17-11-2024

6001CJA10100124007SRG JA

PHYSICS

SECTION-I(i)

1) A small particle A is released from rest inside a fixed hemispherical bowl from the horizontal
position. Another identical particle B is resting at the lowest position. The right half of the bowl is
smooth and left half is rough with coefficient of friction µ ≥ 0. The mass of each particle is m and
radius of bowl is R. Then which of the following options is incorrect

If collision between the particles is perfectly inelastic and particles rise to a maximum height
(A)
of R/8 above the lowest point. Then work done against friction in this period is
If collision is perfectly elastic and particle B is just unable to collide with particle A for
(B)
the second time then total work done against friction in this period is mgR

If coefficient of restitution is and µ = 0 for left half of the hemisphere also, then
(C)
maximum potential energy achieved by B above the lowest point is mgR
If collision is perfectly elastic and particle B is just unable to collide with particle A, then
(D)
total work done against friction in this period is

2) A uniform thread of linear mass density λ = 2.0 g/m passes through a fixed ideal pulley. At its
ends, the thread is stacked into two heaps that do not interfere motion of the thread. A beetle of
mass m = 80 g tries to manage itself at a constant height on the thread by adjusting its
speed relative to the thread. At some steady speed of the thread, the beetle succeeds in doing so.
Find this steady speed of the thread. Acceleration due to gravity is g = 10 m/s2.

(A) 10 m/s
(B) 20 m/s
(C) 15 m/s
(D) 25 m/s

3) At time t = 0, the velocities of two particles A and B of equal masses and both lying at origin are
m/s and m/s respectively. The acceleration of both particles is always constant
such that acceleration of A has magnitude aA = 10 m/s2 and acceleration of B is m/s2 .If the
centre of mass of system of two particle system moves along a straight line with increasing speed,
then the acceleration vector of particle A in m/s2 is

(A)
(B)
(C)
(D)

4) A uniform disc rotating about its vertical axis of symmetry is gently placed on a horizontal floor
with one of its flat face on the floor. The floor has two portions, where coefficients of frictions
between the disc and the floor are µ1 = 0.78 and µ2 = 0.67. Consider the line dividing the
two portions as y-axis and the point where centre of the disc is placed as the origin of a coordinate
system as shown in the figure. Find acceleration of the centre of the disc immediately after it is
placed on the floor. Assume acceleration of free fall to be g = 10 m/s2 and π = 22/7.

(A)
(B)
(C)
(D)

SECTION-I(ii)

1) Two bodies A and B of masses 5.00 kg and 10.0 kg respectively moving in opposite directions with
velocities 4.00 m/s and 0.50 m/s respectively make head-on collision in free space. The force of their

mutual interaction during collision varies according to the given graph

(A) Period of deformation is 0.20 s

(B) Coefficient of restitution is 0.50
(C) Body A will move with velocity 0.50 m/s in the original direction
(D) Body B will move with velocity 1.75 m/s in the original direction

2) In each of three figures shown, two blocks are connected by a light spring and the system is
placed on smooth horizontal surface. A constant horizontal force of magnitude F is applied to left
block as shown. Assuming spring constant in all three cases to be same, which of the following

statements is/are true

(A) Maximum compression in spring 1 is greater than that in spring 2

(B) Maximum compression in spring 3 is greater than that in spring 1
(C) Maximum compression in spring 3 is greater than that in spring 2
(D) Maximum compression in all springs is equal

3) A uniform disc of mass M and radius R is lifted using a string as shown in the figure. Then

(A) Its linear acceleration is g upward

(B) Its linear acceleration is g downward
Its angular acceleration is
(C)

(D) Its rate of change of angular momentum about its COM is MgR

SECTION-II (i)

Common Content for Question No. 1 to 2

A boy and a girl skate towards each other on smooth ice, but in parallel lines. The distance between

the lines is . The mass of the girl is m and that of the boy is m. The velocity of the boy is V and
that of the girl is 5V. The girl holds a stick of length and negligible mass. The stick is directed
normal to the direction of motion as shown in the figure. When the couple passes each other, the boy
grasps the stick and the couple move together, each of them holding different ends of the stick.
1) The angular velocity of the rod after the couple begin moving together is . Find P

2) They start moving towards each other by pulling the stick until the distance between them is

. The work done by them as they move from to is N [Link] N

Common Content for Question No. 3 to 4

A system consists of block A and B each of mass m connected by a light spring of spring constant K
as shown with block B in contact with a wall. Initially the spring is in natural length and the block A

is displaced towards left by and then released from rest. Neglect friction everywhere (g = 9.8

ms-2):

3) Find Acceleration of centre of mass of system comprising A and B just after A is released, is (in
m/s2)

4) Maximum extension in the spring after system loses contact with wall is , where p and q are

the smallest possible integers. Find .

SECTION-II (ii)

1) Three identical uniform rods, each of length , are joined to form a rigid equilateral triangle.
Its radius of gyration about an axis passing through a corner and perpendicular to the plane of

the triangle is where n is

2) A man wishes to break a long rod of 6 m length by hitting it on a rock. The end of the rod which
is in his hand rotates without displacement. The man wishes to avoid having a significant force
act on the his hand at the time the rod hits the rock. Point on the rod should hit the rock from his
hand at a distance in m is :(ignore gravity)

3) In a closed trolley there is some water and a pump. The pump ejects water in the form of a
jet which after impinging on a light vertical plate A comes back in the trolley. The plate A is
attached to an ideal spring (k = 1000 N/m) which remains compressed by 0.1 m as long as jet of
water strikes the plate. The pump operates for 3 sec and then it stops. If the mass of the trolley with
the water and the pump is 300 kg and initially the trolley system is at rest, find the final speed, in
m/s, of the trolley assuming no friction between the trolley and the ground. Assume that the spring
remains horizontal. (Neglect the effect of currents in water)

4) A block of mass Mand cylindrical tank which contains water having small hole at bottom, which
is closed initially (total mass of cylinder + water is also M), are attached at two ends of an
ideal string which passes over an ideal pulley as shown. At t = 0 hole is opened such that water
starts coming out of the hole with a constant rate μ kg/s and constant velocity Ve relative to the

cylinder. Acceleration of the block at any time t is . Here α is an integer. Find α

5) An old record player of 10 cm radius turns at 10 rad/s while mounted on a 30° incline as shown
in the figure. A particle of mass m can be placed any where on the rotating record. If the
least possible coefficient of friction μ that must exist for no slipping to occur is μ, find [g=

10 m/s2]

6) A part of inner surface of a vertical smooth, fixed hollow circular tube of mean radius 5m is
removed as shown. A particle is projected from lowest position with minimum velocity such that
particle just can complete vertical circular motion with the support of part CD. Ratio of normal force
acting on the particle at lowest position to highest position is and width of tube is
small). Then value of α is

CHEMISTRY

SECTION-I(i)

1) The correct IUPAC name of following compound is

(A) 2-Chloro-3-methoxy cyclohex-5-ene carboxylic acid

(B) 6-Chloro-5-methoxy cyclohex-2-ene carboxylic acid
(C) 6-Chloro-5-methoxy cyclohex-2-enoic acid
(D) 2-Chloro-3-methoxy cyclohex-5-enoic acid

2) The enthalpy of neutralization of a weak mono protic acid, HA in 1 M solution with a strong base
is -55.95 kJ/mol. If the unionized acid requires 1.4 kJ/mol heat for its complete ionization and
enthalpy of neutralization of the strong monobasic acid with a strong mono acidic base is -57.3
kJ/mol. Then % ionization of the weak acid in a molar solution is

(A) 1.2 %
(B) 3.57 %
(C) 6.07 %
(D) 12.01 %

3)
The degree of dissociation of PCl5 at one atmosphere is 0.3. The pressure at which PCl5 is
dissociated to 50% is nearly (at same temperature)

(A) 2.73 atm

(B) 0.3 atm
(C) 0.273 atm
(D) 1.67 atm

4) The pH of 0.2 M NaHCO3 solution at 25°C is 9.2. A 22 mL of 2.0M solution of H2CO3 when treated
with 80 mL of 0.5M NaOH results into formation of H2CO3 -NaHCO3 buffer with pH of 8.6. Hence
of H2CO3 is

(A) 10.8
(B) 7.6
(C) 9.2
(D) 8.6

SECTION-I(ii)

1) 25mL of H2O2 solution were added to excess of acidified solution of KI. The iodine so liberated
required 20mL of 0.1N Na2S2O3 for titration in mild acidic medium. Then the strength of H2O2 is

(A) 0.08N

(B)
0.136%
(C) 0.448 volumes
(D) 0.04M

2) Which of the following statements is/are correct

The decreasing order of priority of some functional group is

(A)
(halogroup)

(B)

Structure of ortho xylene is

(C) , Its IUPAC name is Hex–4–en–1–yne.

(D)

The structure of 5-Ethenylcyclopenta-1, 3-diene is

3) pH of saturated aqueous solution of Ba(OH)2 is 12 at 25°C. Identify the correct statement(s) at

25°C.

–5
(A) The solubility of Ba(OH)2 in a buffer solution of pH=13 is (5 × 10 )moles/L
(B) The solubility of Ba(OH)2 decreases in presence of NH4Cl
 –5
(C) The solubility of Ba(OH)2 in a buffer solution of pH=1 is 5 x 10 moles/L
–7 3
(D) The solubility product of Ba(OH)2 is 5 × 10 M

SECTION-II (i)

Common Content for Question No. 1 to 2

The change in internal energy (U) can be brought about in two ways:
i) Either by allowing the heat to flow into the system or out of the system
ii) By doing work on the system or the work done by the system Using the symbol q to represent
heat transferred to system and using work done by the system –w, we can represent the
internal energy change of a system, ΔU, as:
q = ΔU + (–w) (First law of thermodynamics)
If the reaction is carried out in a closed container with constant volume, so that ΔV = 0
Hence, qv = ΔU
On the other hand, if a reaction is carried out in open vessel that keeps the pressure constant and
allows the volume of the system to change freely. In such case and –w = P. ΔV
Hence, qp = ΔU + PΔV
Also, qp = qv + Δng RT
As reactions carried out at constant pressure are so common, the heat change for such process is
given a special symbol ΔH, called the enthalpy change of the reaction. The enthalpy (H) of the
system is the name given to the quantity (U + PV).

1) The latent heat of vaporization of liquid at 500 K and 1 atmospheric pressure is 10.0 kcal/mol.
What will be the change in internal energy of 3 moles of the liquid in this process at the
same temperature (in Kcal) [R=2 cal K–1 mol–1]

2) The enthalpy change (ΔH) for the reaction, is –92.38kJ at 298 K. The
numerical value of internal energy change |ΔU| at 298 K is(in KJ) (R = 8.314 J mol–1K–1)

Common Content for Question No. 3 to 4

In gaseous phase reactions taking place under given set of pressure and temperature conditions
volume changes occur due to change in moles. If volume is fixed the pressure changes occur
according to stoichiometric ratios.

3)
Due to complete decomposition of PH3 an increase of 50 cm3 gaseous volume is recorded. What is
the degree of dissociation of PH3 when the volume of reaction mixture is 110 cm3, under
same conditions.

4) 60 % of mass of oxygen is converted into ozone at an equilibrium pressure of 4 atmospheres in a

rigid container. What is KP for the reaction

SECTION-II(ii)
1) Solubility of in pure water is . How many times the solubility of will
increase in buffer of pH = 10 at same temperature (if no complex is formed) ?

2) 0.15 mole of pyridinium chloride has been added into 500cm3 of 0.2M pyridine solution. What is
the pH of the resulting solution at 25°C, assuming no change in volume. (Kb for pyridine
)

3) 0.2M NH3 is titrated against 0.2M HCℓ. Determine pH at the equivalence point at 25°C. Assume
Kb of NH3 = 10–5.

4) The heat capacity of bomb calorimeter and its contents is 100 J/k. When one
gram was burnt in this calorimeter, the temperatures increases by 5°C . Then the enthalpy
of combustion at 300K will be –10 × x in kJ / mole. Then x is (approximately)

5) During reversible isothermal expansion of 2 moles of an ideal diatomic gas at 27°C Gibb's free
energy change is found to be –2.7636 kcal, entropy change during same process is found to be 'X'

cal/k, then value of will be

6)
Equivalent mass of H2SO4 in this reaction is equal to

MATHEMATICS

SECTION-I(i)

1) Three circles C1, C2, C3 with radii r1, r2, r3 (r1 < r2 < r3) respectively are given as r1 = 2, and r3 = 8.
They are placed such that C2 lies to the right of C1 and touches it externally, C3 lies to the right of
C2 and touches it externally. There exist two straight lines each of which is a direct common tangent
simultaneously to all the three circles, then r2 is equal to

(A) r2 = 4
(B) r2 = 5
(C) r2 = 10
(D) r2 = 16

2) A palindrome is a word, number, phrase or sequence of words that reads the same backwards as
forwards e.g. "SOLOS". The number of palindromes that can be formed using the letters
AABBBBCCCDDDD are

(A)

(B)
(C)

(D) None of these

3) The number of proper divisors of is

(A) 19
(B) 20
(C) 21
(D) None of these

4) In a , the incircle touches the sides BC, CA and AB at D, E, F respectively. If radius of

incircle is 4 units and BD, CE and AF are in A.P. with common difference 1, then area of is

(A) 84 sq. units

(B) 42 sq. units
(C) 168 sq. units
(D) Data insufficient

SECTION-I(ii)

1) Let A(4, 3), B(-4, 3) and C(0, -5) be the vertices of triangle and P(5, 0). Let L, M and N be the feet
of the perpendiculars drawn from P onto the sides BC, CA and AB respectively, then

(A) Area of is 5 sq. units

(B) The centroid of does not exist
(C) The orthocentre of is the origin
(D) L, M and N are collinear

2) A rectangle HOMF has sides HO = 11 and OM = 5. A triangle ABC has H as the intersection of
the altitudes, O the centre of the circumscribed circle, M the mid point of BC, and F the foot of the
altitude from A, then

(A) Perimeter of is greater than 70

(B) Area of in integer
(C) One side of is rational
(D) All sides of are less than 30

3) Which of the following options are correct?

(A)

If a and b are two positive numbers such that a5b2 = 4 then the maximum value of
(B)
is equal to 4
(C)
Constant term in is equal to 2
24
The coefficient of x in

(D)
is equal to
2925

SECTION-II(i)

Common Content for Question No. 1 to 2

A square unit2 area is shown in the diagram, contain 25 square of area. A person
can move on this grid (on the sides of small squares) either right or up, then

1) How many rectangles can be formed by joining small squares so that none of
rectangles contain alphabets M, N, C and B

2) Number of such paths from P to Q, which always pass through the boundaries of the square which
contain either (M and N) or (C and B)

Common Content for Question No. 3 to 4

Consider the 6x6 square in the figure. Let A1, A2, ......, A49 be the points of intersections (dots in the
picture) in some order. We say that Ai and are friends, if they are adjacent along a
row or along a column.

3) The number of ways of selecting two distinct points out of points A1, A2, ......A49, such that they are
friends is

4) Let Ni be the number of points having i number of friends, for i = 0, 1, 2, 3, 4, then the value of
is
 SECTION-II(ii)

1) The value of is (P)P+1, then P2 is (where )

2) Quadrilateral ABCD is inscribed in a circle with AD as diameter. If AD = 4, AB = BC = 1 and

perimeter of quadrilateral ABCD is K, then 2K = _______

3) If the coefficient of in (x - 1) (x2 - 2) (x3 - 3) (x4 - 4) ...... (xn - n), where is k, then k is
equal to _______

4) If the radius of circumcircle of the , where PQ is the chord of contact corresponding to

point T with respect to circle , is 6 units. Then the minimum distance of T
from director circle of the given circle is , then k is equal to

5) A person can take one step or two steps or three steps at a time. If "P" is the number of distinct
ways he can cover exactly 8 steps, then value of P is

6) Find the number of permutations x1, x2, x3, x4, x5 of numbers 1, 2, 3, 4, 5 such that the sum of five
products x1 x2 x3 + x2 x3 x4 + x3 x4 x5 + x4 x5 x1 + x5 x1 x2 is divisible by 3
 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. D B A A

SECTION-I(ii)

Q. 5 6 7
A. A,B A,B,C A,C,D

SECTION-II (i)

Q. 8 9 10 11
A. 6 30 14.7 1.5

SECTION-II (ii)

Q. 12 13 14 15 16 17
A. 2 4 1 2 6 1

CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21
A. B B B A

SECTION-I(ii)

Q. 22 23 24
A. A,B,C,D A,C,D A,D

SECTION-II (i)

Q. 25 26 27 28
A. 27 87.41 to 87.43 0.2 0.5

SECTION-II(ii)

Q. 29 30 31 32 33 34
A. 4 5 5 6 4 98

MATHEMATICS
 SECTION-I(i)

Q. 35 36 37 38
A. A B B A

SECTION-I(ii)

Q. 39 40 41
A. B,D A,B,C,D A,B,D

SECTION-II(i)

Q. 42 43 44 45
A. 73 218 84.00 9.00

SECTION-II(ii)

Q. 46 47 48 49 50 51
A. 36 19 0 2 81 80
 SOLUTIONS

PHYSICS

1)
(Work done against friction) Wf = loss in M.E

= =

(Work done against friction) Wf = loss in M.E.

= = mgR

V1-V2 = ... (1)

V1-V2 = ... (2)
From (1) and (2),

P.E. =

3)

and makes an angle 30º with y-axis as shown

Since, aA = aB , for be parallel to , θ should be 30º
4)

5) Magnitude of impulse on other body

= 22.5 N

before

After
Final momentum of A = 20 – 22.5 = –2.5 N-s

therefore, velocity of A after collision m/s

i.e. 0.5 m/s in opposite to original direction 0.5 m/s
Final momentum of B = –5 + 22.5 = 17.5 N-s

Final velocity of B after collision = = 1.75 m/s

i.e. 1.75 m/s opposite to original 1.75 m/s

Therefore, e =

Impulse till deformation

t = 0.2

6) The maximum compression in spring for shown situation is

Since (m1 + m2)K is same for all situations ; the compression is maximum for spring 3 and least
for spring 2
7)

8) Let C be the C.M

and

and
From conservation of angular momentum about C
Alternate Solution :
the rod is massless
just after the boy holds the other end of rod the speed of boy and girl do not change

9) When they come to , the moment of inertia about C.M. will become and angular
velocity
Work done = ΔKE

= 30 mv2

10)

11) Velocity of A at natural length of spring towards right

at maximum extensition they are moved with common velocity so
pi = mVA
pf = 2mV

Using Energy conservation

12) MI of the system w.r.t an axis to plane & passing through one corner

Now

13) Let point of impact be at a distance x from the end which is in hand. If F is the force acting
on rod due to rock & F’ is force due to the hand of man
x. mv =
For end in the hand to remain stationary

14) The horizontal force acting on the trolley system and the plate A = kx = 1000 x 0.1 =
100N
The impulse imparted by this force in 3 sec = 300 N–s
The change in momentum of the sytem = 300 N–s
If the final speed of the trolley is v , we have 300v = 300
v = 1 m/s

15) ... (1)

... (2)
From (1) and (2), we get

... (3)

... (4)

Therefore,

16)
f ≥ mg sin θ + mrω2
µ mg cos θ mg ≥ sin θ + mrω2

or µ ≥ tan θ +

17) Let at Angle θ, particle loose contact with outer surface than N + mg cos θ = {N =
0}

; by Energy conservation b/w A and C

 when particle reaches at highest point

CHEMISTRY

19)

1.4 kJ/mol heat is required for ionization

So, % of heat utilized by 1 M acid for ionisation

= 96.43% so % of ionisation 100 - 96.43 = 3.57

20)

Since α = 0.3 at 1 atm pressure

When α = 50% = 0.5 the pressure can be calculated as follows

21) HCO3– ion is amphiprotic anion

Na+ ion is unhydrolysable. Hence pH of a

solution of NaHCO3 is equal to

irrespective of the concentration of solution

Thus,
The pH of H2CO3 - NaHCO3 buffer is given by the equation

From question
No. of m. mole of H2CO3 taken = 22 × 2 = 44
No. of m. mole of NaOH added = 80 × 0.5 = 40
No. of m. mole of NaHCO3 formed = 40
No. of [Link] of H2CO3 left out = 4

So, 8.6 =
Therefore,

22) The redox changes are

,

,
Meq of H2O2 = meq of I2 = meq of
;

Wt of H2O2 =
% by wt = 0.136%
Therefore, also it is 0.448 vol of H2O2

24) Since pH = 12 pOH = 14 – 12 = 2

[OH–] = 10–2M
We know Ba (OH)2 Ba++ + 2OH–
 KSP = [Ba++] [OH–]2 = × (10–2)2 = 5 × 10–7M3

25) ΔH = 10.0 K cal/moles

For 3 moles ΔH = 30 K cal
ΔH = ΔU + ΔnRT
& Δn = 1

30 =ΔU + 3
ΔU = 27 K cal

26)

27)
Let initial presence PH3 = P0 on complete decomposition

‘H2’ is formed

Increase volume (given)

P0 = 100

(given)

Degree of dissociation

28)

(at equilibrium)
O2 and O3 have same number of moles hence partial pressure of each gas is 2 atm
(total pressure is given as 4 atm)

atm-1

29)

Solubility in buffer
 In buffer of pH = 10,

solubility in buffer

Ratio =

30) [ Pyridinium Chloride ]

[Pyridine] = 0.2M
A mixture of pyridine and its salt pyridinium chloride forms a basic buffer and therefore

pH = 14 - 9
pH = 5

31) [NH4Cl] = 0.1 M

32)

MATHEMATICS

35)

Similarly
and PD = x then

Hence,
36) Letters C must be in middle of word

Required number are

37)
Number of proper divisors = 20

38) As s-b, s-c, s-a are in AP with common difference = 1

Also
A = 13, c = 14, b = 15

39) P lies on circumcircle (x2 + y2 = 25)

So, L, M, N are collinear (i.e. Simson's line)

40) Centroid G of triangle is collinear with H and O and G lies two third of way from A to M,
therefore H is two third of the way from

A to F. So
Since
So, and are similar

Now
But

41) (A)

Put where
(B) Take modulus both sides

when 5
(C) For constant term put x = 0 and get constant term = 4
(D) Coefficient of

42) (I) There are 4 distinct path

(II) There are distinct path

(III) Count rectangle of all possible dimension = 73
(IV) There are 218 distinct path

43) (I) There are 4 distinct path

(II) There are distinct path

(III) Count rectangle of all possible dimension = 73
(IV) There are 218 distinct path

44) The number of ways in which 2 friends are selected

(Since 6 ways on each row (or) column)

45) The number of ways in which 2 friends are selected

(Since 6 ways on each row (or) column)

46)

47) Let and AC = x

By Cosine Rule

2K = 19.00

48) Highest power of (let) have to find coefficient of

49)

50) Suppose there are Tn ways to cover n steps

51) Let x3 = 3, then x1 x2 x3 + x2 x3 x4 + x3 x4 x5 + x4 x5 x1 + x5 x1 x2 = 3 (x1 x2 + x2 x4 + x4 x5) + x5

x1 (x2 + x4) So, the sum is divisible by 3 if x2 + x4 is divisible by 3, the possible sums of (x2 +x4)
can be (1, 2), (2, 1), (1, 5), (5, 1), (2, 4), (4, 2), (4, 5) or (5, 4) are we have 2 ways to designate
x1 and x5 for a total of
So, desired =