Eng.

Admission Program, 2024

WM-11, Physical, Written, Set-C
HMath 1st Paper, Ch-09+10, (AšÍixKiY+†hvMRxKiY)
D”PZi MwYZ HMath
01 10
y= n‡j †`LvI †h, 4x y + 4xy − (1 − 4x )y = 0 If y = , then show that 4x y + 4xy −
√ √
(1 − 4x )y = 0
y= y=
√ √
√ . √ .
√ √
⇒𝑦 = ⇒𝑦 =
⇒ −y = ⇒ −y = + ⇒ −y = ⇒ −y = +
√ √ √ √
.√ .√
√ √
⇒ −y = + ⇒ −y = +
⇒ −y = − + ⇒ −y = − +
√ √ √ √
⇒ −y = y − −y − + ⇒ −y = y − −y − +
⇒ −2x y = 2x y + xy + + xy − y ⇒ −2x y = 2x y + xy + + xy − y
⇒ −2x y = 2xy + 2x − y ⇒ −2x y = 2xy + 2x − y
⇒ 4x y = −4xy − (4x − 1)y ⇒ 4x y = −4xy − (4x − 1)y
∴ 4x y + 4xy − (1 − 4x )y = 0 ∴ 4x y + 4xy − (1 − 4x )y = 0

b¤^i eÈbt Marks Distribution:

√ . √ .
𝑦 = √
; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, 𝑦 = √

.√ .√
−y = √
+ ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, −y = √
+
−2x y = 2x y + xy + + xy − y ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, −2x y = 2x y + xy + +
4x y + 4xy − (1 − 4x )y = 0 ; ‡`Lv‡bvi Rb¨ 04 b¤^i| xy − y
04 marks for showing, 4x y + 4xy − (1 − 4x )y = 0

D”PZi MwYZ HMath

02 10
GKwU D‡ovRvnvR gvBj Dci w`‡q N›Uvq 15 gvBj †e‡M Avbyfw~ gKfv‡e An aeroplane is flying horizontally with velocity 15 miles per
D‡o hv‡”Q| 2 wgwbU Av‡M f~wg¯’’ †h we›`ywUi Dci w`‡q AwZµg K‡i‡Q, hour at the height miles. The aeroplane is moving away
†m we›`y †_‡K D‡ovRvnvR Kx †e‡M `~‡i m‡i hv‡”Q? with what velocity from the point on the ground that it has
crossed 2 minutes earlier?
 t t

awi, OA = x, Z‡e PA = 15t

 OA = PA + OP  x = (15t) +  x = 225t + Let, OA = x, Then, PA = 15t
… … … . (𝑖)
 OA = PA + OP  x = (15t) + x =
2x = 450t  = ........(ii); hLb t = 2 wgwbU = N›Uv 225t + … … … (𝑖)

ZLb, (i)  x = + x = + = x=

× 2x = 450t  = ........(ii); when t = 2 minutes =
∴(ii)  = 225 × × = 9 gvBj/N›Uv| [Ans.] hour

b¤^i eÈbt Then, (i)  x = + x = + = x=

×
x = 225t + ; wbY©‡qi Rb¨ 02 b¤^i|
= ; wbY©‡qi Rb¨ 02 b¤^i| ∴(ii)  = 225 × × = 9 miles/hour. [Ans.]
x = ; wbY©‡qi Rb¨ 03 b¤^i|
Marks distribution:
= 9 gvBj/N›Uv; wbY©‡qi Rb¨ 03 b¤^i|
02 marks for determining, x = 225t +
[we:`ª: GKK bv wjL‡j ev fzj GKK wjL‡j 01 b¤^র KZ©b Kiv n‡e|] 02 marks for determining, =
03 marks for determining, x =
03 marks for determining, = 9 mile/hour
[N. B: 01 mark will be deducted if unit is not written or wrong
unit is written.]

D”PZi MwYZ HMath

03 10
1 wjUvi Zij aviY ¶gZv m¤úbœ 1 wU Lvov e…ËvKvi wmwjÛv‡ii cÖ‡qvRb, 1 vertical circular cylinder with capacity 1 litre is required
hvi 2 cÖvšÍ Ave×| wmwjÛviwUi D”PZv I e¨vmva© Kxiƒc n‡j me©v‡c¶v Kg whose two ends are closed. What should be the height &
†¶Îdj wewkó wUb w`‡q Zv ‰Zwi Kiv m¤¢e? radius of the cylinder so that it can be made with tin of
minimum area?
awi, wmwjÛv‡ii D”PZv h †Wwmwg. Ges e¨vmva© r †Wwmwg.  πr h = Let, height of the cylinder is h deci m. and radius is r deci
m.
1 ⇒ 2rh + r =0⇒ =−

 πr h = 1 ⇒ 2rh + r =0⇒ =−
Avevi, A = 2πr (r + h) ∴ = 2π(r + h) + 2πr 1 +
=0 ⇒r+h+ 1− r = 0 ⇒ r + h + r − 2h = 0 Again, A = 2πr (r + h) ∴ = 2π(r + h) +
2πr 1 + =0⇒r+h+ 1− r=0⇒r+h+
⇒ h = 2r ∴ 2πr = 1 ⇒ r = 0.542 dm = 5.42 cm এবং
h = 2r = 1.084 dm = 10.84 cm [Ans.] r − 2h = 0

b¤^i eÈbt ⇒ h = 2r ∴ 2πr = 1 ⇒ r = 0.542; dm = 5.42 cm and

h = 2r = 1.084 dm = 10.84 cm [Ans.]
= − ; wbY©‡qi Rb¨ 02 b¤^i|
h = 2r; wbY©‡qi Rb¨ 02 b¤^i| Marks distribution:
r = 5.42 cm; wbY©‡qi Rb¨ 03 b¤^i|
02 marks for determining, =−
h = 10.84 cm; wbY©‡qi Rb¨ 03 b¤^i|
[we:`ª: GKK bv wjL‡j ev fzj GKK wjL‡j 01 b¤^র KZ©b Kiv n‡e|] 02 marks for determining, h = 2r
03 marks for determining, r = 5.42 cm
03 marks for determining, h = 10.84 cm
 [N. B: 01 mark will be deducted if unit is not written or
wrong unit is written.]

D”PZi MwYZ HMath

04 10
†`LvI †h, x + y = a eµ‡iLvi †h‡Kv‡bv ¯úk©K KZ…©K Aÿ `ywU †_‡K Show that, the sum of squares of intercepts from the
KwZ©Z As‡ki e‡M©i †hvMdj aªæeK| two axes by any tangent of x + y = a is a constant.

awi, eµ‡iLvi ¯úk© we›`y (x , y ) Let, contact point of curve (x , y )

∴ x + y = a … (i) ∴ x + y = a … (i)
GLb, x + y = a Now, x + y = a

⇒ x + y =0⇒ = ⇒ x + y =0⇒ =

(𝑥 , 𝑦 ) we›`y‡Z ¯úk©K, 𝑚 = Tangent at point (𝑥 , 𝑦 ), 𝑚 =

∴ ¯úk©‡Ki mgxKiY, y − y = (x − x ) ∴ Equation of tangent, y − y = (x − x )

⇒ yy − y = −x x + x ⇒ yy − y = −x x + x

⇒ yy + xx =a ⇒ yy + xx =a
⇒ + =1 ⇒ + =1

Sum of the squares of the intercept parts =

KwZ©Z As‡ki e‡M©i †hvMdj = 𝑎 𝑦 +𝑥 = 𝑎 𝑎 = 𝑎 = aªæeK
𝑎 𝑦 +𝑥 = 𝑎 𝑎 = 𝑎 = Constant (Showed)
(Showed)
b¤^i eÈbt
Marks Distribution:
(𝑥 , 𝑦 ) we›`y‡Z ¯úk©K, 𝑚 = ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining,

tangent at point (𝑥 , 𝑦 ), is 𝑚 =
¯úk©‡Ki mgxKiY, yy + xx = a ; wbY©q Kivi Rb¨ 03 b¤^i|
KwZ©Z As‡ki e‡M©i †hvMdj = 𝑎 = aªæeK ; †`Lv‡bvi Rb¨ 04 b¤^i| 03 marks for determining, equation of tangent,
yy + xx =a
04 marks for showing, sum of the squares of the
intercept parts = 𝑎 = Constant

D”PZi MwYZ HMath

05 10
y = tan x , 0 ≤ x ≤ Ges y = cot x , ≤ x ≤ `ywU eµ‡iLv I x- What is the area of region enclosed by the two curves
Aÿ Øviv Ave× †ÿ‡Îi †ÿÎdj wbY©q Ki| y = tan x , 0 ≤ x ≤ and y = cot x , ≤ x ≤ and the
x axis.
 cot x cot x

2 2
0 4 3 0 4 3

tan x , 0 ≤ x ≤ tan x , 0 ≤ x ≤
y= y=
cot x , ≤ x ≤ cot x , ≤ x ≤

∴ †ÿÎdj = ∫ (tan x) dx + ∫ (cot x) dx ∴ Area = ∫ (tan x) dx + ∫ (cot x) dx

= [− ln|cos x|] + [ln|sin x|] = [− ln|cos x|] + [ln|sin x|]

√ √
= − ln − 0 + ln − ln = − ln − 0 + ln − ln
√ √ √ √
√ √
= ln − 2 ln = ln √3 = 0.549 eM© GKK = ln − 2 ln = ln √3 = 0.549 sq. units
√ √

b¤^i eÈbt Marks Distribution:

†ÿÎdj = ∫ (tan x) dx + ∫ (cot x) dx ; wbY©q Kivi Rb¨ 04 b¤^i| 04 marks for determining, Area = ∫ (tan x) dx +

†ÿÎdj = ln √3 = 0.549 eM© GKK ; wbY©q Kivi Rb¨ 06 b¤^i| ∫ (cot x) dx

[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|
06 marks for determining, Area = ln √3 = 0.549 sq.
units
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.

D”PZi MwYZ HMath

06 10
y = x Ges y = Øviv Ave× †ÿ‡Îi †ÿÎdj wbY©q Ki| Determine the area of region enclosed by y = x and
y= .
y=x2 y=x2
(0,2) (0,2)
(-1,1) (1,1) 2 (-1,1) (1,1) 2
y= y=
1+x2 1+x2

x = ⇒x +x −2 =0 x = ⇒x +x −2 =0
⇒ (x + 2)(x − 1) = 0 ∴ x ∈ ℝ ⇒ (x + 2)(x − 1) = 0 ∴ x ∈ ℝ
∴ x = ±1 ∴ x = ±1
∴ †ÿÎdj = 2 ∫ −x dx ∴ Area = 2 ∫ −x dx

= 2 × 2 tan x− =2 − = 2.4749 eM© GKK = 2 × 2 tan x− =2 − = 2.4749 sq.

units
b¤^i eÈbt
x = ±1 ; wbY©q Kivi Rb¨ 02 b¤^i| Marks Distribution:
†ÿÎdj = 2 ∫ −x dx ; wbY©q Kivi Rb¨ 04 b¤^i| 02 marks for determining, x = ±1
04 marks for determining, Area = 2 ∫ −x dx
†ÿÎdj = 2 − = 2.4749 eM© GKK ; wbY©q Kivi Rb¨ 04 b¤^i|
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| 04 marks for determining, Area = 2 − = 2.4749
 sq. units
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.

Eng. Admission Program, 2024

WP-11, Weekly Physical, Written, Set-C
nd
Physics 2 Paper, Ch-07+08, Physical Optics and Modern Physics

c`v_©weÁvb Phy
01 [Medium] 10
Bqs Gi wØwPo cixÿvq `ywU wP‡oi ga¨eZx© `~iZ¡ 2mm| Av‡jvi Zi½‰`N©¨ In Young's double-slit experiment, the distance between the
600 nm Ges c`©v n‡Z wPo؇qi `~iZ¡ 2m| hw` †K›`ªxq Pi‡gi ZxeªZv two slits is 2 mm. The wavelength of light is 600nm, and
0.2 Wm nq Z‡e, †K›`ªxq D¾¡j †Wviv n‡Z 0.5 cm `~i‡Z¡ ZxeªZv the distance from the slits to the screen is 2 m. If the
KZ? intensity at the central maximum is 0.2 Wm , what is the
intensity at a point 0.5 cm away from the central bright
fringe?
. × × × . × × ×
c_ cv_©K¨, ∆x = = = 5 × 10 m Path difference, ∆x = = = 5 × 10 m
∆ ∆
`kv cv_©K¨, Q = = Phase difference, Q = =

A = A + A + 2A cos =A A = A + A + 2A cos =A
A = √A + A + 2A = √4A = 2A A = √A + A + 2A = √4A = 2A
=( )
⇒ I = × 0.2 =( )
⇒ I = × 0.2
I = 0.05 Wm I = 0.05 Wm

b¤^i eÈbt Marks Distribution:

∆x = 5 × 10 m ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, ∆x = 5 × 10 m
Q= ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, Q =
I = 0.05 Wm ; wbY©q Kivi Rb¨ 06 b¤^i|
06 marks for determining, I = 0.05 Wm
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.

c`v_©weÁvb Phy
02 10
GKwU AceZ©b †MÖwUs G cÖwZ 10 𝑐𝑚 G 7000 †iLv Av‡Q| †MÖwUs n‡Z In a diffraction grating, there are 7000 lines per 10 cm.
c`©vi `~iZ¡ 750 𝑐𝑚| me©wb¤œ KZ †KŠwYK `~i‡Z¡ 340 𝑛𝑚 Ges Distance of the screen from the grating is 750 cm. What
453.33 𝑛𝑚 Zi½‰`‡N©¨i `ywU Av‡jvi Rb¨ Pig GKB ¯’v‡b cvIqv hv‡e? should be the minimum angular distance at which the
maximum of two lights of wavelength 340 nm and 453.33
nm will be found at a same place?
sin 𝜃 = 𝑛 𝑁𝜆 = 𝑛 𝑁𝜆 ⇒ = = 1.333 ≈ sin 𝜃 = 𝑛 𝑁𝜆 = 𝑛 𝑁𝜆 ⇒ = = 1.333 ≈
∴ 𝑛 = 4, 𝑛 = 3 ∴ 𝑛 = 4, 𝑛 = 3
∴ sin 𝜃 = 4 × 70000 × 340 × 10 ⇒ 𝜃 = 5.463 [Ans.] ∴ sin 𝜃 = 4 × 70000 × 340 × 10 ⇒ 𝜃 = 5.463 [Ans.]

b¤^i eÈbt Marks Distribution:

sin 𝜃 = 𝑛 𝑁𝜆 = 𝑛 𝑁𝜆 ; ‡jLvi Rb¨ 03 b¤^i| 03 marks for writing, sin 𝜃 = 𝑛 𝑁𝜆 = 𝑛 𝑁𝜆
𝑛 = 4, 𝑛 = 3 ; wbY©q Kivi Rb¨ 04 b¤^i| 04 marks for determining, 𝑛 = 4, 𝑛 = 3
𝜃 = 5.463 ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, 𝜃 = 5.463
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| [Note: 01 mark will be deducted if unit is not written or
wrong unit is written.

c`v_©weÁvb Phy
03 [Easy] 10
A‡bK¸‡jv mgeZ©K dvwj cici GKmv‡_ ¯’vcb Kiv n‡jv †hb †h‡Kv‡bv Several parallel polarizers are arranged serially such that
GKwU dvwji Av‡jvK Aÿ Zvi cv‡ki Av‡jvK A‡ÿi mv‡_ 15° †KvY K‡i the polarization axis of each polarizer makes a 15° angle
_v‡K| Gfv‡e A‡bK¸wj dvwj cici mvRv‡bv n‡jv hZÿY bv †kl dvwjwU with the adjacent one. This setup continues until the last
1g dvwji mv‡_ 90° †KvY Drcbœ K‡i| Gevi 1g dvwj w`‡q 1.2 × 10 polarizer forms a 90° angle with the first. If an unpolarized
jv· ZxeªZvi GKwU AmgewZ©Z Av‡jv cÖ‡ek Ki‡j †kl dvwj w`‡q KZ light of intensity 1.2 × 10 lux enters through the first
ZxeªZvi Av‡jv wbM©Z n‡e? polarizer, what is the intensity of light emerging from the
last polarizer?
†gvU dvuwj cÖ‡qvRb = + 1 = 7wU| Total polarizers needed = + 1 = 7nos
. × . ×
I = (cos 15°) = × (0.933) = 3.958 × 10 I = (cos 15°) = × (0.933) = 3.958 × 10
jv·| lux.

b¤^i eÈbt Marks Distribution:

†gvU dvuwj cÖ‡qvRb = 7wU ; wbY©q Kivi Rb¨ 04 b¤^i| 04 marks for determining, total polarizers needed = 7
I = 3.958 × 10 jv· ; wbY©q Kivi Rb¨ 06 b¤^i| 06 marks for determining, I = 3.958 × 10 lux
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| [Note: 01 mark will be deducted if unit is not written or
wrong unit is written.

c`v_©weÁvb Phy
04 [Medium] 10
†Kv‡bv e„ËvKvi cÖ¯’‡”Q‡`i cwievnx Zv‡ii GKK AvqZ‡b 4.8 × 10 wU A conductive wire of circular cross-section has 4.8 ×
e Av‡Q| d‡Uv B‡jKwUªK †Kvl Drm †_‡K ZviwU‡Z 1.6A Zwor cÖevwnZ 10 nos electrons per unit volume. When connected to a
n‡”Q| †Kv‡l AvcwZZ Av‡jvi Zi½‰`N©¨ 300 nm Ges wbM©Z d‡Uv photoelectric cell, it produces a current of 1.6A.
B‡jKUª‡bi †e‡Mi 0.0004% †e‡M cwievnx‡Z cwievnx e QzU‡Q| Zv‡ii Wavelength of light incident on the cell is 300nm. If the
cÖ¯’‡”Q‡`i ‡ÿÎdj KZ? [λ = 350 nm, a‡iv, me¸‡jv e Zwor velocity of conduction electrons is 0.0004% of the velocity
of photoelectrons, what is the cross-sectional area of the
cÖev‡n Ask †bq]
wire? [λ = 350 nm, assume all electrons contribute to the
current flow]
= + mv = + mv

⇒v= × − = 4.56 × 10 ms ⇒v= × − = 4.56 × 10 ms

GLb, Zvob‡eM, V = 0.0004% × v now, drift velocity, V = 0.0004% × v
⇒ = 0.0004% × v ⇒ = 0.0004% × v
∴A= = 1.142 × 10 m = 1.142 mm ∴A= = 1.142 × 10 m = 1.142 mm
× × . % × × . %

b¤^i eÈbt Marks Distribution:

= + mv ; m~Î ‡jLvi Rb¨ 02 b¤^i| 02 marks for writing formula, = + mv
v = 4.56 × 10 ms ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, v = 4.56 × 10 ms
A = 1.142 × 10 m = 1.142 mm ; wbY©q Kivi Rb¨ 05
05 marks for determining, A = 1.142 × 10 m =
b¤^i|
1.142 mm
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| m~Î bv
[Note: 01 mark will be deducted if unit is not written or
wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|] wrong unit is written. Direct input of values without writing
formula is also acceptable.]
c`v_©weÁvb Phy
05 [Medium] 10
2 km j¤^v GKwU weªR Gi aviYÿgZv 7350N| 0.8c †e‡M Pjgvb A 2 km long bridge has a load capacity of 7350N. A car of
600 kg-Gi GKwU Mvwo weªRwU‡K AwZµg Ki‡Z †Póv Kij, MvwowU wK mass 600 kg attempts to cross the bridge at a velocity of
weªRwU‡K AwZµg Ki‡Z cvi‡e? 0.8c. Will the car be able to cross the bridge?
m = = 750 kg m = = 750 kg
. .
GLb, m = = 1000 kg Now, m = = 1000 kg

∵m>m ∴ AwZµg Ki‡e bv| ∵m>m ∴ will not be able to cross.

b¤^i eÈbt Marks Distribution:

m = 750 kg ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, m = 750 kg
m = 1000 kg ; wbY©q Kivi Rb¨ 05 b¤^i| 05 marks for determining, m = 1000 kg
MvwowU weªRwU‡K AwZµg Ki‡e bv ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, the car will not be able to cross
the bridge.

c`v_©weÁvb Phy
06 [Easy] 10
GKwU †Uª‡bi wbðj ˆ`N©¨ 250m| GKwU e¨w³‡K †UªbwU 6.5 × A train of rest length 250m passes an observer at a relative
10 ms Av‡cwÿK †e‡M AwZµg Ki‡Z †UªbwUi KZ mgq jvM‡e? velocity of 6.5 × 10 ms . How much time will it take
[e¨w³i wn‡m‡e] (according to the observer) for the train to pass?
V= V=
. × . ×
× ×
× ×
⇒t = = = = 3.755 μs ⇒t = = = = 3.755 μs
. × . ×

b¤^i eÈbt Marks Distribution:

t = ; ‡jLvi Rb¨ 03 b¤^i| 03 marks for writing, t =

mwVKfv‡e gvb emv‡bvi Rb¨ 04 b¤^i| 04 marks for putting the values correctly.
t = 3.755 μs ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, t = 3.755 μs
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.

Eng. Admission Program-2024

Weekly Exam Chemistry-11 (Physical) Written ‰Re †hŠM (A¨vjwWnvBW - A¨vwgb)
Set-C

imvqb Chem
01 10
A †hŠMwU‡K (0 − 5)°C ZvcgvÎvq NaNO I HCl Gi mv‡_ wewµqv Kiv‡j Compound ‘B’ is produced when compound ‘A’ reacts
‘B’ †hŠM Drcbœ nq| ‘B’ †hŠMwUi cÖfveKxq wbiæ`‡bi gva¨‡g ‘C’ †hŠM Drcbœ with NaNO and HCl at (0 − 5)°C temperature.
nq| ‘C’ †hŠM 𝐾𝑂𝐻 wgwkÖZ KMnO Gi `ªeY‡K eY©nxb K‡i I †hŠMwU mswkøó Compound ‘C’ is produced by the catalytic dehydration
mg‡MvÎxq †kÖwYi ÿz`ªZg m`m¨| Dchy³ wewµqvmn A, B, C †hŠMmg~n kbv³ of compound ‘B’. Compound ‘C’ decolorizes KMnO
Ki| solution mixed with KOH and the compound is the
smallest member of the concerned homologous series.
 Identify compound A, B, C with suitable reactions.
CH CH NH + HNO ⎯⎯⎯⎯⎯⎯⎯⎯ CH CH OH + N + H O CH CH NH + HNO ⎯⎯⎯⎯⎯⎯⎯⎯ CH CH OH + N +
° °
,∆ H O
CH CH OH ⎯⎯⎯⎯⎯ CH = CH + H O ,∆
CH CH OH ⎯⎯⎯⎯⎯ CH = CH + H O
CH = CH + [O] + H O ⎯⎯⎯⎯⎯⎯ CH – CH
| |
CH = CH + [O] + H O ⎯⎯⎯⎯⎯⎯ CH – CH
| |
A → CH CH NH ; B → CH CH OH ; C → CH = CH
A → CH CH NH ; B → CH CH OH ; C → CH = CH

b¤^i eÈb:
A I B †hŠ‡Mi mswkøó wewµqv ‡jLvi Rb¨ (02×02) = 04 b¤^i| Mark distribution:
C †hŠ‡Mi mswkøó wewµqv ‡jLvi Rb¨ 03 b¤^i| (02 ×02) = 04 marks for writing the reactions
A, B I C kbv³Ki‡Yi Rb¨ (01×03) = 03 b¤^i| concerned with Compound A & B.
[we.`«.t c«fveK/ ZvcgvÎv bv wjL‡j ev fyj wjL‡j 01 b¤^i KZ©b Kiv n‡e|] 03 marks for writing the reactions concerned with
Compound C
(01×03) = 03 marks for identifying A, B & C.
[N.B.: 01 mark will be deducted if temperature/catalyst
is not written or wrong written.]

imvqb Chem
02 10
‘𝐴’ †hŠMwU‡K †mvWvjvB‡gi mv‡_ DËß Ki‡j B †hŠM Drcbœ nq| ‘B’ †hŠMwU‡K MoO When compound ‘A’ reacts with soda lime
cÖfve‡Ki Dcw¯’wZ‡Z Aw·‡R‡bi mv‡_ wewµqvq ‘C’ †hŠM Drcbœ nq| C †hŠM mswkøó †kÖwYi with heated, compound ‘B’ is produced.
ÿz`ªZg m`m¨ Ges 2,4: 𝐷𝑁𝑃 cixÿv †`q| wewµqvmn A, B, C †hŠMmg~n kbv³ Ki| Again, when compound ‘B’ reacts with
Oxygen in presence of the catalyst MoO ,
compound ‘C’ is produced. Compound ‘C’ is
the smallest member the concerned series and
gives 2,4: 𝐷𝑁𝑃 test. Identify the compounds
A, B, C with reaction.
,∆ ,∆
CH COOH + NaOH ⎯⎯⎯ CH + Na CO CH COOH + NaOH ⎯⎯⎯ CH + Na CO

CH + O ⎯⎯⎯ HCHO + H O CH + O ⎯⎯⎯ HCHO + H O

NO2 NO2 NO2
\ \
HCHO + NH − NH NO ⎯⎯ /C = N − NH NO + HCHO + NH − NH NO ⎯⎯ /C =

H O NO2
A ⎯⎯ CH COOH N − NH NO + H O
B ⎯⎯ CH A ⎯⎯ CH COOH
C ⎯⎯ HCHO B ⎯⎯ CH
C ⎯⎯ HCHO

b¤^i eÈb:
Mark distribution:
A I B †hŠ‡Mi mswkøó wewµqv ‡jLvi Rb¨ (02×02) = 04 b¤^i|
(02 ×02) = 04 marks for writing the reactions
C †hŠ‡Mi mswkøó wewµqv ‡jLvi Rb¨ 03 b¤^i| concerned with Compound A & B.
A, B I C kbv³Ki‡Yi Rb¨ (01×03) = 03 b¤^i| 03 marks for writing the reactions concerned
[we.`«.t c«fveK/ ZvcgvÎv bv wjL‡j ev fyj wjL‡j 01 b¤^i KZ©b Kiv n‡e|] with Compound C
(01×03) = 03 marks for identifying A, B & C.
[N.B.: 01 mark will be deducted if
 temperature/catalyst is not written or wrong
written.]

imvqb Chem
03 10
Dchy³ wewµqvi mvnv‡h¨ wb‡¤œv³ iƒcvšÍimg~n m¤úbœ Ki: Complete the following conversions with the help of
(a) wg_vbwqK GwmW †_‡K B_¨vb¨vj| suitable reactions:
(b) A¨vwmUvjwWnvBW †_‡K †µv‡Uvb¨vjwWnvBW| (a) Ethanal from methanoic acid.
(b) Crotonaldehyde from acetaldehyde.
(a) HCOOH + Ca ⎯⎯ (HCOO) Ca + H (a) HCOOH + Ca ⎯⎯ (HCOO) Ca + H
∆ ∆
(HCOO) Ca + (CH COO) Ca → 2CH CHO + 2CaCO (HCOO) Ca + (CH COO) Ca → 2CH CHO + 2CaCO
(a) (a)
weKí: 01 Alternative: 01
HCOOH ⎯⎯⎯ CH OH ⎯ CH Cl ⎯ CH CN
HCOOH ⎯⎯⎯ CH OH ⎯ CH Cl ⎯ CH CN
,
⎯⎯⎯⎯ CH COOH ⎯⎯⎯ CH CHO ,
∆
⎯⎯⎯⎯ CH COOH ⎯⎯⎯ CH CHO
∆
(a) weKí : 02
(a) Alternative: 02
2HCOOH ⎯⎯⎯ 2HCHO ⎯⎯⎯ 2CH OH ⎯
[ ] [ ] 2HCOOH ⎯⎯⎯ 2HCHO ⎯⎯⎯ 2CH OH ⎯
[ ] [ ]
সূযােলাক (িনয়ি ত)
2CH Cl ⎯⎯⎯⎯⎯⎯ CH CH ⎯⎯⎯⎯⎯⎯⎯⎯⎯
2CH Cl ⎯⎯⎯⎯⎯⎯ CH CH ⎯⎯⎯⎯
( ) [ ]
CH CH Cl ⎯⎯⎯⎯⎯ CH CH OH ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ ( ) [ ]
∆ CH CH Cl ⎯⎯⎯⎯⎯ CH CH OH ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯
∆
CH CHO
CH CHO
লঘু
(b) 2CH CHO ⎯⎯⎯⎯⎯⎯ CH − CH − CH − CHO (b) 2CH CHO ⎯⎯⎯⎯⎯⎯ CH − CH − CH − CHO
|
|

∆ ∆
CH − CH − CH − CHO → CH − CH = CH − CHO + H O CH − CH − CH − CHO → CH − CH = CH − CHO +
| |

H O

b¤^i eÈb: Mark distribution:

(a) wg_vbwqK GwmW †_‡K B_¨vb¨vj iƒcvšÍi m¤úbœ Kivi Rb¨ 05 b¤^i| 05 marks for completing conversion reactions of Ethanal
(b) A¨vwmUvjwWnvBW †_‡K †µv‡Uvb¨vjwWnvBW iƒcvšÍi m¤úbœ Kivi 05 b¤^i| from methanoic acid.
[we.`«.t c«fveK/ ZvcgvÎv bv wjL‡j ev fyj wjL‡j 01 b¤^i KZ©b Kiv n‡e|] 05 marks for completing conversion reactions of
Crotonaldehyde from acetaldehyde.
[N.B.: 01 mark will be deducted if temperature/catalyst
is not written or wrong written.]

imvqb Chem
04 10
wb‡¤œi wewµqv¸‡jv m¤ú~Y© Ki: Complete the following reactions:

NH2 NH2

(i) +HNO ⎯⎯⎯⎯⎯⎯⎯ + +H O (i) +HNO ⎯⎯⎯⎯⎯⎯⎯ + +H O

NHCH3 NHCH3
(ii) +HNO ⎯⎯⎯⎯⎯⎯⎯ +H O (ii) +HNO ⎯⎯⎯⎯⎯⎯⎯ +H O

NH2 NH2

(iii) ⎯⎯ +H O (iii) ⎯⎯ +H O

NH2 NH2
N C N C
(iv) + + → +KCl + H O (iv) + + → +KCl + H O

(v) H N ⎯⎯⎯⎯⎯⎯⎯ (v) H N ⎯⎯⎯⎯⎯⎯⎯

. .

HO HO
(i) +N (i) +N

CH3 N N O CH3 N N O

(ii) (ii)

NO2 NO2

(iii) (iii)

(iv) CHCl + KOH(alc) (iv) CHCl + KOH(alc)

O
O
(v)
(v)
O
O
b¤^i eÈbt
5 wU wewµqvi Rb¨ (05×02) = 10 b¤^i| Mark distribution:
(05×02) = 10 marks for five reactions.

imvqb Chem
05 10

GKwU †hŠ‡Mi bgybv `ªe‡Y eªvwWi weKviK †hvM Ki‡j njy` Aat‡¶c c‡o| Z‡e Addition of Brady's reagent to a sample solution of a
D³ †hŠM wmd weKvi‡Ki mv‡_ wewµqv K‡i bv| wK¬‡gbmb weRvi‡Y GwU compound gives yellow precipitate. However, the
†c‡›Ub Drcbœ K‡i Ges n¨v‡jvdig wewµqvq Ask †bq| bgybv †hŠMwUi compound does not react with Schiff's reagent. It
IUPAC c×wZ‡Z bvg, ms‡KZ Ges Zxeª Rvi‡Y cÖvß cÖavb Drcv`mg~n wjL| produces pentane in Clemmensen reduction and
participates in haloform reactions. Write down the name
in IUPAC method, the formula and the major products
obtained from the strong oxidation of the sample
compound.

‡h‡nZy eªvwWi weKvi‡K Aat‡¶c → A¨vjwWnvBW/wK‡Uvb As precipitation in Brady's reagent → aldehyde/ketone

‡h‡nZy, wmd weKvi‡Ki mv‡_ K‡i bv → wK‡Uvb Since, does not react with Schiff's reagent → ketone
Since in Clemmensen reaction, pentane is produced →
†h‡nZy wK¬‡gbm‡b †c‡›Ub nq → 𝐶-Gi msL¨v 5 wewkó wK‡Uvb| ketone with 5C.

|| || ||
m¤¢ve¨ CH − C − CH − CH − CH , CH − CH − C − Between probable CH − C − CH − CH − CH , CH −
CH − CH Gi g‡a¨ cª_gwU n¨v‡jvdig wewµqv †`q| ||
CH − C − CH − CH the first one of these gives the
|| haloform reaction.
So, Ans: CH − C − CH − CH − CH ; †c›Uvb-2-Ib
||
[ ]
𝐶𝐻 𝐶𝑂𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 + 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 So, Ans: CH − C − CH − CH − CH ; Pentan-2-one

[ ]
𝐶𝐻 𝐶𝑂𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 + 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻
b¤^i eÈbt
wmd weKvi‡Ki mv‡_ K‡i bv → wK‡Uvb ‡jLvi Rb¨ 01 b¤^i|
wK¬‡gbm‡b †c‡›Ub nq → C-5 msL¨v wewkó wK‡Uvb ‡jLvi Rb¨ 01 b¤^i| Mark distribution:
01 mark for writing it does not give reaction with Schiff's
||
→ ketone.
CH − C − CH − CH − CH ‡hŠMwU n¨v‡jvdig wewµqv †`q ‡jLvi
01 mark for writing pentane in Clemenson reaction → 5-
Rb¨ 02 b¤^i|
C ketone.
†hŠ‡Mi ms‡KZ ‡jLvi Rb¨ 02 b¤^i|
||
†hŠ‡Mi IUPAC bvg ‡jLvi Rb¨ 02 b¤^i|
02 marks for writing CH − C − CH − CH − CH gives
bgybv †hŠMwUi Zxeª Rvi‡Y cÖvß cÖavb Drcv`mg~n
haloform reaction.
𝐶𝐻 𝐶𝑂𝑂𝐻, 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 ‡jLvi Rb¨ 02 b¤^i| 02 marks for writing the structural formula.
02 marks for writing the name of compound in IUPAC
method.
02 marks for writing the major products obtained
𝐶𝐻 𝐶𝑂𝑂𝐻, 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 from the strong oxidation of
the sample compound.

imvqb Chem
06 10
GKwU j¨ve‡iUwi‡Z †j‡ejwenxb wZbwU †evZ‡j B_vbj, B_vb¨vj I B_vbwqK In a laboratory, Ethanol, Ethanal and Ethanoic acid is kept in
GwmW i‡q‡Q| Dchy³ wewµqvmn †`LvI †h, wKfv‡e m‡e©v”P `ywU weKviK three unlabeled bottles. How can identify these three
e¨envi K‡i †hŠM¸‡jv kbv³ Kiv hvq| compounds using maximum two reagents. Show with
 reactions.

B_vbwqK GwmW Ges B_vbj 2,4-𝐷𝑁𝑃𝐻 Gi mv‡_ †Kv‡bv wewµqv K‡i bv| Ethanoic acid and Ethanol don't react with 2, 4-DNPH,

CH COOH + NaHCO ⎯ CH COONa + H O + CO ↑ CH COOH + NaHCO ⎯ CH COONa + H O + CO ↑

C H OH + NaHCO ⎯ No reaction C H OH + NaHCO ⎯ No reaction

A_ev, 𝐎𝐫,

CH CH OH + 4I + 6NaOH ⎯ CHI + HCOONa + 5NaI + H O CH CH OH + 4I + 6NaOH ⎯ CHI + HCOONa + 5NaI + H O

CH COOH + 4I + 6NaOH ⎯ No reaction CH COOH + 4I + 6NaOH ⎯ No reaction

b¤^i eÈb : Mark Distribution:

Dchy³ wewµqvmn `ywU weKviK e¨envi K‡i †hŠM¸‡jv kbv³ K‡i †`Lv‡bvi (05 × 02) = 10 marks for showing, the identification of the
Rb¨ ; (05×02) = 10 b¤^i| compounds using two reagents with suitable reactions.
[we.`ª. : B_vb‡ji kbv³Ki‡Y PCl e¨envi Ki‡j 02 b¤^i KZ©b Kiv n‡e| [N.B.: 02 marks will be deducted if PCl test is showed for
†Kbbv GLv‡b wbwðZKi‡Y PCl Ges NH /NH OH `ywU weKviK e¨envi ethanol identification. Because, for confirmation PCl and
Kiv n‡q hvq ] NH /NH OH two reagents are already used here]