15-06-2025

1001CJA106213250005 JA

PART-1 : PHYSICS

SECTION-I (i)

1) In the arrangement shown in the fig, the block of mass m = 2 kg lies on the wedge of mass M = 8
kg. The initial acceleration of the wedge if the surfaces are smooth and pulley & strings are mass-

less is:

(A)
m/s2

(B)
m/s2

(C)
m/s2

(D) 2
m/s

2) Two identical blocks of same masses are placed on a fixed wedge as shown in figure. Coefficient
of friction between all the contact surfaces is µ. Choose the correct alternative.

(A) For motion at any surface, θ ≤ tan–1(µ).

(B) Acceleration of block A will be more than acceleration of block B in downward direction.
(C) Acceleration of block A will be less than acceleration of block B in down ward direction.
(D) Two block A and B move with same acceleration.
3) In the figure shown below masses of blocks A and B are 3 kg and 6 kg respectively. The force
constants of springs S1 and S2 are 160 N/m and 40 N/m respectively. Length of the light string
connecting the blocks is 8 m. The system is released from rest with the springs at their natural

lengths. The maximum elongation of spring S1 will be :

(A) 0.3 m
(B) 0.5 m
(C) 0.6 m
(D) 0.9 m

4) Consider the following system of massless and frictionless pulleys, ropes, and springs :

Initially, a block of mass m is attached to the end of a rope, and the system is
in equilibrium. Next the block is doubled in mass, and the system is allowed to come to equilibrium
again. During the transition between these equilibria, how far does the end of the rope (where the
block is suspended) move ?

(A)

(B)

(C)

(D)

SECTION-I (ii)
1) A projectile is thrown from the ground at a speed of 40 m.s–1 at angle of elevation 60° above the
horizontal. Select the correct option(s). [ g = 10 m.s–2 ]

(A) Rate of change of speed of the projectile just after projection is +5 m. s–2.
(B) The projectile is moving away from point of projection at all instants till hitting the ground.
(C) Velocity vector of the projectile is rotating at a rate of 0.5 rad . s–1 at top most point.
(D) Maximum height reached by the projectile is 60m.

2) Block A is placed on cart B as shown in figure. If the coefficients of static and kinetic friction
between the 20 kg block A and 100 kg cart B are both essentially the same value of 0.3. [g = 10

m/s2]

(A) The blocks A and B will have a common acceleration of 1 m/s2, if P = 40N
(B) Acceleration of cart A is 2m/s2, if P = 50 N.
(C) Acceleration of cart B is 1.2 m/s2, if P = 60 N
(D) Minimum value of P at which relative motion starts between the two block is 50 N.

3) The figure shows a block of mass M = 2m having a spherical smooth cavity of radius R placed on
a smooth horizontal surface. There is a small ball of mass m moving at an instant vertically
downward with a velocity v with respect to the block. At this instant :

(A)
The normal reaction on the ball by the block is
The normal reaction on the ball by the block is
(B)

(C)
The acceleration of the block with respect to the ground is

(D)
The acceleration of the block with respect to the ground is

4) A bucket is attached to a rope of length L = 1.2 m and is made to revolve in a horizontal circle.
Drops of water leaking from the bucket fall and strike the floor along the perimeter of a circle of
radius d (θ = 30°) (Take : g = 10 m/s2)

(A) time of flight of drop is approximately 0.52 sec.

(B) time of flight of drop is 3.15 sec.
(C) radius d is approximately 1.08 m
(D) radius d is 0.9 m

SECTION-II

1) Two bodies with a mass of 1 kg each hang on a spring with a force constant of 250 N/m, attached
to each other using a thread with a length of 10 cm, as shown in the figure. We burn the thread.
What is the distance (in cm) between the two bodies when the top body first arrives at its highest

position ?

2) Figure shows a ball of mass m connected with two ideal springs of force constant k, kept in
equilibrium on a smooth incline, suddenly right spring is cut. What is magnitude of instantaneous

acceleration (in m/s2) of ball. [g = 10 m/s2]

3) A wedge can slide frictionlessly on a fixed incline of angle 37°. A girl having twice the mass of the
wedge is strapped to the wedge. She pushes a small ball of negligible mass on the horizontal smooth
upper surface of wedge as shown in figure. Ball is pushed at the same instant as the motion of
wedge starts. Initial velocity of ball is 12 m/s relative to wedge. Find the time (in s) after which ball
returns to girl. Assume that horizontal surface of wedge is very long. [g = 10 m/s2]

4) A car starts from rest from origin an straight line with an acceleration (a) given by the relation

, where a is in m/s2 and x is in metre. The maximum velocity (in m/s) of the car will be (x
is the position of the car)

5) A particle is projected horizontally at a speed 5 m . s–1 along a smooth inclined plane. The inclined
plane is inclined at 30° with the horizontal. Find the radius of curvature (in m) followed by the
particle 1s after the particle is projected, [g = 10 m . s–2]

6) A board is being moved with a constant velocity v0 on a smooth horizontal plane. A small block is
projected on the rough boards. Coefficient of friction between board and block is μ = 0.3. Block is
projected with velocity v1 = 25 m/s at an angle of θ = 37° relative to ground. What is the velocity of

block (in m/s) relative to ground after time t = 10 sec.

7) Three blocks A, B, and C, whose masses are 9 kg, 9kg and 18 kg respectively as shown in the
figure, are released from rest. The co-efficient of friction between block A and surface-2 is 0.5 and
the co-efficient of friction between block B and surface-1 is also 0.5. The acceleration of block C just

after release is (m/s2). All strings and pulleys are ideal. Approx value of n is :

8) A physics student decides to perform an experiment to land a small box of mass m = 60 g onto the
center of a target a distance Δd away. The student puts the box on a top of a frictionless ramp with
height h2 = 0.5 m that is angled θ = 30° to the horizontal on a table that is h1 = 4 m above the floor.
If the student pushes the spring with spring constant k = 6.5 N/m down by Δx = 0.3 m compared to
its rest length and lands the box exactly on the target, what is Δd ? Answer in meters. You may

assume friction is negligible.

PART-2 : CHEMISTRY

SECTION-I (i)

1) On study it is seen that the electronegativity of the atom linearly increases with the partial ionic
charge (q). Thus electronegativity can be written as, x = a + bq, where large and soft atoms have
low value of b, while small and hard atoms have a large value of b, and a is constant, then which of
the following given plot describes the electronegativity variation of F and Cℓ accurately? [Given : XF
= 4, XCℓ = 3 and XH = 2]

(A)

(B)
(C)

(D)

2) Maximum amount of energy is involved in which of the following process ?

(A)

(B)

(C)

(D)

3) The ground state electronic configurations of the elements, U, V, W, X, and Y (these symbols do
not have any chemical significance) are as follows :
U 1s2 2s2 2p3
V 1s2 2s2 2p6 3s1
W 1s2 2s2 2p6 3s2 3p2
X 1s2 2s2 2p6 3s2 3p6 3d5 4s2
Y 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6
Among these only, determine which sequence of elements satisfy the following statements :
(i) Element with 2pπ-2pπ type of π-bond in one of its oxide
(ii) Element with maximum paramagnetism.
(iii) Element has largest radius.
(iv) Element forms only acidic oxide.

(A) VWYU
(B) UXYW
(C) UWYX
(D) VXWU

4) Which of the following is/are correctly matched for the given species?
BeCl2 , XeF2 , IF7 , CH2Cl2 , SiF4 , , H2O , SF4 , BF3 , ,

(A) Planar species = 7

(B) Total number of species in which atleast one bond angle is 180° = 3
(C) V-shape species = 1
(D) Polar species = 5

SECTION-I (ii)

1) INCORRECT order of number of planes present in molecule which contain maximum number of
atoms of corresponding molecule :

(A) IF7 > SF6 > PCl5

(B) PCl5 > SF6 > IF7
(C) SF6 > IF7 > PCl5
(D) PCl5 > IF7 > SF6

2) Which of the following statement is incorrect ?

(A) In BrF3, Maximum four halogen atoms are lie in same plane.
(B) In , lone pair occupy axial position.
(C) CH3F > CH3Cl > CH3Br
Molecules IOF5 and XeO2F4 have similar electronic geometry but have different number of lone
(D)
pairs in whole molecule.

3) Two elements have set of quantum numbers of their last filled subshell of valence shell as follows
:
'X' → n = 4 l = 1
'Y' → n = 5 l = 2
Then which statement is correct

(A) Element 'Y' has greater atomic number than atomic number of element 'X'
(B) Element 'X' can have 10 electrons in 'd' subshell
(C) Element 'X' is not a transition element
(D) Atomic size of element 'Y' is must be equal to the atomic size of element 'X'

4) The CORRECT statement among the following is:

(A) the first ionization energy of Al is less than first ionization energy of Mg.
(B) the second ionization energy of Mg is greater than second ionization energy of Na.
(C) the first ionization energy of Na is less than first ionization energy of Mg.
(D) the third ionization energy of Mg is greater than third ionization energy of Al.

SECTION-II

1) In a hypothetical world, if four quantum number have values as given below :-

n = 1 to ∞
ℓ = 0 to (n+1)
m = –(ℓ+1) to (ℓ+1)

s= , , ,
Calculate the number of electrons present in n = 1 for z = 65 (if n + ℓ rule is same).

2) If energy order of subshells is defined according to (n – ℓ) rule instead of (n + ℓ) rule, then total
number of orbitals between 1s and 2s subshell would be (If (n – ℓ) same, then subshell having lower
'n' will be consider as lower in energy) [consider that system have only first four shells] –

3)

Count the number of incorrect statement among the following :-

(A) The first ionisation potential of Tℓ is less then the first ionisation potential of B
(B) Ionic radius of free H– is more than that of Br–
(C) The formation of S2– from sulphur atom is an endothermic process
(D) The first ionisation energies of carbon, silicon, germanium, tin, and lead change as C > Si > Ge
> Sn < Pb
(E) Hydration energy of Cs+ > Li+
(F) Among oxides, CO is neutral, Cl2O7 is acidic and SnO is amphoteric.

4) The number of process that are definitely exothermic (Energy is released) out of the
following processes are:

(i)
(ii)
(iii)
(iv)
(v)
(vi)

(vii)

(viii)

5) Total number of planar molecule in which d-orbital(s) is/are used in their bonding.
SO2, SO3, XeF2, XeF4, XeF6, PH3, ICl4– , PCl5, I3–

6) For the following molecules :

PCl3, BrF3, , , , XeO2F2, ,

Calculate the value of .

a = Number of species having sp3d-hybridisation
b = Number of species which are planar
c = Number of species which are non-planar

7) For a species of type MX4 :

(a) If shape is trigonal bipyramidal
(i) Total number of 90° angles = x
 (ii) Total number of 120° angles = y
(b) If shape is tetrahedral
(i) Total number 109°28' angles = z
What will be the value of x + z – y ?

8) Calculate the sum of "Code numbers" of all the cases in which correct order of the mentioned
parameter is represented.

S. Code
Order Parameter
NO. Number

1. Na < Cl < F Electronegativity 28

2. Be < Mg < Na Metallic character 53

3. Al3+ > Mg+2 Ionic radius 14

4. O < F < Cl |ΔegH| 8

5. Cl2O7 > Al2O3 > Na2O Basic Nature of oxide 59

For example if Sr. No. (3) & (5) are correct your answer should be 59 + 14 = 73 therefore fill 73.00.

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let λ = , then value of λ is equal to

(A) 1
(B) 2
(C) 3
(D) None of these

2) Let 12 + 22 + 32 + ... + 20032 = (2003)(4007)(334) and (1)(2003) + (2)(2002) + (3)(2001) + ... +

(2003)(1) = (2003)(334 )(x), then the value of x is

(A) 2005
(B) 2004
(C) 2003
(D) 2001

3) Let a, b, c are distinct positive numbers such that b + c – a, c + a – b and a + b – c are positive,
then the expression (b + c – a)(c + a – b)(a + b – c) – abc is

(A) positive
(B) negative
(C) non-positive
(D) non-negative

4) Let α and β are the distinct real roots of x2 + ax + b = 0 and α4 and β4 are the roots of x2 – px + q
= 0 then the roots of x2 – 4bx + 2b2 – p = 0 are always

(A) both non-real

(B) both positive
(C) both negative
(D) one positive and other negative

SECTION-I (ii)

1) Consider an equation 8x4 – 16x3 + 16x2 – 8x + a = 0 then the sum of all the non-real roots of
the equation can be [a ∈ R]

(A) 1
(B) 2

(C)

(D)

2) Let x + y + z = 0 and x3y + y3z + z3x = –9, then choose the correct option (s)

(A) for x,y,z ∈ R, xy + yz + zx = –3

(B) for x,y,z ∈ R, xy + yz + zx = 3
(C) for x,y,z ∈ C (compelx number), xy + yz + zx = ±3
(D) Given x,y,z are not all distinct, then (|x| –1) (|y| – 1) (|z| –1) = 0

3) Let x1, x2, x3, x4 are four positive real numbers such that

and , then

(A) x1 = x3
(B) x2 = x4
(C) x1x2 = 1
(D) x3x4 = 1

4) a1, a2, a3 ......are distinct terms of an A.P. We call (p, q, r) an increasing triad if ap, aq, ar are in G.P.
where p, q, r ∈ N such that p < q < r. Let (5, 9, 16) be an increasing triad, then which of the
following option is/are correct

(A) let a1 is a non-zero multiple of 4 then every term of the A.P. is an integer
(B) (85, 149, 261) is an increasing triad
(C) let the common difference of the A.P. is , then its first term is

(D) ratio of the (4k + 1)th term and 4kth term can be 4

SECTION-II

1) The value of a, if a and b are integers such the x2 – x – 1 is a factor of ax17 + bx16 + 1 is P, then the

value of .

2) Given sequence of numbers x1, x2, x3, ... x1005 which satisfy,

... = where x1 + x2 + ... x1005 = 2010 then is

3) Let positive numbers x, y, z are in A.P., then the minimum value of is equal to

4) Let a, b, c, > 0 and then the minimum value of

a2 b2 c2 (Consider = 1.41 and = 1.73)

5) is

6)

Let then no. of integers x satisfying the inequality is :

7) The number of integer values of k in the closed interval [–500, 500] for which the equation log
(kx) = 2log (x + 2) has exactly one real solution.

8) Let a, b, c ∈ R and a2 + b2 + c2 = 1, then the maximum value of |a–b| + |b–c| + |c–a| is ?

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A D A D

SECTION-I (ii)

Q. 5 6 7 8
A. B,D A,B,C B,C A,C

SECTION-II

Q. 9 10 11 12 13 14 15 16
A. 38.00 5.00 5.00 2.50 14.10 to 14.20 8.00 7.00 2.70 to 2.90

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 17 18 19 20
A. D A B D

SECTION-I (ii)

Q. 21 22 23 24
A. A,C,D B,C A,B,C A,C,D

SECTION-II

Q. 25 26 27 28 29 30 31 32
A. 53.00 15.00 1.00 5.00 6.00 1.20 9.00 89.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 33 34 35 36
A. C A B D

SECTION-I (ii)

Q. 37 38 39 40
A. A,B A,C,D A,B,C,D A,B,C
 SECTION-II

Q. 41 42 43 44 45 46 47 48
A. 3.00 0.50 4.00 2.82 7.00 31.00 501.00 2.83
 SOLUTIONS

PART-1 : PHYSICS

1)
⇒ If acceleration of wedge is x then acceleration of block w.r.t. wedge is x + x cos60°.

T + N sin 60° = Ma

T+N = Ma
Tcos60° – Nsin60° = m[a – a cos 60° – a cos2 60°]

⇒
mg – N cos 60° – T sin60° = m(a sin60° + a cos60° sin60°)

mg –

2mg – N – = ⇒a= m/s2

2)
F.B.D. for A block
F.B.D. for B block

for block A
mg sinθ – f1 = ma .......(1)
for motion w.r.t. block B
mg sinθ – µmg cosθ = ma ........(2)
for limiting case
a=0
and a = b = 0
⇒ mg sinθ = µmg cosθ
µ = tanθ
θ = tan–1µ
for block B
mgsinθ + f1 – f2 = mb
for motion w.r.t. wedge
f2 = 2 µmgcosθ
mgsinθ + f1 2µmg cosθ = mb ..............(3)
for no relative motion between A and B block from equation (1) & (3) : a = b
2mg sinθ – 2µmg cosθ = 2ma
for limiting case a = 0
⇒ θ = tan–1 (µ)
for motion θ ≥ tan–1 (µ)
when block B is moving w.r.t. wedge
mgsinθ + f1 – 2µ mgcosθ = mb
But f1 = µmg cosθ ⇒ mgsinθ – µmg cosθ = mb
for block A
mgsinθ – µmgcosθ = ma ⇒ a = b.

3)

Correct Answer is (A)

4)

Correct Answer is (D)

5)

Correct Answer is (B,D)

6)

Correct Answer is (A,B,C)

7)

Correct Answer is (B,C)

8)

;
x = 1.73 × 0.52 = 0.89
R = 1.08 m

9)

Correct Answer is (38)

10)

Correct Answer is (5)

11)

Correct Answer is (5)

12)

Correct Answer is (2.50)

13)

Correct Answer is (14.10 to 14.20)

14)

a = –3
 at t = so it will stop relative motion before 10 sec. So it will have same velocity as
plank.

15)

Case I : Net driving force on the

system = 180 N
Net limiting friction on the system = 180 N
Hence all blocks will not move
Case II : Let block A is at rest and
block B moves
2mg – T = 2ma1 ........(i)

2T – = ma2 =
⇒ 4T – mg = ma1 ........(ii)
Equation (i) × 4 + Equation (ii), we have

7mg = 9ma1 ⇒ a1 =

T = 2mg – 2ma1 = 2 × 9 ×

16)

Correct Answer is (2.70 to 2.90)

PART-2 : CHEMISTRY

17)

The correct answer is option (D)

18)

The correct answer is option (A)

19)

(i)
(ii) Transition having unpaired d-electrons.
(iii) In case of Kr van der Waal’s radius is considered, which is largest atomic radius →Y
(iv) Si atom has only acid SiO2 →W
20)

A → Planar species ⇒ 6
B → Species at least 1 bond angle is 180° ⇒ 4
C → V-shapes species ⇒ 2
D → Polar species ⇒ 5

21)

IF7 sp3d3
6 atom in one plane
No. of such planes 1

SF6
5 atom in one plane
No. of such planes 3

PCl5
4 atom in one plane
No. of such planes 4
Option (B) is correct
IF7 < SF6 < PCl5

22)

The correct answer is option (B), (C)

23)

The correct answer is option (A), (B), (C)

24) IE2 of Na > Mg as in Na, second electron is to be removed from stable inert gas
configuration of Na+ i.e.,1s22s22p6.

25) 1s12 1p20 2s12 1d21

26)

The correct answer is 15.00

 27)

The correct answer is 1.00

28)

The correct answer is 5.00

29)

The correct answer is 6

30)

The correct answer is 1.20

31)

The correct answer is 9.00

32)

The correct answer is 89.00

PART-3 : MATHEMATICS

33) λ = =

= = =

= + +..........+

= = 4 - 1 = 3, λ = 3
34) If 12 + 22 + 32 + ... + 20032 = (2003)(4007)(334)
(1)(2003) + (2)(2002) + 3(2001) + ... + (2003)(1) = (2003)(334)(x)

= (2003)(334)(x)
2
⇒ 2004(Σr) – (Σr ) = (2003)(334)(x)

⇒ 2004
⇒ (2003)(334) ⇒ x = 2005

35) Here,

and
Multiplying, abc > (a + b – c)(b + c – a)(c + a – b)

36)

α + β = –a
αβ = b .............(1)
4 4
α +β =p
α4β4 = q .............(2)
Using (1) and (2), we get (a2 – 2b)2 = p + 2b2
a4 – 4ba2 + 2b2 – p = 0
a2 is one of roots of x2 – 4bx + 2b2 – p = 0
Product of roots of equation = 2b2 – p
2α2β2 – (α4 + β4) = –(α2 – β2) < 0
Hence one root is positive and other is negative.

37) 8x (x – 1) (x2 – x + 1) + a = 0
a = 8x(1–x) (x2– x + 1)
f(x) = 8x(1–x) (x2– x + 1)
f(x) has only 2 real roots x = 0, 1 and is concave downwards

and its maximum value is at

Maximum value of f(x) =

If
All roots will be imaginary of sum = 2

If
Only two roots will be imaginary of sum = 1

38) x + y + z = 0
Let xy + yz + zx = – p
and xyz = q
∴ Equation whose roots are x,y,z is
t3 – 0.t2 – pt – q = 0
⇒ x3 = px + q, y3 = py + q, z3 = pz + q
∴ x3y + y3z + z3x = –9
⇒ p(xy + yz + zx) + q (x + y + z) = –9
⇒ –p2 = –9
⇒ P = 3 or –3
also xy + yz + zx = xy + z(x + y) = xy – (x + y)2
= –(x2 + xy + y2) < 0 ∀ x,y ∈ R
= – P < 0 ⇒ P > 0 ∀ x, y ∈ R
∴ P = 3 ∀ x,y,z ∈ R ( option A)
P = ±3 ∀ x,y,z ∈ C (option C)
If x = y
∴ z = –2x = –2y
and –p = x2 + xz + xz
⇒ –3 = x2 – 4x2 ⇒ x2 = 1
⇒ |x| = 1
⇒ (|x| – 1) = 0
∴ A,C,D are correct.

39)

∴ to hold all the inequalities x1 = = 2,

∴ x1 = x3 = 2 & x2 = x4 =

40) Let R be the common ratio of the G.P. and D be the common difference of A.P.
a5 = a5,a9 = Ra5, a16 = a5R2
a9 – a5 = 4D ⇒ (R –1) a5 = 4D.............(1)
a16 – a9 = 7D ⇒ R(R –1) a5 = 7D.............(2)

From equation (1)/(2), we get

From equation (2) – (1), we get (R – 1)2 a5 = 3D ⇒

41) Since roots of x2 – x – 1 = 0, are P = and
ax17 + bx16 + 1 = 0
ap17 + bp16 = – 1 ... (1)
aq17 + bq16 = – 1 ... (2)
Multiply (1) by q and (2) by p16
16

ap + b = – q16
aq + b = – p16

= (p8 + q8) (p4 + q4) (p2 + q2) (p + q)

p+q=1 p4 + q4 = (p2 + q2)2 – 2(pq)2 = 9 – 2 = 7
p2 + q2 = 3 p8 + q8 = (p4 + q4)2 – 2(pq)4 = 49 – 2 = 47
a= 47 × 7 × 3 × 1 = 987

42) Above sequence is in A.P.

= ................ =k

∴k=

k=1+ =

⇒ x21 =

43) Since x, y, z are in A.P., x + z = 2y and hence

≥ 1 + 3 [A.M. ≥ G.M.]
⇒ minimum value of the given expression is 4

44) Let a2 = tan α, b2 = tan β and c2 = tan γ

Then, cos2 α + cos2 β + cos2 γ = 1 ⇒ sin2 α = cos2 β + cos2 γ
Use AM ≥ GM
sin2 α = cos2 β + cos2 γ = 2(cos2 β cos2 γ)1/2
⇒ sin2 α ≥ 2 cos β cos γ ….. (1)
Similarly, sin2 β ≥ 2 cos α cos γ ….. (2)
and sin2 γ ≥ 2 cos α cos β ….. (3)
Multiplying 1, 2, 3
sin2 α sin2 β sin2 γ ≥ 8 cos2 α cos2 β cos2 γ
⇒ tan2 α tan2 β tan2 γ ≥ 8 ⇒ tan α tan γ tan γ ≥ 2
⇒ a2 b2 c2 ≥ 2 minimum value 2 = 2.82

45) tr =

=
⇒ t1 + t29 = 2
But t15 = 1 & t30 = 1
⇒ Final sum = 31
So required answer is 7

46)
For to be defined x < 0

Since are positive & –x2 + x – 1 is always negative

x<0

⇒
⇒ No. of integers = 31

47) The equation log (kx) = 2log (x + 2) is valid for kx > 0 and x > – 2.
It is easy to seen that the all negative values of k make the equation log (kx) = 2 log (x + 2)
have 500 integer values and for positive reason of x, k has only one value.

48)

Let assume a ≥ b ≥ c; (|a–b| + |b–c| + |c–a|)2 ≤4(a–c)2 ≤ 8 ⇒ |a–b| + |b–c| + |c–a| ≤ 2