1 Name (please print carefully!

) __________________________

Student Number

Signature_____________________________________

Please check to indicate your section: Check here: Section Number 01 03 Time of class MWF, 3:30 pm TTh, 8:30 am Instructor Dr. A. Bartole-Scott Dr. M.F. Paige

CHEMISTRY 114.3 FINAL EXAMINATION

December 8, 2007 Time: 3 hours INSTRUCTIONS - PLEASE READ THIS FIRST! a. This is a closed-book examination. A data-sheet with a Periodic Table accompanies this examination paper; no other paper is required or permitted. b. Simple scientific calculators (maximum two-line display) are permitted; graphing calculators, PDA's, electronic dictionaries, etc., are not. No equations should be stored in memory. c. This examination paper has 12 pages, including a data sheet. To ensure your copy is complete and to become familiar with the questions, please read through the entire examination before you answer any questions. d. Total marks are 100. e. Answer multiple choice questions in Section A by circling a response on this paper AND by filling in the corresponding response on the blue opscan sheet USING ONLY A SOFT-LEAD PENCIL. No deductions will be made for incorrect answers so it is in your interest to answer all questions. Multiple answers to a question will be treated as NO answer; if you change your mind, erase carefully. In the event of a discrepancy between an answer on the examination paper and on the computer sheet, your response on the opscan sheet will count as your answer. f. Answer the questions in Section B on this examination paper. Show all your work on this paper because these questions will be hand-marked and partial credit can be earned. No scratch paper is permitted; use the backs of pages if necessary. g. If you have not already done so, please fill out the top of this paper now, and write your name (legibly!) and code your student number on the computer blue sheet in soft pencil. h. When handing in your exam, place the opscan sheet on top of this paper and hand in both together. i. Failure to observe these procedures may result in docking of marks. Questions Section A Section B Q 1 - 30 Q 31 Q 32 Q 33 Q 34 Total Marks Maximum Marks 60 10 10 10 10 100 Marks Earned

Section A: Multiple Choice Questions

These are worth 2 marks each. Please answer as directed above.

1. The diameter of metal wire is often referred to by its American wire gauge number. A 16gauge wire has a diameter of 0.1291 cm. What length of wire, in meters, is there in a 1.00 kg spool of 16-gauge copper wire? The density of copper is 8.92 g/cm3. A. B. C. D. E. 2.14 m 8.56 x 10-3 m 85.6 m 26.9 m 2.14 x 103 m

2. The unbalanced equation for the mixing of ammonia with chlorine bleach is shown below. NH3 + OCl- Cl2 + N2H4 Which of the following statements is correct? A. B. C. D. E. Ammonia is acting as an oxidizing agent. The chlorine atom in OCl- is reduced. The above reaction is an example of a disproportionation reaction. The oxidation state (oxidation number) of each N in N2H4 is +1. None of A, B, C or D is correct.
65 29

3. Determine the number of protons, neutrons and electrons in the following: A. B. C. D. E. p+ = 36 p+ = 36 p+ = 29 p+ = 29 p+ = 29 no = no = no = no = no = 29 29 36 34 36 e- = 34 e- = 38 e- = 29 e- = 29 e- = 27

X 2+

4. A breathing gas mixture consists of 20% (by moles) of O2 and the rest He. A sample of this gas mixture at a total pressure of 2.0 atm is compressed to exactly 1/4 its former volume; the temperature is unaltered. What is the new partial pressure of He? A. B. C. D. E. 5. 6.4 atm 1.6 atm 0.8 atm 0.4 atm None of A, B, C or D.

Which of the following contains the most number of atoms? (Hint: You do not need to do calculations) A. B. C. D. E. 10.0 g He 10.0 g Ne 10.0 g Ar 10.0 g Kr 10.0 g Pt

3 6. When the following redox reaction is balanced in basic solution, what will be the smallest whole number coefficients in front of P4 , H2PO2- and PH3, respectively? P4(s) H2PO2- (aq) + PH3(g) A. 1, 3, 1 B. 1, 2, 2 C. 2, 6, 2 D. 4, 12, 4 E. None of the above.

7. A solution of silver(I) nitrate is mixed with a solution of ammonium sulfate. The net ionic equation for the resulting reaction is: A. B. C. D. E. 2AgNO3(aq) + (NH4)2SO4(aq) => Ag2SO4(s) + 2NH4NO3(aq). 2AgNO3(aq) + (NH4)2SO4(aq) => Ag2SO4(aq) + 2NH4+(aq) + 2 NO3-(aq). NH4+(aq) + NO3-(aq) => NH4NO3(aq). 2Ag+(aq) + SO42-(aq) => Ag2SO4(s). None of A, B, C or D.

8. If an ideal gas at standard temperature and pressure occupies a volume of 40.0 mL, then what is its volume at -30.15 oC and 0.808 atm? A. B. C. D. E. 49.5 mL 44.0 mL 35.6 mL 28.8 mL None of the above.

9. A total of four moles of oxygen atoms would be found in: A. B. C. D. E. 4 moles of hydrochloric acid. 2 moles of chloric acid. A mixture containing 1 mole of perchloric acid and 1 mole of hypochlorous acid. A mixture containing 1 mole of chloric acid and 1 mole of hypochlorous acid. None of the above.

10. A compound is found to be 30.45% N and 69.55%O by mass. If 1.63 g of this compound occupy 389 mL at 0.00 oC and 775 mm Hg, what is the molecular formula of the compound? A. B. C. D. E. NO2 N2O N4O2 N2O5 N2O4

11. Which of the following solutions has the highest total concentration of ions? A. B. C. D. E. 0.15 M sodium chloride 0.15 M calcium nitrate 0.15 M sodium hydroxide 0.20 M perchloric acid 0.20 M acetic acid

4 12. Which of the following are not strong acids? I. hydroiodic acid II. hydrofluoric acid III. perchloric acid IV. bromic acid V. sulfurous acid A. B. C. D. E. I, II, and III only II and IV only I and III only II, IV, and V only All of the above are not strong acids

13. When 250 mL of 0.10 M aqueous lead(II) nitrate solution and 100 mL of 0.30 M aqueous sodium chloride solution are mixed, what mass of precipitate results? A. B. C. D. E. 7.0 g 4.2 g 0.030 g 0.025 g None of the above.

14. Determine the empirical formula for a compound that is found to contain 20.31 mg P and 34.85 mg Cl. A. B. C. D. E. PCl PCl3 PCl5 P2Cl3 None of the above.

15. If all gases are measured at the same temperature and pressure, what volume of NH3(g) is produced when 150 L H2(g) is completely consumed in the following unbalanced reaction. Assume all gases behave ideally. N2(g) + H2(g) NH3(g) A. B. C. D. E. 225 L NH3(g) 150 L NH3 (g) 100 L NH3(g) 75 L NH3(g) Not enough information given to answer this question.

16. How much energy is required to decompose 765g of PCl3 according to the reaction below: 4PCl3(g) P4(s) + 6 Cl2(g) A. 4.33x103 kJ B. 2.31 x 103 kJ C. 1.68x103 kJ D. 5.95 x103 kJ E. None of the above. H0rxn = 1207 kJ

5 17. A 35.6 g sample of CH3CH2OH (MW=46.07 g/mol) is combusted in excess oxygen to yield carbon dioxide and water. The temperature increased from 35oC to 76oC and the heat capacity of the calorimeter is 23.3kJ/oC. The Hrxn for this process is equal to: A. -1.24x103 kJ/mol B. -8.09x103 kJ/mol C. +1.24x103 kJ/mol D. -9.55x103 kJ/mol E. None of the above. 18. Which of the following are not valid combinations of quantum numbers: i. n=4 , l=3, ml =2 ii. n=3 , l=2, ml =3 iii. n=1 , l=0, ml =1 iv. n=2 , l=1, ml =0 A. i. only B. ii. only C. iii. only D. ii. and iii. E. None of the above. 19. The ground state electronic configuration of Ar2+ is: A. [Ar] 4s2 B. [Ne] 2s2 2p4 C. 1s2 2s2 2p6 3s2 3p4 D. 1s2 2s2 2p6 3s2 3p6 4s2 E. None of the above. 20. Which of the following atoms and ions are paramagnetic? A. Ca+ B. Al3+ C. FD. Both A & C E. None of the above. 21. Which of the following atoms should have the largest ionization energy? A. Sn B. As C. S D. F E. Impossible to predict. 22. The number of valid resonance structures that can be drawn for NO3- are: A. 1 B. 2 C. 3 D. 4 E. None of the above.

6 23. The next set of orbitals that occur after the f-orbitals are the g-orbitals. What is the total number of electrons that can be placed in the g-orbitals? A. 18 B. 10 C. 9 D. 8 E. None of the above. 24. For a correct Lewis structure of one resonance form of CO32-, the number of single bonds between oxygen and carbon is: A. 0 B. 1 C. 2 D. 3 E. 4 25. The molecular geometry of PF5 is expected to be: A. Trigonal bipyramidal B. Planar bipyramid C. Square pyramidal D. See-saw E. None of the above. 26. Which of the following molecules would you expect to be polar? i. CHCl3 ii. XeF4 iii. SF4 A. i. only B. ii. only C. iii. only D. i. and ii. E. i. and iii. 27. For a trigonal bipyramidal molecule, the bond angle between equatorial electron groups should be approximately: A. 90o B. 120o C. 180 o D. 109 o E. None of the above. 28. The molecular geometry of PCl3 is expected to be: A. Trigonal planar B. Bent C. Trigonal bipyramidal D. T-shaped E. None of the above.

7 29. Which of the following has dipole-dipole forces as its strongest intermolecular force: i. H2 ii. SO2 iii. NH3 iv. CF4

A. H2 B. SO2 C. NH3 D. CF4 E. None of the above. 30. Place the following substances in order of increasing boiling point: Ne, Cl2, O2 : A. Ne < Cl2 < O2 B. Cl2 < O2 < Ne C. O2 < Cl2 < Ne D. Ne < O2 < Cl2 E. None of the above.

End of Section A - Section B continues on the next page.

Section B: Short Answer Questions

Answer on this examination paper. Please show all work as partial marks can be earned. 31. (10 marks). Fill in the blanks in this table. A sample row has been filled in for you. The central atom is underlined in each case. If the Lewis structure involves resonance, then draw only one resonance form, but write "resonance" next to it. Molecule or Ion Formal Charge of underlined atom 0 Description of Molecular Geometry (Shape)** Bent or angular

Lewis Dot Structure

Electron Group Geometry * tetrahedral

H2O

NO3-

I3 (note: give formal charge and geometries of central I atom only)

AtCl2+

FNO

* You may give a verbal description OR a drawing. In the case of a drawing, it must be unambiguous, with important bond angles indicated. **Describe the arrangement of the atoms around the central (underlined) atom.

9 32. (10 marks). The combustion of methane gas, the principal constituent of natural gas is represented by the equation CH4(g) + 2O2(g) CO2(g) + 2H2O(l) Ho = -890.3 kJ What volume of CH4(g) in litres, measured at 298 K and 0.855 atm would you need to heat one block of ice (2.00 kg) to 25.0 oC and completely vaporize the water at 25.0 oC? Assume CH4(g) behaves ideally, assume initial temperature of the ice is 0.00 oC, and assume no loss of H2O in heating process. (Specific Heat capacity, Cs (H2O(l)) = 4.184 J/ g oC) (Hfus (H2O(s): 273 K) = 6.01 kJ/mol ; Hvap (H2O(l): 298K) = 44.0 kJ/mol)

10 33. (10 marks). A 0.2278 g sample that contains an unknown amount of the compound As2O3 requires 22.15 mL of 0.02237 M KMnO4(aq) for its titration under acidic conditions. Determine the percentage by mass of As2O3 in the original sample. The unbalanced titration reaction is: As2O3(s) + MnO4-(aq) H3AsO4(s) + Mn2+ (aq)

11 34. (10 marks). Answer the following questions based on the phase diagram shown below:

Pressure (atm)

1.00

E A C B
55o

0.10

Temperature (oC)

i)

What phases are present at point: A: ______________________ C: ______________________ B: ________________________ D: ________________________

ii)

What is the name given to point: E: ______________________ F: ________________________

iii)

Clearly draw a dot and label where the normal boiling point should appear on the phase diagram. What will happen if the sample is heated from a low temperature to 55oC at a pressure of 0.10 atm?

iv)

THE END

Useful Data
1A 1

H
1.008 3 2A 4

Periodic Table of the Elements

THE PERIODIC TABLE of ELEMENTS 3A 4A 6 5A 7 6A 8 7A 9

8A 2

He
4.003 10

Li
6.941 11

Be
9.012 12 8B 3B 21 4B 22 5B 23 6B 24 7B 25 8 26 9 27 10 28 1B 29 2B 30

5 B
10.81 13

C
12.01 14

N
14.01 15

O
16.00 16

F
19.00 17

Ne
20.18 18

Na
22.990 19

Mg
24.305 20

Al
26.98 31

Si
28.09 32

P
30.97 33

S
32.07 34

Cl
35.45 35

Ar
39.95 36

K
39.10 37

Ca
40.08 38

Sc
44.96 39

Ti
47.88 40

V
50.94 41

Cr
52.00 42

Mn
54.94 43

Fe
55.85 44

Co
58.93 45

Ni
58.69 46

Cu
63.55 47

Zn
65.39 48

Ga
69.72 49

Ge
72.59 50

As
74.92 51

Se
78.96 52

Br
79.90 53

Kr
83.80 54

Rb
85.47 55

Sr
87.62 56

Y
88.91 57

Zr
91.22 72

Nb
92.91 73

Mo
95.94 74

Tc
(98) 75

Ru
101.1 76

Rh
102.9 77

Pd
106.4 78

Ag
107.9 79

Cd
112.4 80

In
114.8 81

Sn
118.7 82

Sb
121.8 83

Te
127.6 84

I
126.9 85

Xe
131.30 86

Cs
132.9 87

Ba
137.3 88

La *
138.9 89

Hf
178.5 104

Ta
180.9 105

W
183.8 106

Re
186.2 107

Os
190.2 108

Ir
192.2 109

Pt
195.1

Au
197.0

Hg
200.6

Tl
204.4

Pb
207.2

Bi
209.0

Po
(210)

At
(210)

Rn
(222)

Fr
(223)

Ra
(226)

Ac **
(227)

Rf
(257)

Ha
(260)

Sg
(263)

Ns
(262)

Hs
(265)

Mt
(266)

* **

58

59

60

61

62

63

64

65

66

67

68

69

70

71

Ce
140.1 90

Pr
140.9 91

Nd
144.2 92

Pm
(147) 93

Sm
150.4 94

Eu
152.0 95

Gd
157.3 96

Tb
158.9 97

Dy
162.5 98

Ho
164.9 99

Er
167.3 100

Tm
168.9 101

Yb
173.0 102

Lu
175.0 103

Th
232.0

Pa
(231)

U
238.0

Np
(237)

Pu
(242)

Am
(243)

Cm
(247)

Bk
(247)

Cf
(249)

Es
(254)

Fm
(253)

Md
(256)

No
(254)

Lr
(257)

USEFUL DATA
Constant Atomic mass unit Avogadros number Gas Constant Molar Volume of an Ideal Gas at STP Plancks constant Hvap (H2O, 373K) Conversions 1 cm3 = 1 mL 1 kg m2/s2 = 1 J 1 cal = 4.184 J 1 L atm = 101.33 J 1 Pa = 1 N/m2 STP conditions: Volume of a sphere = (4/3)r3 Volume of a cylinder = r2xh Symbol u NA
R

Value 1.6605 x 10-27 kg 6.0221 x 1023 mol-1 0.082058 L atm mol-1 K-1 8.3145 J mol-1 K-1 22.414 L mol-1 6.6261 x 10-34 J s 40.7 kJ/mol

P = 1 atm = 760 Torr = 760 mm Hg = 101.325 kPa Temperature = 0 oC = 273.15 K