Chapter 20: Oxidation-Reduction Reactions: Lesson 20.3: Describing Redox Equations
Chapter 20: Oxidation-Reduction Reactions: Lesson 20.3: Describing Redox Equations
- One class of chemical reactions is oxidation-reduction (redox) reactions, in which electrons are
transferred from one reacting species to another.
- The other class includes all other reactions, in which no electron transfer occurs.
- Two different methods for balancing redox equations are the oxidation-number-change method
and the half-reaction method.
oxidation-number-change method
Step 1: Assign oxidation numbers to all the atoms in the equation. Write the numbers above the
atoms.
Step 2: Identify which atoms are oxidized and which are reduced.
Step 3: Use one bracketing line to connect the atoms that undergo oxidation and another such
line to connect those that undergo reduction.
Step 4: Make the total increase in oxidation number equal to the total decrease in oxidation
number by using appropriate coefficients
Step 5: Finally, make sure the equation is balanced for both atoms and charge. If necessary,
finish balancing the equation by inspection
half-reaction method.
- The second method for balancing redox equations involves the use of half-reactions.
- A half-reaction is an equation showing just the oxidation or just the reduction that takes place in
a redox reaction.
- In the half-reaction method, you write and balance the oxidation and reduction half-reactions
separately before combining them into a balanced redox equation.
- The procedure is different, but the out-come is the same as with the oxidation-number-change
method.
Step 2: Write separate half-reactions for the oxidation and reduction processes.
Step 4: Add enough electrons to one side of each half-reaction to balance the charges.
Step 5: Multiply each half-reaction by an appropriate number to make the numbers of electrons
equal in both.