Cha CH
É
CHz
g Cet
Chi
C
CH CH CH
CL
g 6h
on
um
Itisaspecidtypeffctional
isomerism
which the in
isomers
convertible s
inter
are
hence
readily maintain a
dynamic
they
with each other Hence
equilib known as
this phenomena is
DIAMICISOMERISM
4341011 1 4,04
Tautomerism is caused by
monovalent atom
Migration of
a
H D b w two
Mostly
atom with necessary rearrangement
of linkage
CHEECH
ÉÉÉcH keto
nob
migration TIFF
1,3
c o
C O
O H
C H
c c
C c
STEM 1,2 Migra
DYADSY
C L H I
H
isocyanide
oh
gaff a
Aci nitro
NITRO
Ismet
R CHIH
B
NEE R
[Link]
4Panisnet
Examine
Ene amine
AEDILE
FRID ketone tautomer
Acid catalysed
Base Catalysed
mechanism
mechanism
tc
gy co
C d H
OH
Mechanism CBase
BE
ÉÉÉI
ÉJ
Acidic
to teach
ÉÉÉ enoliate
n
I I
pÉ
t
Benzaldehyde
st Cecil
cumulated diene
unstable
Kentner
product
pagehemodynamic
Has
n Feat
CROTONALDEHYDE I
CHECH
CH ÉH
HE
41
9 9
0
Eate famas
E 11
n
be than
rn can't faster
I
toy
I 1 9 I
Intermediate
g
rate account
[Link]
I ratefmnxstab intmedat
L H is not
presence of tautomer's
related to formation of
always s
L H is not sufficient
condition fertatemesis
necessary
Acidic H
Look at
Always
AR P steps
as
to R
IjPp exp
fond
fintemedit
op
no [Link]
m T
LI
OFF
Hi MIA
It
07808ft
Egotist
too
o
I
on
Is
Qidi
i
x
o
eh Acetophenone
Ph É Ph Benzophenone
six
an
É
0
Once
I
G I r d e
a b
Te
InnostMg
enol form is negligible
CH É CH I CHEECH
100 10
4
f
10
41
i
tequilibfusableinbacked
Reson
ight end
11
Htc at c
Mo H tee
C o
359 Kcal mal 347kcal mere
y
12 kcal male
difference
or 50 KJ mol
DH 50 KJ mal
endothermic
enol
keto
Keto form is
thermodynam
stable cally
more
5015 mal
than
enol form by
É
E3
p
canoe
EI
set
again
EEE
strong
[Link]
to weak Acid s
I
C 1.3
CH C CH I CHz
wand faded
1 ec ascEiIcistrm
or dominates
hatamoto
form
over keto
not 50 KJ
cameo
NRJ
011 100
I 100
I Aromaticity
so iso
kJ
J y 50 2
All
It Edo
dominates
11
É
50
FEE
3
II HE
it
I i
lies in enol
mere
Jepulsion
key
Mono carbonyl
In
conclusion is
compels
enol negligible
T
i
enol form dominates for cyclic
ketodominatesforacult
ÉEE
H Bond
50
N chelation
chelation
ring formation stabilising
5,6 memb
sing
8 8
É
9 II
rotation
cry 9
cant
allowed
syn assume thisfem
t
no te
Budig
significant
HickIi
is
Acetone AA
Acetyl
Aet
cycodattany
Acetone
etc y ÉIÉI yk
Aceto acetic ester or
Ethyl Acetoacetate
E A A
ester AztoAceti_cAi
of
sc qec
on
I CH
I cha 011
t.A ACY I 4
X tn
ham
t
Eye
Is
vinyl
CRICH
allyl
Cha
CHICK
ÉÉ É
TÉ
241 Bond
50th R ETH
NKT it
chelation
iiI
8f I
921 Rie
us
igi
[Link]
cs
CH
a methyl Acetyl Acetone 44 f
Éenefaane
m
er me
H
o i
ICI e
n
Me 1
repulsion
Me
steric
É Eg I n
Es ch
EH I o CH EÉÉÉo er
1
is
Aldehydestetoneyester
É oÉg keto
H É z É H Aid aid
t o
us I co
CH I co É 7
och
CHO
I Ifc's
Ph d cha
É Ph
conjugation
Carded
ie
dit
apply Acidifule
I II I I IV V
D
E Fam
IED
Eet
E
E e
are_
dire
[Link] t
[Link]
Wo tE
f end
of AA gay
er cheaters
[Link] enoe PPS
NPS
PAS Non Pola
polar Aprotic
[Link] alkane
95Acetone4 cycloalkate
thy
NH3
cry É CH benzol
ROH pi methyl sulphur'll
oxide allyl
DMSO Deville
CH
H É N
CH
N N dimethlformamide
DME
N
TMI
de
CA 43 AMPA
Hexa methyl phospheramide
Ijpads
nips
i
Hy
1h0oh strayed
Carbone
oxygen
enol
TÉÉÉ
content is least
c
M water competes with
because tho molecule
intermolecuk
Carbonyl oxygen
and can form
H bond be
DMF there can
In PAS like b w the carbonyl
dipole dipole attractionMolecule
and solvent
oxygen
there is no engagement
M NPS
carbonyl oxygen
of solvent increales
Hence polarity of
YH
c c's
3 3 3
CH
II
ca ch
enol
Tsoi
Conc 11505
Aso
dilksonchyAcid
atalysed ated
enol
enolate
i
f
i
intermediate
I
compds
giganent
later
Liang
Chi
I I ar e as
as
g
ti
Teniente
I let R
R Coo
a
É
