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Physical Chemistry By Sudhanshu Kumar Sir DPP: 8
Structure of Atom
Q1 In the Schrodinger's wave equation ψ represents Q5 The total number of subshells in fourth energy
(A) Orbit level of an atom is
(B) Wave function (A) 4 (B) 8
(C) Wave (C) 16 (D) 32
(D) Radial probability
Q6 How many electrons can fit in the subshell for
Q2 Match column I with column II. which n = 3 and l ?
= 1
(A) 2 (B) 6
(C) 10 (D) 14
Q7 Maximum number of electrons in a subshell with
l = 3 and n = 4 is
(A) 10 (B) 12
(C) 14 (D) 16
Q8 The maximum number of such electrons in an
atom with quantum number n = 3, l = 2 is:
(A) 2 (B) 6
(C) 10 (D) 14
The correct match is
(A) a(iii), b(i), c(iv), d(ii) Q9 The number of orbitals in n = 3 are:
(B) a(iii), b(i), c(ii), d(iv) (A) 1 (B) 4
(C) a(i), b(ii), c(iii), d(iv) (C) 9 (D) 16
(D) a(i), b(iv), c(ii), d(iii)
Q10 For each value of l , the number of ml values are
Q3 Orbital angular momentum of electron in (A) 2l (B) nl
5 d
z
2 orbital (C) 2l + 1 (D) n − l
–
(A) √5 ℏ
– Q11 A subshell with n = 6, l = 2 can accommodate
(B) √6ℏ
– a maximum of
(C) √2ℏ
(A) 10 electrons (B) 12 electrons
(D) Zero
(C) 36 electrons (D) 72 electrons
Q4 Total number of orbitals in any shell is given by
Q12 The correct designation of an electron with
(A) n
,
n = 4, l = 3 m = 2 , and s = +1/2 is:
(B) n2
(A) 3d
(C) 2n 2
(B) 4f
(D) 2l + 1
(C) 5p
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(D) 6s (A) If the value of l , the electron distribution
= 0
is spherical.
Q13 A 3 d-electron having s = +1/2 can have a
(B) The shape of orbital is given by subsidiary
magnetic quantum no:
quantum number.
(A) +2 (B) +3
(C) The Zeeman's effect is explained by magnetic
(C) -3 (D) +4
quantum number.
Q14 The orbital angular momentum for an electron (D) all of the above.
revolving in an orbit is given by
−−−− −− Q19 The correct set of quantum numbers for the
√ℓ(ℓ + 1) h/2π . This momentum for an s-
unpaired electron of the chlorine atom is
electron will be given by
(A) + 1 ⋅
h
2 2π
(B) zero
(C) h
2π
–
(D) √2 ⋅ h
2π
Q15 The number of orbitals in nth Bohr orbit of an
atom equal to (A) 1 (B) 2
(A) n 2
(C) 3 (D) 4
(B) 2n 2
Q20 Azimuthal quantum number for the last electron
(C) (2l + 1)
in Na atom is
(D) (3l + 2)
(A) 1 (B) 0
Q16 g -orbital is possible if (C) 2 (D) 3
(A) n = 5, l = 4
Q21 The quantum numbers for the outermost
(B) it will have 18 electrons
electron of
(C) it will have 9 types of orbitals
an element are given below
(D) all of the above.
. The atom is
1
n = 2, l = 0, m = 0, s = +
2
Q17 (X) Matching Column Types (A) hydrogen (B) lithium
(C) beryllium (D) boron
Q22 Magnetic quantum number for the last electron
in sodium is:
(A) 3 (B) 1
(C) 2 (D) zero
Choose the correct option from the following Q23 For a d-electron, the orbital angular momentum
combinations is
(A) 1-P, 2-Q, 3-R, 4-S, 5-T –
(A) √6 ( 2π
h
)
(B) 1-T, 2-S, 3-R, 4-Q, 5-P –
(B) √2 ( 2π
h
)
(C) 1-S, 2-T, 3-P, 4-Q, 5-R (C) ( 2π
h
)
(D) 1-P, 2-Q, 3-R, 4-T, 5-S
(D) 2 ( 2π
h
)
Q18 Which of the following statement about quantum
Q24 The principal quantum number of an atom is
number is correct?
related to the
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(A) size of the orbital Q30 Statement-I: The orbital with l = 0 is spherical in
(B) spin angular momentum shape.
(C) orientation of the orbital in space Statement-II: Azimuthal quantum number
(D) orbital angular momentum describes the shape of an orbital which is
according to the quantum theory, in the space
Q25 The angular momentum of electron in ′ d ′ orbital
around the nucleus.
is equal to
(A) Both Statement-I and Statement-II are
(A) 0 h
–
correct.
(B) √6ℏ
–
(B) Both Statement-I and Statement-II are
(C) √2ℏ
–
incorrect.
(D) 2√3ℏ
(C) Statement-I is correct and Statement-II is
Q26 The total number of orbitals present for principal incorrect.
quantum number, n = 4 is: (D) Statement-I is incorrect and Statement-II is
(A) 30 (B) 12 correct.
(C) 15 (D) 16
Q31 The maximum number of electrons which can be
Q27 Given below are two statements: one is labelled held by subshell with azimuthal quantum number
as Assertion A and the other is labelled as “l” in an atom is given by:
Reason R: (A) 2l+1 (B) 2l+2
Assertion A: For n = 3, l may be 0, 1 and 2 and m (C) 2(2l+ 1) (D) 2(2l + 2)
may be (0, ± 1 and ± 2).
Q32 The correct quantum number of 3p-electrons,
Reason R: For each value of n, there are 0 to (n –
are:
1) possible values of l; and for each value of l,
(A) n = 3, l = 2, m = 2, s = +
1
there are 0 to ± l values of m. 2
(B) n = 3, l = 1, m = −1, s = −
1
In the light of the above statements, choose the 2
(C) n = 3, l = −2, m = −2, s = +
1
correct answer from the options given below: 2
(D) n = 3, l = 1, m = −2, s = −
1
(A) A is true but R is false. 2
(B) A is false but R is true. Q33 The set of quantum no. not applicable for an
(C) Both A and R are true and R is the correct electron.
explanation of A. (A) 1
(B) 1
2, 0, 0, −− 3, 1, −2, +−
(D) Both A and R are true but R is NOT the 2 2
correct explanation of A. (C) 1
(D) 1
4, 2, −2, −− 6, 0, 0, +−
2 2
Q28 How many electrons can fit in the orbital for
which: n = 3 and l = 1? Q34 Match the column :
(A) 10 (B) 14
(C) 6 (D) 2
Q29 What is the maximum number of orbitals that can
be identified with the following quantum
numbers?
n = 3, l = l, ml = 0?
(A) 2 (B) 3
(C) 4 (D) 1
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Choose the correct answer from the options Q40 Any f-orbital can accommodate upto
given below : (A) 2 electrons with parallel spin
(A) A − P B − R C − Q D − S (B) 6 electrons
(B) A − R B − P C − Q D − S (C) 2 electrons with opposite spin
(C) A − R B − P C − S D − Q (D) 14 electrons
(D) A − P B − R C − S D − Q
Q41 Match the column:
Q35 Splitting of spectral lines under the influence of
magnetic field is called:
(A) Zeeman effect
(B) Stark effect
(C) Photoelectric effect
(D) None of these
Q36 The quantum number not obtained from
Schrodinger equation is:
(A) n (B) l
(C) m (D) s
Q37 The correct set of four quantum numbers of a
Choose the correct option from the following
3d− electron is
combinations:
(A) n = 3, ℓ = 2, m = 0, s = +1/2
(A) 1-P, 2-Q, 3-R, 4-S
(B) n = 3, ℓ = 3, m = 0, s = +1/2
(B) 1-Q, 2-R, 3-S, 4-T
(C) n = 3, ℓ = 1, m = 2, s = +1/2
(C) 1-Q, 2-S, 3-R, 4-P
(D) n = 3, ℓ = 1, m = 0, s = +1/2
(D) 1-T, 2-S, 3-R, 4-P
Q38 Consider the following sets of quantum numbers
Q42 The maximum number of 4 d-electrons having
spin quantum number s are
1
= +
2
(A) 10 (B) 7
(C) 1 (D) 5
Q43 Which of the following sets of quantum numbers
is correct for an electron in 4f orbital?
(A) n = 4, l = 3, m = +4, s = −1/2
(B) n = 4, l = 4, m = −4, s = −1/2
Which of the above sets of quantum numbers is (C) n = 4, l = 3, m = +1, s = +1/2
not permissible? (D) n = 3, l = 2, m = −2, s = +1/2
(A) II, III only
(B) Only I Q44 Any p-orbital can accommodate up to
(C) III and IV only (A) four electrons
(D) II, III and IV (B) six electrons
(C) two electrons with parallel spins
Q39 Maximum number of electrons, that can be (D) two electrons with opposite spins
present in a d-orbital is
(A) 2 (B) 10 Q45 If protium, tritium and deuterium have one
(C) 8 (D) 6 electrons then the spin quantum number of that
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electron is; The shapes of dxy, dyz, and dzx orbitals are
(A) + 2 1
similar to each other; and dx2 – y2 and dz2 are
(B) + 2 or − 2
1 1
similar to each other.
(C) − 2 1
(B) All the five 5d orbitals are different in size
(D) None of these when compared to the respective 4d orbitals.
(C) All the five 4d orbitals have shapes similar to
Q46 Match List I with List II the respective 3d orbitals.
(D) In an atom, all the five 3d orbitals are equal in
energy in free state.
Q52 Which of the following pairs of d-orbitals will
have electron density along the axes?
(A) dz 2 , d x 2 −y 2 (B) dxy , dx 2
−y
2
(C) dz 2 , dxz (D) dxz , dyz
Choose the correct answer from the options
Q53 Among the three types of orbitals p, d and f
given below:
(A) Both p and f orbitals have center of
(A) A-II, B-I, C-IV, D-III
symmetry.
(B) A-I, B-III, C-II, D-IV
(B) Both p and d orbitals have center of
(C) A-III, B-IV, C-I, D-II
symmetry
(D) A-III, B-IV, C-II, D-I
(C) Only d orbitals have center of symmetry.
Q47 Two electrons occupying the same orbital are (D) F orbitals alone have center of symmetry
distinguished by:
Q54 Which of the following is incorrect?
(A) Spin quantum number
(A) The allowed vibrations of an electron in 3D
(B) Principal quantum number
space is known as orbitals.
(C) Magnetic quantum number
(B) All s-orbitals are spherical.
(D) Azimuthal quantum number
(C) All p-orbitals have 2 nodes.
Q48 Calculate the spin multiplicity for H-atom (D) All p-orbitals are directional.
(A) 10 (B) 2
Q55 Which orbital has two angular nodal planes:
(C) 5
(D) 11
2 (A) s
Q49 The number of lobes in most of the d orbitals are (B) p
(A) 6 (B) 8 (C) d
(C) 10 (D) 4 (D) f
Q50 What is the shape of orbital having radial node Q56 An orbital with orbitals angular momentum zero
one and n = 3? and three radial node
(A) Spherical (A) 3s (B) 3p
(B) Dumbbell (C) 3d (D) 4s
(C) Double dumbbell
Q57 Assertion (A): 2p orbital does not have any
(D) Complex
spherical node.
Q51 Identify the incorrect statements from the Reason (R): The number of nodes in p-orbitals is
following. given by (n – 2) where n is the principal quantum
(A) number.
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(A) Both Assertion (A) and Reason (R) are True (C) n = 3, ℓ = 2, m = −2, s = −
1
and the Reason (R) is a correct explanation of (D) n = 4, ℓ = 0, m = 0, s = +
1
the Assertion (A).
(B) Both Assertion (A) and Reason (R) are True Q62 The electrons identified by n and l
but Reason (R) is not a correct explanation of (i) n = 4, l = 1 (ii) n = 4, l = 0
the Assertion (A). (iii) n = 3, l = 2 (iv) n = 3, l = 1
(C) Assertion (A) is True but the Reason (R) is can be placed in order of increasing energy, from
False. lowest to highest
(D) Assertion (A) is False but Reason (R) is True. (A) (iv) < (ii) < (iii) < (i)
(B) (ii) < (iv) < (i) < (iii)
Q58 For radial probability curves, which of the (C) (i) < (iii) < (ii) < (iv)
following is/are incorrect? (D) (iii) < (i) < (iv) < (ii)
(A) The number of radial node in 2 s orbital is
one.
(B) The number of spherical or radial nodes is
equal to n− l − 1
(C) The number of angular nodes is l
(D) 3 d
2
z
has 3 angular nodes.
Q59 Assertion (A): The number of radial nodes in 3s
and 4p orbitals is are equal.
Reason (R): The number of radial nodes in any
orbital depends upon the values of ‘n’ and ‘l’
which are different for 3s and 4p orbitals.
(A) Both Assertion (A) and Reason (R) are True
and the Reason (R) is a correct explanation of
the Assertion (A).
(B) Both Assertion (A) and Reason (R) are True
but Reason (R) is not a correct explanation of
the Assertion (A).
(C) Assertion (A) is True but the Reason (R) is
False.
(D) Assertion (A) is False but Reason (R) is True.
Q60 The number of angular nodes and radial nodes in
3s orbital are:
(A) 1 and 0, respectively
(B) 3 and 0, respectively
(C) 0 and 1, respectively
(D) 0 and 2, respectively
Q61 Which of the following is not
permissible arrangement of electrons in an atom?
(A) n = 5, ℓ = 3, m = 0, s = +
1
(B) n = 3, ℓ = 2, m = −3, s = −
1
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Answer Key
Q1 (B) Q31 (C)
Q2 (B) Q32 (B)
Q3 (B) Q33 (B)
Q4 (B) Q34 (C)
Q5 (A) Q35 (A)
Q6 (B) Q36 (D)
Q7 (C) Q37 (A)
Q8 (C) Q38 (D)
Q9 (C) Q39 (B)
Q10 (C) Q40 (C)
Q11 (A) Q41 (C)
Q12 (B) Q42 (D)
Q13 (A) Q43 (C)
Q14 (B) Q44 (D)
Q15 (A) Q45 (B)
Q16 (D) Q46 (C)
Q17 (A) Q47 (A)
Q18 (D) Q48 (B)
Q19 (C) Q49 (D)
Q20 (B) Q50 (B)
Q21 (B) Q51 (A)
Q22 (D) Q52 (A)
Q23 (A) Q53 (C)
Q24 (A) Q54 (C)
Q25 (B) Q55 (C)
Q26 (D) Q56 (D)
Q27 (C) Q57 (A)
Q28 (C) Q58 (D)
Q29 (D) Q59 (A)
Q30 (A) Q60 (D)
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Q61 (B) Q62 (A)
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