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Alcohol Synthesis and Reactions Overview

The document discusses the reactions of alcohols as electrophiles and their interaction with bases, highlighting the excellent yields obtained in various reactions. It also covers the conversion of secondary and tertiary alcohols into ketones, the use of different reagents, and the importance of conditions such as temperature and pressure in these processes. Additionally, it touches upon the mechanisms of esterification and the reactivity of alcohols in different chemical environments.

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anshbagaria15
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78 views3 pages

Alcohol Synthesis and Reactions Overview

The document discusses the reactions of alcohols as electrophiles and their interaction with bases, highlighting the excellent yields obtained in various reactions. It also covers the conversion of secondary and tertiary alcohols into ketones, the use of different reagents, and the importance of conditions such as temperature and pressure in these processes. Additionally, it touches upon the mechanisms of esterification and the reactivity of alcohols in different chemical environments.

Uploaded by

anshbagaria15
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

ALlOHOL PHEnbL &ETHER

DATE:

Notes
Protorated alcokols as eletphiles
NaoH
they react as eletiophiles.
hhO4 +
3 CH
ntacten, aleohol Bn e****c**.

In tu yied.
obtained in eaccellent
R- HO+ H
ane bronates
açido , ie, they cam donate a protn
ty to a a b s n n base.
ercellent yield k
in
atrony eduey Bcidie chasacter eleohol iscdue
to the polar natuhe y o-H bond.
eageut &thete e gpeielemicals fodium ethontde, la a abengu
acds
"Cosmnecially, audo ara reduj bae tha oodium gduentd
accegar them lydmide lem
to eatone folowes bytheet redut hgrideo anethsnger bae
tham golnoude
atalyatlonblytiebydroge)
Meeelo at a brenstes bases as
atkyR-HOH uell.t io dee to t e tne ot
whieh alees tein prten acpta
oleu
he reaction e! phenol wutth aaueo
odiun tuydroaide lindicates that
phts are stonge aldo tan
-Diagonium salta are bydroyaed alohols uater
by trety cuith dilce aeld. thogh there ia albo chage
deloalatin in phnol, io ionane

cumone wahmtelene) otable tham plenotde im


ydroGnide also taines
dr/RoH + R'-cooH r/RoLoR't Hro
Mioho ae veastie compum Ar/k-oH +(R'c)0 r/kOCOR'
+RCOOH
nucleepllee
slestrophiles.nueleophiles The eaterifiat"nn aleshel it
C-As & aitd amhyide io caied
obokeen. ut in the tne of a smal amout
onem*****o*
Motes
R/AroH+RCOu araoR
DATE:

2° ale ae sridns to keones


by eomie ana dride (oo,)
Te n with acid chloe 3 de dont wmdgo Gocidot
aQaePyuda) asto netnaia nder S-o-# &dastii conc

aide
takes plae & amnne

Aetylat" aalloylie acid prduces


akoylie aid
no eutoimed.
lese
anbem atns io ormed
S73 K

3* CHyLOH
S73k

Slaget cone Ha +zucle delydut


delydrat
egholromaenes
DA

n ating with protie aid


ehas amhye
ateam ditillat

2°& 3alcghole dbgatd


neermildlen comotiu Preparal poni ais neuadaya
CHh-CH-Hs 440K H2say O
SogH
+ho
358K.
(Ot2H2-oo-30atm
S73673k
9n the mehamiamm sf oletydut",
fotut anboation the alowest
alep B linee t sae oletemimny
ynas>LoH + 0
Cro3mandd. mediuio wsed
as O:A o oolat old. Fermentatiom takes lae m
--RhOH-0,RHO, anaercaie condition, ie, in abuon
A better reagent fa rida Atiom me, o nhgited omce
of 1°ae ad in goed yeeld
6enetat" mitara, theetoe
CHz- H=4-CnoH W-C=4-cHo wli in twm det-o the
DATE:
eunentat alestet io made wnft Wotes
CNy, miciy,
alßhate
nit
(Vto gine
CHy-I +eHyOH

colewr
melling pnidine Ca Paet
qudj.
devtition f aliohol.
HaSoy
CH,
443k niroe mdorgee bilgmination
with boomine n ethanoc a
413K

due Ao the aiuat bengene


Tre metho io
ing by the metthery ggp.
itade for the prepat -fasa tsomen o btanet m
ethgro hainy iimay'aey grep

Fuillismasn aytheois attk


lnuvlweams allegide Gthangie
Br
Ethens coutaininy subatitatd aey huisole wndergoea Fc alkyat2
opa
thu
a)may also be prepaned
etthod.
Better eoultt ae sltaiHes Ef th
&3 atkythaide, elm
Compele ouer
3 e hade subatituter 2f
io wed, e ltkeme

ore.ot
a el. 7hey eat
elimim balido lehdiy to
Miaceulity of etheu with wator
9esembls thee 9falesho
e e molealar masa
Stthe are e leant reatiue
Te eagefmctigmal g
cobsus in ethe
taleo
goge laidea
TROR+HX R-X+RoH
Teden e! ractiuity HXo
IHer>Ha. lenge et
aees_lace cth cgne HI

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