist, or dust may result, use approved respiratory protection equipment. Respiratory protective equipment must be checked to
ensure it fits correctly each time it is worn. Provided an air-filtering/air-purifying respirator is suitable, a filter for particulates can be used for mist or
fume. Use filter type P or comparable standard. A combination filter for particles and organic gases and vapours (boiling point >65°C) may be
required if vapour or abnormal odour is also present due to high product temperature. Use filter type AP or comparable standard.
Personal protective equipment symbol(s):

Environmental exposure controls:


See Heading 12. See Heading 6.
Consumer exposure controls:
PVC gloves. Neoprene or nitrile rubber gloves.
Other information:
Do not put the product-soaked rags into the pockets of working clothes. Do not use cloths stained with the product to dry hands. Wash hands and
other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or smoke during use.
Wash contaminated clothing before reuse.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state : liquid
Appearance : Oily. liquid.
Colour : Brown.
Odour : characteristic.
Odour threshold : no data available
pH : no data available
Relative evaporation rate (butylacetate=1) : < 0,1
Melting point : < -33 °C
Freezing point : no data available
Boiling point : > 280 °C
Flash point : 205 °C
Auto-ignition temperature : > 240 °C
Decomposition temperature : no data available
Flammability (solid, gas) : no data available
Vapour Pressure 20°C : < 0,1 hPa
Relative vapour density at 20 °C : > 1 (air=1)
Relative density : no data available
Density : 0,87 - 0,88 kg/l
Solubility : insoluble in water.
Log Pow :>3
Viscosity, kinematic : 125 - 160 mm²/s
Viscosity, dynamic : no data available
Explosive properties : no data available
Oxidising properties : no data available

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Eurol Harley 20W-50
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Explosive limits : 0,6 - 7 vol %
9.2. Other information
VOC content :0%
Other properties : Gas/vapour heavier than air at 20'C.

SECTION 10: Stability and reactivity


10.1. Reactivity
Stable under normal conditions of use.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Refer to section 10.1 on Reactivity.
10.4. Conditions to avoid
Moisture. Overheating.
10.5. Incompatible materials
Strong oxidizing agents. strong acids.
10.6. Hazardous decomposition products
CO, CO2, POx, NOx, SOx, H2S. Metallic oxides.

SECTION 11: Toxicological information


11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

Distillates (petroleum), hydrotreated heavy paraffinic (64742-54-7)


LD50 oral rat > 5000 mg/kg
LD50 dermal rat > 5000 mg/kg
LC50 inhalation rat (mg/l) > 5,53 mg/l
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified

Eurol Harley 20W-50


Viscosity, kinematic 125 - 160 mm²/s
Other information : Toxicological data have not been determined specifically for this product. Information given
is based on a knowledge of the components and the toxicology of similar products. Likely
route of exposure: ingestion, skin and eye.

SECTION 12: Ecological information


12.1. Toxicity
Ecology - general : Ecotoxicological data have not been determined specifically for this product. Information
given is based on a knowledge of the components and the ecotoxicology of similar
products.
Ecology - water : This product floats on water and may affect the oxygen-balance in the water.
Hazardous to the aquatic environment, short-term : Not classified
(acute)
Hazardous to the aquatic environment, long-term : Not classified
(chronic)

Distillates (petroleum), hydrotreated heavy paraffinic (64742-54-7)


LC50 fish 1 100 mg/l
EC50 Daphnia 1 10000 mg/l

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Eurol Harley 20W-50
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

12.2. Persistence and degradability


Eurol Harley 20W-50
Persistence and degradability Not readily biodegradable.

Distillates (petroleum), hydrotreated heavy paraffinic (64742-54-7)


Biodegradation 31 %
12.3. Bioaccumulative potential
Eurol Harley 20W-50
Log Pow >3
Bioaccumulative potential This product is not expected to bioaccumulate through food chains in the environment.
12.4. Mobility in soil
Eurol Harley 20W-50
Ecology - soil Not miscible with water. Spillages may penetrate the soil causing ground water
contamination. This product floats on water and may affect the oxygen-balance in the
water.
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Regional legislation (waste) : Disposal must be done according to official regulations.
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Do not discharge
into drains or the environment.
Additional information : Hazardous waste.
Ecology - waste materials : Every mixture with foreign substances such as solvents, brake- and cooling liquids is
forbidden. Empty containers retain product residue (solid, liquid, and/or vapor) and can be
dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such
containers to heat, flame, sparks, static electricity, or other sources of ignition. They may
explode and cause injury or death. Empty containers should be completely drained,
properly closed, and promptly returned to a drum reconditioner or disposed of properly.
When not empty dispose of this container at hazardous or special waste collection point.
European List of Waste (LoW) code : 13 02 05* - mineral-based non-chlorinated engine, gear and lubricating oils

SECTION 14: Transport information


In accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA ADN RID

14.1. UN number
Not applicable Not applicable Not applicable Not applicable Not applicable

14.2. UN proper shipping name


Not applicable Not applicable Not applicable Not applicable Not applicable

14.3. Transport hazard class(es)


Not applicable Not applicable Not applicable Not applicable Not applicable

14.4. Packing group


Not applicable Not applicable Not applicable Not applicable Not applicable

14.5. Environmental hazards


Dangerous for the Dangerous for the Dangerous for the Dangerous for the Dangerous for the
environment : No environment : No environment : No environment : No environment : No
Marine pollutant : No
No supplementary information available
14.6. Special precautions for user
Overland transport
no data available

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Eurol Harley 20W-50
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Transport by sea
no data available
Air transport
no data available
Inland waterway transport
no data available
Rail transport
no data available
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
Contains no substance subject to REGULATION (EU) No 649/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 July 2012
concerning the export and import of hazardous chemicals.
Contains no substance subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on persistent
organic pollutants

VOC content :0%

15.1.2. National regulations


No additional information available
15.2. Chemical safety assessment
No additional information available

SECTION 16: Other information


Full text of H- and EUH-statements:
Asp. Tox. 1 Aspiration hazard, Category 1
H304 May be fatal if swallowed and enters airways.
EUH208 Contains Benzenesulfonic acid, methyl-, mono-C20-24-branched alkyl derivs, calcium salts,
Benzenesulfonic acid,methyl-mono-20-26-branched alkylderivates, calcium salt. May produce an allergic
reaction.
EUH210 Safety data sheet available on request.

SDS EU (REACH Annex II) - Copy Eurol


This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

22-8-2019 (Version: 3.0) EN (English) 7/7

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