Maneiosaa ioienora snawrrensio ciaunee Gawaponot: 1x Kom erauiTst niicconnanuit coornercraenno 117+ 10°? 1 9,3+10-2 3 . Ose KucwioTst cnocoditt 3a cxeT KapGoKcHAbHEIX rpynn O6pazonE- arb coal, CnoxkHIe axKpH, MIAN W HeKoTOpHe ApyrHe NPOHSBORNME xucaoT, OwaKo dymaposam KilcaoTa He aeT LIKANNeCKOFO AFHApIIAA, a manenttonan nerKo ero o6pasyer, TAK Kak O6a ee KapGOKCHAIa pactio- HOHKEHE! NO OAHY ctoponty oF ABOMKO cBASH: Maxenosan xneaota (na6uabnar copwa) nox refcrsiem 6poma, woga, asoTuctoli KucmOTLA sterKo NepexoanT B yeToliwHByio, craw nyto opwy — dymaposyio xneaory. Odparsisit nepexon ocymecrans- fete nox AelenBiter yasrparoneroass aye Maseunoseit aneudpud | 2 Kak YyiKe ToBopHnocs, serKO h oGpasyerca np warpesanmm warenionof xuenors. Tosromy npn KaTaqiiTHyeckoM OKNCTeHIIH Gei130na ~M HagranMHa nonywaeTeR He” ‘cana Manennosan KicnoTa, a ee aHrHApHA. i ‘Manenuonuil aurnapna— Gecusetiioe KpucranzmiecKoe nemectBo cr. na. 52,6 °C; pacrsopaace 8 Boze, o# nepexoAHT B MaenHoByIo KiLc- aory. Manenmosuit anrnapna cays xapaktepysim peaxrusom a1 06- Napyxxeuna 1,3-ueHoBisx coeunHenMi: OH NerKO BerynaeT B peaKINo — AueHoporo cuuTesa (ext. rt, 1.3) H BO MHOTHX eay¥aRX NaeT LeNHHe mpoaykrs. B nocaeguie roast on npwoGpen mupoKoe npuvenienue B npona- RogeTae MomMZpNpHLX CMON, a TakKRe AAA MOTyYeHUs conomMepos (co cruponow, axpizosuni meraxpHsoBsiM adupanm). at Manenvosiah auruapna rparaiweli nepesomiter B aGnounyio xalenory, mpunenmemyio B mneso% npomBmutenwocri: a HC—Co HC(OH)—COOH - eres | HK HCH—cooH TUABA 7 CEPOCOXEPARAMHE OPTAHHYECKHE CORAMHEHUSL Cepa spanercm aliazorom KutcwOpoRa H nOTOMY MO‘eT OGpasoBEe= Barb opraieckne coeaiHemis, ocrpoemmiie aflanorHaio coesHe ula kucciopoza. Xopowo Hayseust TakHe COeaIMEHIIA CepLl, KAK TH-PELE Ccmpres, THosdupss, THOAAbAerNE H THOKeTON, THOKICAOTE, a TAKE _ Syauboxucnotss, B sot pasnene Gyayr paceworpenss -ruocapris, | Thosdupsr u cyabpoxncaors. Hexoropsie aauuste 0 THOKtICHOTax CO! —— OGuatoren B ra. 11.5, x 4, THOCUMPTEI (THOABI) I THODOUPEI (CYABONAB Tlonoto tomy Kak cnuiprix u mpoctixe sfupsx MoxHO pacemarpit= BaTb Kak aTKIABHBLe NpONSBOANEIe BOR, TAK M THOCKHpTEx H THO2KuIpLt MOXHO paccnaTpuBars KaK MpoHIsBOAHBIe alanora BOM — cepoBO}O- ona, oOpasonariute savtemenitem ankiinaM OxHOTO Tint OGOHX aTOMOS Bouopoaa B ero nomexyae. OOutan Gopuyaa THocmIproD, WHaNe aati | BaeNDIX muoaawu rant wepxanmarasu, RSH, a THospipos (eyasspi 00) R—S—R’ ‘cust evumwepxanrad, weranmuoa (cncrewartsetKam HowemEnarypa} HSH ‘tuaepkanran, grata GH-S—CH swotuneymug, saaruosran Gly—S—GH,stwanponsacymegug, 1-sraatuonponan Tuocnuptet 1 THoxpupsr onyNaloT M3 ranoreHOrpOHSBORNENX HA enupros caeaytouimt oGiuiniH MeToRaNt: (GH + KSH — C,Hs—SH+KI CoHLOH +18 sips HSH + H,0 2Cyl + KyS — (GHy),S+ 2K HBr + (NHY.C=5 — [git c=8 — c,t4,] Br HOS HASH + (NHLY,CO ‘Mepxanramss xitnar np stauurenbuo Gomee HiSKHX Texeparypax, ‘eat coorpererayrouue cniipri, oveDiLtWo, 13-34 MeHBINeH ACZOUNaII ux wonexya. Maa stumepxanrana 7. xun, 37°C, a ats stuaoBoro caupta 78,3 °C. Mepxantanst naoxo pacroopias's Bone. Jo xusmnveckint csoficraam mepxamranisa 8 OLA OT caupros NpuGruxaiorea K caaGsM KuemOTaM (WanoMiuM, Ho HS — may xoc- Hostiaa cnaGaa KyeToTa, Kq = 6-10; ana staxtiona Ke = 10", Mlostosy tions, sepranratis, pactaopaacs B wetovax, “oGpaayiot ConeoSpastisie coeqHHeHuA —THoOnATE, HAN sepKannude RSNa: C,H;SH + NaOH —- H,0+C,H,SNa 2CH,SH 4-Hg0 — H,0+ (GH,S),He Aeiterone caa6ax oxncantereli na mepKantannl TpMBOAUT K OOpa- sopanio Oucyaopudos. Crabbe oKuealtTent alot ‘cyavponucaomer: ( | Bisar tsar GHsS—S—Cy Tennant moe Sheen CllsSOMH oaacloreTaxus oSpasost,B onmimae OF CnHIpTOB NpH OKUCAHNE THONOB OKH= caneren ne yraepoa, a cepa. Peakitia wet, BepoaTHo, no onuoMy 13 exeayiomu myrens : tt t rssn— Rd tr _ neyadon i sé sil} 88 [ersost ; rmeymton | gute, son — R-§—oH—| } eopeaet exmipunonan ‘Mepxanramu nerko npuicoeaunmoren K HenpenembabiM coeaHne- wus 10 paxHKanbHoxty mi HyKneoduabHoMy wexamusmam. Panue xanbHoe npiicoezmmenie: SHR: — RS RH (CH,—CH=CH, + RS‘ — CHj—CH—CH,SR +254 cH, —CH,—CH;SR++RS* Hyxaeopunsnoe npucoexmene: Yo, +Rg"—+ cH —cusn— Zit, Be cm cris — Ch . cic Hexoropnie mepxantaia nonysuinit npaxriseckoe mpuwenenne. Me- ‘uawepxantan, nponsnoxnentt ® npoMBlLiAeHHocTH nponycKaniie eMe~ cu MeTiwioBoro cmupra H cepoBoxopoza Hax raunosewos mpu 400 *C, ue- homssyerem Jina ciitresa npreriseMoro B 7kiLBOTHOBOXCTBE MemuoALUNG CH,—S—CH,—CH:CHNH,—COOH, Srua- 1 rsoanuawepxanrant ncnombayiores AAA OROpatLIM OuiTOBOrO Taga. Hisutie Mepxanranist — 2KWAKOcTH ¢ OTRpATHTeAbHEM sanaxoM. Tlockoabxy no sanaxy 1x MOKHO OGHApYaKuT) sake B CAMBIX HATYTOX- hx KOMM¥eCTBAX, a Mpupoawul ras npaKruyeck He uMeeT sanaxa, RoGapeie HesHauiTeNbHOTO KomMMecTBa iSoaMHAMepKanTaHa AaeT oaoxkHOCTl erKO saneTiT yreuKy B rasonpotorax, ZoxeunaMep- xantaH CjHSH npunewsered Kak peryanTop sstyascHonsofi mom Mepusanin 8 nponsRONeTBe cititeTHNecKOTO KayyKa. Cyabbiie — xuAKocTH, XHMAMDIe pH Temepatype, GanaKolh x reumeparype KilNeiin MepKantakos ¢ Toll >Ke moeKy.aApHioit waccol Stavepxantas, wanpumep, uncer 7. xin. 37°C, a anMeTnacymedHa 38°C. Oni HepacropliMbt B Boxe H untetor sdupweili sanax. Flo xnMm- Necxuist cpoficrpat THosips — peutectsa nelitparpmme, Lelieroue wa «hiv oxitemeaeli, Kax noxesaa paborst A. M. Safinesa (1866), npx- Boat k odpasosanitio cyambhoxcnjos R-S—R unr cyampouos R,SO,§ (@ sasuciMocru of cum 1 Komuuectea oKuemTena): fa [raatae Onecare —ICHIS +O wun (es (ais io Sa oa OS. aa (6888s < Gt, C ankuaranorennaani oun o6pasyior TuoHtenue (cyabiponnesuie) cont: Chis, S: —for,—$ ae >$+ cH [ee a re cH onsets K xzaccy cyavipuzos ornocutca Goesoe OTpaBsaionjee BeulecTBO Koxtio-HapsisHoro deicrons — unpum (B, Br-aurenopauatiiacyassi), ‘S10 Gecuserian axnaKoeT (r. Kim. 217 °C) c HecHouint aanaxoM. Mupirr noxkto noaysnrs no exene (CH,—CH,OH Jie S LOH ayer 5 AH, —CHy Koerner ZLaa gerasauin unpitra nenoavsyere xnopHar waBecTS uit XT0p- awit B wT (ex. ra. 19). Jlerasaropst npespauiaior nmpitt 8 cy.abpoK- CHA WH ApyrHte BemecrBa, Aunemuacyanpoxcud (CHy),S-+O wwupoxo npuneusetes Kak Bu SoKonozapustl pacraopurens (iunoabittlt monextt 4,0 D, tian 1,34 % x10 Ras. 2, OPFAHIMECKME C¥/IbbORUCTOTE Cyanporucsiorawn wastinator mportsnoanie yresoropox08, conep- -malile B KavecTae SamecruTea cyauporpyany. B coorseterann ¢ oxrerioli dopmy.ioit cyawporpynna uveer pe KoBaMeHTHBe HABE ceminorapHne ceasH. Tlocaexine oOpasoBanes ‘eyuiactiteu TonbKo saexrpovion aroma cepst. Oaniako aa cyasboxneaoT MOXKET HeMOMBSOBATHCA H GopMy.ta C UeCTHIO KOBATeXTHEIMH CBSISASEIE (aoyos opanmapinsisa m xoywa oOfiM), Tare KaX ATOM CepEt HMeIOT Aue d-op6itraTH, Wa KOTOPLIX MOFyT OsITb TAKE pasmeutenes smexnponut (¢ pacumpeiiiew oxreta):