Safety data sheet number 003 Version 3 Revision date 09/Mayi2014 Supercedes date 11/Jan/2008 Safety Data Sheet Soda Ash M3 1. Identification of the substancelpreparation and of the Company/undertaking 44 Product identifier Product name ‘Soda Ash M3 Product code ‘Moos Norway Pr. no. 52700 Denmark Pr. no. 1309326 1.2 Relevant i tance or mixture an is inst Recommended use Buffer in oilfield applications Uses advised against Consumer use ‘i ils of i she ‘Supplier identification ‘Schlumberger Oilfield UK PLC Vietory House, Churchill Court ‘Manor Royal, Crawiey West Sussex RH10 OLU +47 51877424 [email protected] 414 Emergency Telephone Number Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3030, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 261 595 3518 [Denmark [Poison Control Hotline (DK): +45 82 12 12 12 [Germany [Poison Center Berlin (DE): +49 030 30686 700 INorway [Poison information centre: +47 22 69 13 00 2. Hazards identification 2. Classification of the substance or mixture Regulation (EC) No. 1272/2008, Health hazards. Serious eye damage/eye iran ategory2 Environmental hazards Not classified Physical Hazards Not classified Label Elements Page 1/41Soda Ash M3 Safety data sheet number M003 Revision date 09/May/2014 WARNING Hazard statements H319 - Causes serious eye irritation Precautionary Statements - EU (§28, 1272/2008) 264 - Wash face, hands and any exposed skin thoroughly after handling 280 - Wear protective gloves/protectve clothing and eye/face protection P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye imitation persists: Get medical advice! attention 501 - Dispose of contents/container in accordance with local regulations. Classification according to EU Directives 67/548/EEC or 1999/45/EC Indication of danger Xi Iritant R-code(s) R36 Contains Sodium carbonate For the full text of the R-phrases and H-Statements mentioned in this Section, see Section 16. 2.3 Other data_ Not classified as PBT/vPVB by current EU criteria, 3. Composition/information on ingredients ‘Component EC-No, CAS-No |Woight % -| Classification | Classification (Reg. REACH range (671548) 427212008) registration ‘number Somumentonst [areas | ar-i08 60-100 XRG Eye init 2(H319) | Nodata available 3.2 Mixtures _ Page 2/11Soda Ash M3 Safety data sheet number M003 Revision date 09/May/2014 Not Applicable 4. First aid measures 44 First Aid _ Inhalation IF inhaled, remove from area to f. Get medical attention if respiratory irtation develops or itbreathing becomes difficult. Ingestion Rit jthout medical advice. Never give anything by mouth to an unconscious i edical attention if initation occurs. ‘Skin contact ho of water removing all contaminated clothes and toms occur. ye contact soloratiast torn Sockets ninue fo rinse fora Most important symptoms and effects, both acute and delayed General advice ‘The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible. ‘Main symptoms Inhalation Please see Section 11. Toxicological Information for further information Ingestion Please see Section 11. Toxicological Information for further information, Skin contact Please see Section 11. Toxicological Information for further information. Eye contact Please see Section 11. Toxicological Information for further information. 43 Indication of any immediate medical attention and special treatment needed Notes to physician ‘Treat symptomatically 5; Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing media Use extinguishing media appropriate for surrounding material Extinguishing media which shall not be used for safety reasons None known. 5.2 Special hazards arising from the substance or mixture Unusual fire and explosion hazards None known. Page 3/41Soda Ash M3 Safety data sheet number M003 Revision date 09/May/2014 Hazardous combustion products ‘Thermal decomposition can lead to release of irritating gases and vapours, 5.3 Advice for firefighters ‘Special protective equipment for fire-fighters {As in any fire, wear self-contained breathing apparatus and full protective gear. Special Fire-Fighting Procedures Containers close to fire should be removed immediately or cooled with water. 6. Accidental release measures. 8.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment, See also section 8. Avoid dust formation. 6.2 Environmental precautions ‘The product should not be allowed to enter drains, water courses or the sol. Environmental exposure controls, Avoid release to the environment. 63 Methods and materials for containment and cleaning up. Methods for Containment Prevent further leakage or spillage if safe to do so, Methods for cleaning up ‘Sweep up and shovel into suitable containers for disposal. After cleaning, flush away traces with water. 8.4 Reference to other sections ‘See section 13 for more information. . Handling and storage 2.4. Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation, 1.2 Conditions for safe. including any incompatibilit ‘Technical measuresiprecautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture ‘Avoid contact with water and moist air - product is hygroscopic. Store away from incompatibles, Powdered aluminum Strong acids. Packaging material Use specially constructed containers only Polyethylene bag or drum with polyethylene liner Bag with moisture barrier Page 4/41Soda Ash M3 Safety data sheet number M003 Revision date 09/May/2014 See also Section 1.2, 8. Exposure controls/personal protection 8.1 Control parameters ‘Component EUOEL- Third List Austra “Austalia Denmark Sadium carbonate Not determined! Not determined (Not determined Not determined ‘Component Malaysia France ‘Germany Hungary ‘Sodium carbonate Not determined Nol determined Not determined. Not determined ‘Component New Zealand Tay Netherlands Nonway, ‘Sodium carbonate Not Determined ‘Notdeternined Not determined No determined ‘Component Poland Portugal Romania: Russia ‘Sodium carbonate Nol determined Not determined Not determined Nal determined ‘Component Spain Switzerland Turkey UK ‘Sodium carbonate Not determned Not determined Not determined Notdetermined 8.2 Exposure controls All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard ppresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation, Engineering measures to reduce exposure Provide appropriate exhaust ventilation at places where dust is formed, Personal protective equipment Eye protection Itis good practice to wear goggles when handling any chemical. Tightly fiting safety goggles. Page 5/11Soda Ash M3 Safety data sheet number M003 Revision date 09/May/2014 Hand protection Repeated or prolonged contact:, Use protective gloves made of, Neoprene gloves, Rubber gloves, Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment, Effective dust mask, Half mask with a particle fiter P2 (BS EN 143) ‘Skin and body protection Wear appropriate personal protective clothing to prevent skin contact, Eye wash and ‘emergency shower must be available at the work place. Hygiene measures Wash hands before breaks and immediately after handling the product, Remove and wash ‘contaminated clothing before re-use. 0006 9. Physical and chemical properties 9.1 Information on basic physical and Physical state ‘Solid ‘Appearance Powder Odour Odourless Colour White Odor threshold Not applicable Property. Values Remarks pH No informnation available pH @ dilution Metting/freezing point 851 °C | 1564 °F Boiling pointirange Not Applicable Flash Point Not applicable Evaporation rate Not applicable Flammability (solid, gas) Not Applicable Flammability Limits in Air _~ Upper flammability Limit Not applicable Lower flammability limit Not applicable Vapor pressure Not applicable Vapor density Not applicable Specific gravity 25 @20 °c Bulk density 'No information available Relative density 253 @20°c Water solubility 212.59/L @20°C Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature >400°C! 752°F Kinematic viscosity Viscosity, dynamic ‘No information available Log Pow Not determined Explosive properties Not Applicable Oxidizing properties None known. ‘9.2 Other information Pour point No information available Page 6/11Soda Ash M3 Safety data sheet number M003 Revision date 09/May/2014 Molecular weight No information available VOC content(%) None Density VALUE No information available 10. Stability and reactivity 10.1 Reactivity Decomposes by reaction with strong acids. 10.2 Chemical stability ‘Stable under normal temperature conditions and recommended use. Possibility of Hi Hazardous polymerization Hazardous polymerisation does not occur. 10.4 Conditions to avoid Protect from moisture, Avoid contact with water and moist air - product is hygroscopic. 19.5 Incompatible materials Powdered aluminum, Strong acids. 10.6 Hazardot ition products ‘See also section 5.2. 411. Toxicological information 11.4 Information on toxicological effects Acute toxicity Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat and ‘cough. Eye contact Causes serious eye imitation. Skin contact May cause skin irntation and/or dermatitis. Ingestion Ingestion may cause stomach discomfort. Unknown acute toxicity ‘Not Applicable. ‘Component. LD50 Oral D5 Dermal L680 Inhalation Sodium carbonate = 4090 mg/kg ( Rat) No data available No data available Page 7/14‘Soda Ash M3 Safety data sheet number M003 Revision date 09/May/2014 Sensitisation ‘This product does not contain any components suspected to be sensitizing, Mutagenic effects ‘This substance has no evidence of mutagenic properties. Carcinogenicity ‘This substance has no evidence of carcinogenic properties. Reproductive toxicity No information avaitable. Routes of exposure ‘Skin contact. Eye contact. Routes of entry ‘Skin contact. Eye contact. Specific target organ toxicity (single Not classified exposure) Specific target organ toxicity Not classified. (ropeated exposure) Aspiration hazard ‘No hazard from product as supplied. 12. Ecological information 124 Toxicity ‘The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Toxicity to algae ‘See component information below. Toxicity to fish ‘See component information below. Toxicity to daphnia and other aquatic invertebrates ‘See component information below. ‘Component ‘Toxicity to fish Toxicity to algae ‘Toxicity to daphnia and other aquatic invertebrates Sodium carbonate ‘300 mg/L LOSO (Lepomis [242 mg/l EGSO (Nizschia) = 120 h [265 mail ECSO (Daphnia magna) =| rmacrochirus) = 66 h 4h '310 - 1220 mgl. LC80 (Pimephales| promelas) = 96 h 12.2 Persistence and degradability No product level data available. 123 ial Page 8/14Soda Ash M3 Safety data sheet number M003 Revision date 09/May/2014 No data available, 12.4 Mobility in soil_ Mobility ‘The product is water soluble, and may spread in water systems. ts of PBT and vPvB. nt Not classified as PBT/vPVB by current EU criteria, 128 Other adverse effects. ‘None known, [ 13. Disposal considerations 13.1 Waste treatment methods Waste from residues / unused Dispose of in accordance with local regulations. products Contaminated packaging Empty containers should be transportedidelivered using a registered waste carrier for local recycling or waste disposal EWC waste disposal No. ‘According to the European Waste Catalogue, Waste Codes are not product specific, but application specific, Waste codes should be assigned by the user based on the application ‘or which the product was used. The following Waste Codes are only suggestions: EWC. ‘waste disposal No: 16 03 04 - inorganic wastes other than those mentioned in 16 03 03 14. Transport inform: The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,ADR/RID/ADG), in 14.4. UN number Not regulated Not regulated 14.3. Hazard class(es)__ ‘ADRIRIDIADN Hazard class Not regulated IMDG Hazard class Not regulated Page 9/41Soda Ash M3 Safety data shoot number M003 Revision date 09/May/2014 ICAO Hazard class/division Not regulated 14.4 Be m ‘ADRIRIDIADN Packing Group Not regulated IMDG Packing group Not regulated ICAO Packing group Not regulated 44.5 Environmental hazard No 14.6 tions Not Applicable ‘Transport in bul ling to Annex Il \L. 73178 and the Please contact [email protected] for info regarding transport in Bulk. 75, Regulatory information 48.4 Safety, health and environmental res legislation specifi substance or mixture Germany, Water Endangering Hazardous to water/Class 1 Classes (VwVwS) ‘Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/18S/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. ‘This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008. International inventories USA, Toxic Substances Control Act inventory (TSCA) Complies European Union - EINECS and ELINCS Complies Canada, Domestic Substance List (DSL) Complies Philippines (PICCS) Complies Inventory - Japan - Existing and New Chemicals list, Complies China (IECSC) Complies Australia (AICS) Complies Korea (KECL) Complies Inventory - New Zealand - Inventory of Chemicals (NZIoC) Complies 15.2 Chemical Safety Report No information available Page 10/14Soda Ash M3 Safety data sheet number M003 Revision date 09/May/2014 16. Other information Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Nicola Anderson ‘Supercedes date 44/danv/2006 Revision date ogiMayi2014 Version 3 ‘The following sections have been Updated according to GHS/CLP. revised ‘Text of R phrases mentioned in Section 3 R36 - Irritating to eyes Full text of H-Statements referred to under sections 2 and 3 H319 - Causes serious eye imitation Disclaimer The information contained herein is considered in good faith as reliable of the date issued and is based upon on ‘measurements, tests or data derived from supplier's own study or furnished by others. In providing this SDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the ‘maximum extent permitted by law, supplier’s warranty obligations and buyer's sole remedies are as stated in separate agreement between the parties. Page 11/11