= ALLEN SRGBT | JE (MAIN+ADVANCED) 2024 WURTURE COURSE ert 023 aru as CLAS: HINTS AND SOLUTION PART-1 : PHYSICS 1. (A) Sol. Conceptual. 2 (Dd) Sol. Change in the intemal energy of from A to Bis AU = nC AT = 5P,Vy and Heat oxchanged sue w =Py,( 2285) 3. (A) Sol. of mais balanced by of ion mg x mgxx=fxl=>f= 1 directed towards mid-point of PN. F., =-mo’x for SHM f =-mo’x 4. (D) Sol. Atthe displaced position ro S (88) $8) SRGBTgx (acy 4 Vertical foree = gf pLxdy = a pl-vHy dy 0 H & Horizontal force is (0 (ac) (ac) Ifx be the initial length of the gas chambers & A be the area of cross section of the cylinder then, My = Also PA = 2h =2 =2kx = PV, = 2kx? 2 Fran Kx? = 2k? = PV, Similarly, P,A = ae Se Vo P\A =2k—2 A =Ht-¥p-By, Po Vo Vo Now -.Q=dU+W =23(nV, -PV,) +w =12PN, SRGBT9. 10. te PV =nkT 1. AB, T = constant, = PV = constant. Now p increases = Vdecreases . Pincreases. cout of Aand B, Ais true. BC: pT = constant P= constant +. out of Cand D ; Cis true. -. Ans. A, C (ABD) (AB) por): Toy B feral ale A NE Na 2 VE Lica ata? For (B) gla) = gikey For(C): Net possible [¥="] 1 = ska? For (D) :TE= 5 (A.D) Total displacement along x-direction 1-cos eat) = Sem2 01+ 30 cordon 20 = constant Then y, = 10 cos at & 2-10 + 10cos2at ao 4 =10+y, motion will be linear in y-z plane. Resultant amplitude = SRGBT12. (BCD) 2 Sol. co = 2m" ‘a(requation) 2 Geel] Energy stored = KE,,...—KE -int,(Pexf ind ? 26 eB 14. (18) Sol. A,V, = A,V,>Vq Pat paha + BVA = Pa + pahe +5 VB Py ~Py = 18KPa 15. (3) Sol. Speed just before collision =o8 2 Speed just after collision cnn [EL 4 m 4 16. 6) Sol. F,=F, 2 #=[pawianta-n(e(%4)) ates SRGBTpoe = acm + Rae = ee M * _(0,06)(100}cos10¢ [Forno sipping] 2) RAIR) fy > upward thrust due to lig. (1) fg — upward thr ci be due to liq (2) a Plank (i Ai) SRGBT19. Sol. 20. 21. Sol. Sol. PART-2 : CHEMISTRY © Hin =H" + In K, =5x10° TIO) yey x, Ho) [Hin] tr] (H*] = 5 x 10° x 20 (H"], = 104 5 K, IH"), = 2x10? =1.25%107 pH range +4 to 6.9 (D) NH,OH=—NHj + OH. 1 0 0 tru oa c(t -a) ca co [OH] = co = ®.01-005M 100 K, of Zn(OH}, = [Zn**] [OF {OH ] being common ion, solubility of Zn{OH), will decrease. = 1x10" = [ni] 10.05)" [Zn] = 4 x 10M. Solubility of Zn(OH), = [2Zn**] = 4 x 10 M (D) (90-60) = [Link] in 100 ml yemx+e 30 mass in 40 mi = 755 x 40 y= 60at20°C = 129m y= 90 at 80°C ) [CH,COONa] _ (CH,COOH] (B) NaOH + HCI Solution will be acidic and pH < 7 0.1Vmm 0.2Vmm (A) pH = pk, + log 1 (C) So solution willbe basic and pH = = (pK, + pK,~ pK.) = 7 (D) CH,COOH + NeOH MV mm 2MV mm (BC) CH,COO"Na* = 20 mmol a Nota buffer solution OH ions = 10m mol SRGBTSol. 27. Sol. 1 oe (eel ut {Ot jons =10mmolf C2? mmonium buffer NH,Br = 20 mmol i NH, (ii) NaOH = 10mmel} resultant solution has { H’ jon 8mmol This can still act as buffer Na,CO, = 8 mmol (©) Hejons = Simmolf C%2teS NaHCO, solution which s alkaline (pH = 7) in nature. (Bc) [Ag*] for AgCl ppt = 3.4 x 10° molar & for Ag,CrO,, (Ag*) is 6.16 x 10M. (ABCD) 101 C= 0.1 IH ]= JK, C,+K,,C, =2x10° pH =2.7 (ABC) (H')[HA") (H,Al At pH=3; K, = 10% _jgo HAT Pe AL => [HA] = 1000 [HA] at pH = 6; [HA] = [HA] => at pH = 6.5 [HA] > [HA] at pH = 10; [A*] = [HA] This mean [HA] is very small hence[A*] can not be maximum. Option (D) incotrect. (AB) 4 fsaltllacial iy: | 2S. Butfer capaci ables) mosis [ [salt] + [acid] (pH) SRGBT29. Sol. Sol. 31. (ac) Theory based. (AB) (A) Comect {B)NaCN + HINO, > HCN + NaNO, Remain LR Form Acidic Buffer {C) pHof 0.1 MNa, HPO, is (D) AgCl = Agt + Cr ‘Ag* + 2NH, = [Ag(NH5), ]* 2 pKa, +pKa; Solubility of AgCl increases in presence of NH, (BC) De When base is (3) neutralised Pa, He RIL. = + ha at a ~ 5 (a/5) POH = pk, + bog| gag 2) pk, = 56 1 = 3 K,-pK.-logC]> 4.5 x2 = (14-56 - log) logC = -0.6 C=0.25 Let V ml of HCI is used 05SxV V+100~ V=100 ml ‘[Link] of acid = [Link] of base 0.5 x 100 = 50 0.25 Wt. % of base in sample = “ ie 25 (100) [Salt] He PK + 8 Rl 300-x x = 45=42 + log ee eee 50x10 x45 x100= 90 SRGBTSol. gs gs oR Sol. 300 = 300 - = bog 2 = log “VEX, 2. 800=x x x => 2x =300-x = 3x =300>x= 100ml @) [Mg'?] [OFF] = 10% [OH] a Ky =[2n? IS] HF IS?) For K,,.K,, = TH,SI 19 1 10” = [HP e(H*]=0.1M or pH =1 (3) ForSalt, M,(S0,), bogiM] = Rog, = {logSOF 1 On calculating , y= 1 (0.09) AgBr(s) + 2Na,S,0, —>Nag[Ag(Si0,)2]+NaBr t=0 02M 0 0 t 02-x x2 x2 Ky Kr = “ 0.2-x Onsolvingx = 0.1774 0.177 =0.088mole "br (4.05) 4HON + Ni®* ==[Ni(CN),}? +4H* Kat x Ky 0.1 mole 0.025 mole 0 oO O.1-4x 0.025-x x 4x xx(4x)" (4.9 107)! x 10% =~ (0.1 =4x)*(0.025 =x) SRGBTay'x® (4.9) x 1078 = 0.025 116.0741 x 0.025 5 c= POPE xd =8.95%10 pH = -og(8.96 x 10°5) = 4.05 © (4)'(0.025 =x) SRGBT 10gs gs PART-3 : MATHEMATICS Co) Jog, (25° -1) = log, 4+ log, (5° +1) (a5y*-1 = 45" +1) P-1=4t+ave=5 P-4t-5=0 a+B=13 ap = 23 = PP-14B-0+23+18 = p?-14p-a+41 oF 1a+28+2=0% -130+23 +20.+ 28-21 =2(a + p)-21 =5 BP 148-441 = p*—198+23-B-a+18 -la +p) +18 13 +18=5 X-(5+5)x+5x5 =0 x 10x + 25=0 (a) x -3x+1=Oanda,=a"+ B"-1. _ (a2 +B (ae +B°)— ("a +B)—(a +B) (a? +B") (a +B) Buta. + B = 3 and af = 1 so required value SRGBT ve13|x| +4 Px? = 13x] +4 = Stan 9°19’ | are fourreal rots sum of real roots = 0 ~4)(4) _ 16 product of roots (-1) (+1) Ae - Ro 42. (A.C) Sol. x'= Gx +27 +m? =0 Lot roots be a-34, ad, atd, a+3d Sum of roots taking are ata time =4a=0=a=0 and product of roots (a” - 9d°}{a” - d”) = = 9dh=m? = #-+(2) Now asa = Oso, roots are “3d, ~d, d, 3d and sum of roots taking 2 ata time is 10d? = ~(3m + 2) 10m = e(2)eme => +(10m)=9m+6 6 = m=6orm=—75. Option A, Correct. 43. (AB) Sol. As 2x" + 4xy + Ty? + 12x-2y + t=O has exactly one solution (x, y) = equation (i) represent a pai of straight ines (non-parallel). Partially differentiating (i) w.r.t. x and y. weget ft EB oaxeay-12=0 K SRGBT 12gs ft and [= 4x+Hy-2=0 im solving (ii) and (ii) we get (x, = option A, B correct. (A, C, D) 1 7. ASB. 2840, 4p 37. 28-7 =(A-D) 2° +(2B-A)+(2C-B).2"* (2D-C)2"? = (2B-A+7)+(A-D)2*'* +(2C-B-7)2"’* +(2D-C)2"" = 2B-A+7=A-D=2C-B-7=2D-C=0 = A=D=1, B=-3, C=2 (A,B,C) 1 3, 8 gilbert $= 8 =32 ‘There isa possibility ofa solution x = 3 3 Ae For this value, LHS = 3% 34 =32 = RHS. isasolution, which isa sve integer. 3 5 Next, [Zea x}? +logg x= 3 )oas x 2 = [3ilogs x)? +4logs x —5]logsx -2=0 =36 +42 —5t-2=0-[t=log5x] 338-30 +7 -714+2t-2=0 Gt +7t+2Ht-=0 + BteI(t+2H{t-1)= 0 Ste 1-2-3 3 logsx=1 Sx23 32,519; x3 ‘Thus, there is one +e integral value, one irrational value, two positive rational values. (ABC) We have ax + by = 1 y= Putting this value in the second equation, we get SRGBT 1347. Sol. gs 49. Sol. aad ot + ig (l-ax)=1 => (bc + a’d)x”—2adx + d-b" =0 a This quadratic equation will have equal roots if Dj= 40d) — albre + a'd) db.) = 0 = ald’ + (be + atdjb?— bred — ard => bitte + a’d—ed] = (A.C) e 4438 _ death x= Te = 28-1 a (c+ IP = (28) ox8 +142 = 12x24 2-11 20 .a=2, be-1l 44+3v3 4+3V3 pee ne Bad: itx= given g (x) =x" + 2x°— 10x" + 4x —10 {St =) Std; tx Se thenx? +2x-11=0 +g (x) = (x? + 2x—-11) (x? + 1) + 2x +1 = 4VS-1) (B,C) 3x7 =15x +18 = V28—-x) 3x? — 15x + 18 = 29 -6x + x°) X-3x=0 > 03 ® 2+ 10 + ax+b=0 X44 tax te For common roots : +1 tax baX +4 tax te = 6x + (b= 0) = Let the two common roots be ct, B then sum of roots of (i) =a+p=0 Now let third root of (i) is y and that of (i) is and then : For (i) a + B+ y=-10 > y= -10 For (i) a+ B+ b=4>3=-4(0a+4+B=0) 2 75 = 40-25 5-8 seve) SRGBT 1451. (log, (r+1))(loa, (r+ 2)) Joga (r+ 2) = log (r +1) fog, (r+ I)log, (r+ 2) aa Teg loge) 1 1. (—q,2 fog, 14 Te joq53 oa, 4 1 1 Tw" jGg,16 toap 162 log, 162—log, 2 _ Sum = (fog, 162Mfog, 2) (8) SRGBT 15Sol. Product of roots = 57 == (1) afta = oa 2a 2a+1_b Sum of roots = 37g +5 = 2 2) eta, 2b = da hte a = [a to)’ + ac = 2be + Zab (c+) * ab+be~2ae 54. (9) Sol. t+ PE 4 (Be Togigx = 1 letlogy sx) = h+ £4 jae t=1 2 = ju te-i-yrt 2 ‘on squaring, we get 2S 1434-2 = f-3tt-2en = 46 +9 = (245) fi > +494 F +3t (25)""" = 9. Ans. SRGBT 16