Class 12 Part Test

7 AITS-PT-I (Paper-1)-PCM-JEE (Advanced)/2021
Chemistry PART – II
SECTION – A
(One Options Correct Type)
This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
3/ 2
2 1 
19. If an orbital is represented by        1  2  8  12  e / 2 cos  belong to which
3  3a0 
orbital
(A) 6dx2  y 2
(B) 5p z
(C) 5p y
(D) 6dz2
20. For an elementry reaction

 d A  
mA   Product, the graph is plotted between log10    vs log10  A  . It gives straight line
 dt 
with intercept equal to 0.6 and showing an angle 45 o with origin, then
(A) rate constant = 3.98 time-1 and m = 1
(B) rate constant = 3.98 mole L-1 time-1 and m = 1
(C) rate constant = 1.99 mole L-1 time-1 and m = 1
(D) rate constant = 1.99 mole L-1 time-1 and m = 2
21. In manufacture of Na 2CO3 from solvay process the raw material used is
(A) NaOH
(B) Na 2SO 4
(C) NaCl
(D) NaHCO3
22. Which of the following is the correct statement?

(A) T  3 and Al3 act as an oxidizing agent in aqueous solution
(B) In TI3 ,T oxidization state is (+3)
(C) Hydrogen bonding in H3BO3 gives a layered structure
(D) B  OC2H5 3 burns with blue edge flame
23. The correct order second ionization potential of C, N, O and F is

(A) C>N>O>F
(B) O>N>F>C
(C) O>F>N>C
(D) F>O>N>C
24. In which of the following molecule/ions are all the bond angles not equal
(A) SiF4
(B) ICl4
(C) SF4
(D) PCl4
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AITS-PT-I (Paper-1)-PCM-JEE (Advanced)/2021 8
(One or More than one correct type)

This section contains 06 multiple choice questions. Each question has FOUR options (A), (B), (C) and
(D). ONE OR MORE THAN ONE of these four options is(are) correct.
25. Choose the correct statement(s)

(A) BeCO3 is kept in the atmosphere of CO2 since it is thermally unstable.
2
(B) Be is dissolved in alkali forming Be  OH 4  .
(C) BeF2 form complex ion with NaF in which Be goes with cation.
(D) BeF2 form complex ion with NaF in which Be goes with anion.
h
26. The orbital angular momentum is 3 , which of the following should not be the permissible value

of orbit angular momentum of this electron revolving in Bohr orbit?
h
(A)
2
h
(B)

h
(C) 3
2
2h
(D)

27. 
For a reaction A  B 
 2C, K c  1 . If the initial concentration of A, B and C are 1 M, 1 M and 2
M then at equilibrium
(A) [A] = [B] = [C]
4
(B) A  3 M
2
(C) B  3 M
1
(D)  A   C
2
28. Which of the following statements are correct?

(A) In ClF3 , the axial Cl – F bond length is larger than equilateral Cl – F bond length.
(B) In ClF3 , all the Cl – F bond angles are 90o.
(C) In SF4, F – S – F equitorial bond angle is not 120o but 102o due to lp – bp repulsion.
(D) In OBr2, the bond angle is less than OCl2.
29. Identify the correct statement

(A) time of 75% completion of reaction is thrice of half-life in second order reaction.
(B) for a reaction whose equilibrium constant greater than one. Activation energy of forward
reaction is greater than backward reaction
(C) molecularity of slowest step will be zero or fraction.
(D) In zero order reaction half life is directly proportional to initial concentration
30. Which are correct for radio activity?

(A) Half-life is independent of initial amount of radioactive substance
(B) The increasing the temperature half-life will decrease
(C) Half-life of C-14 in CO2 is different from that C-14 in C6H12 O6
(D) Half-life of U-235 and U-238 are different.
SECTION – C
(Numerical Answer Type)
This section contains 06 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the second
decimal place; e.g. XXXXX.XX).
31. How many ml of 0.1 M NaOH is added to 60 ml of 0.15 M H3PO 4 ( pK a1 ,pK a2 and pK a3 for H3PO 4
are 3, 8 and 13). So, that pH of resulting buffer solution would be 8.3. (log2 = 0.3)
32. In 200 ml solution of 0.1 M NaOH and 0.2 M NH4 OH , 300 ml of 0.1 M HCl is added. Find pH of
solution  pK b of NH4 OH  5  . (and given log3 = 0.48).
33. What is the pH after addition of 40 ml of 0.1 M NaOH in the 50 ml of 0.1 M anilinium chloride
pK a of anilinium ion  4.6 
34. Hydrogen like species is in some excited state ‘P’ and on absorbing a photon of wavelength ‘a’
eV reached to a new state ‘Q’ on de-excitation back to the ground state a total of 10 different
wave lengths were emitted in which seven have energy greater than ‘a’ eV. The ionization energy
in the ground state will be “xa” eV .Find the value of x.
35. In a sample of H atoms, electron are de-excited from a level ‘n’ to ground state. Total number of
Lyman lines emitted are 3. If the electron are ionized from this level ‘n’ by a photon of 15 eV.
Then kinetic energy of emitted photon is x eV. Find x.
36. For a substance P undergoing parallel reaction

Q
K1
P
K2 R
K1  0.372min1 and K 2  0.321 min1

.
What will be concentration of P after 30 sec where initial concentration of P is 1 molar
SECTION – A
19. Select the correct statement with respect to Na2 O2

(A) It decolourises acidified KMnO 4
(B) It is obtained along with Na metal when Na2 O is heated to a temperature more than
400o C
(C) On heating with oxygen at 450o C and 300 atm it becomes paramagnetic
(D) It gives both H2O2 and O2 with water
20. Which of the following disproportionate on heating with NaOH?

(A) P4
(B) S8
(C) Cl2
(D) Boron
21. Which of the following are correct regarding s-Block elements

(A) The reducing character of the alkali metal hydride follows the order:
CsH  RbH  KH  NaH  LiH
(B) The bicarbonates of alkaline earth metal are only stable in solution
(C) LiI is the most ionic in nature among the alkali metal halides
(D) Magnesium nitrate on heating decomposes to give NO 2 and O2
22. Which of the following are correct regarding Si compounds?

(A) Cross link silicones are obtained by hydrolysis of RSiCl3
(B) Linear silicone are obtained by hydrolysis of R 2 SiCl2
(C) Sc 2  Si2O7  is a example of pyrosilicate
(D) In three dimensional sheet silicates three oxygen atom of SiO 44 is shared with adjacent
SiO 44 unit
23. Which of the following statement are correct?

(A) Ionic carbide are formed by highly electropositive metals
(B) Carborundum and boron carbide are covalent compound
(C) Carborundum and boron carbide are used as abrasive
(D) Al4 C3 and CaC2 on hydrolysis gives C2H2
24. Which of the following are polar?

(A) XeO3
(B) XeOF4
(C) XeF4
(D) BrF6
SECTION – B
(Single Digit Integer Type)
This section contains 06 questions. The answer to each question is a Single Digit integer ranging from
0 to 9, both inclusive.
25. xU  SO 4 2  yKMnO 4  zH2O  H2SO4  K 2SO 4  MnSO 4  UO2 SO 4

Find the value of x + y + z? (Minimum integral value of x, y, z)
26. 100 ml of sample of tap water contain 0.192 mg of Mg2 , what is the hardness as parts of
CaCO3 per million part of water.
27. Two bulb P and Q are emitting monochromatic light of wave length such that P can just ionize
H-atom and Q can just ionize He ion. If power of P and Q are 60 W and 80 W. The ratio of
number of photons emitted per sec by bulb P and Q is:
28. For the following reaction


A  B  
C D K c  16
if 0.4 mole of A and 0.4 mole of B, 2 moles of C and 2 moles of D are mixed in container of
volume 80 ml. Then the equilibrium concentration of B will be.
29. During a decay of 952 gram 92 U238 to 82 Pb 206 , total 18.066  10 24   particle are emitted, number of
half lives completed in this decays are
30. What is the concentration ratio of sodium acetate to acetic acid when pH of solution is 5.35.
[pKa of acetic acid = 4.75]
SECTION – C
31. A diatomic molecule has a dipole moment of 1.2 D. if its bond length is equal to 1010 m then the
percentage ionic character is x%. Find x. (1 D = 3.336  10 30 C  metre)
32. Bromophenol is an acid indicator having dissociation constant 105 , the pH of solution at which
indicator is 80% ionized. [log2 = 0.3]
33. When one mole of K 4 Fe  CN 6  is heated with conc. H2SO 4 , the evolved gas during reaction is
reacted with excess of I2 O 5 .find how many moles of I2 will be liberated during the reaction
34. A flask is filled with N2O3  g at 2 bar pressure, and following equilibrium is established.


Reaction 1: N2O3  g  
 NO2  g   NO  g  ; K p  2.5 1
Reaction 2: 2NO2  g  

 N2O4  g ; K p2  ?
If at equilibrium partial pressure of NO (g) is 1.5 bar, then find equilibrium constant for second
reaction

K1 sec 1 
35. A  B

K2 M 1
sec 1 
C  D
Starting with 1 molar initial conc. of reactant of each reaction, it takes 10 sec. to reach to 0.5
molar in each reaction. Then find the ratio of k1/k2.
36. In the following reaction started only with A


2A   2B  3C  D
mole fraction of C is found to be 0.36 at a total pressure of 200 atm. The mole fraction of A at
equilibrium is (Note : Reactant and product are gases).
9 AITS-PT-I-PCM-JEE(Main)/2021
SECTION – A
26. Which of the following statements is not true about BeH2?

(A) It can be obtained by reduction of BeCl2 with LiAlH4
(B) It is polymeric in nature
(C) It is a covalent hydride
(D) It is ionic in nature
27. Choose the correct statement from following:

(A) H2 is more rapidly adsorbed on surface for physisorption than D 2
(B) H2 is more rapidly adsorbed on surface for chemisorption than D2
(C) H2 reacts slower with Cl2 than D2
(D) H2 has higher bond dissociation energy than D2
28. Choose the incorrect statement.

(A) Boron sesquioxide is the anhydride of ortho-boric acid
(B) H3BO3 is a Lewis acid, not a Bronsted acid
(C) H3BO3 no longer used as an antiseptic powder for babies because it sometimes caused
rash
(D) Orthoboric acid is insoluble in H2O
29. The most basic oxide among the following is

(A) SiO2
(B) MgO
(C) Na2O
(D) Al2O3
30. In which of the following process, the magnetic moment value does not change
(A) O 2  O 2
(B) O 2  O 2+
(C) N 2  N 2+
(D) N 2+  N 2
31. Choose the correct statement:

(A) If AB3 molecule is polar then all its bond angles must not be same
(B) If all the bond angle of AB3 is same then it must be a planar molecule
(C) If all bond angle of AB3 is same then it may or may not be planar molecule
(D) If only sigma bonds are present then only AB3 can be a planar molecule
32. Number of distinct spectral line possible during de-excitation, when hydrogen atom in ground
state is excited by providing 3.4 eV of energy
(A) 3
(B) 0
(C) 6
(D) 10
AITS-PT-I-PCM-JEE(Main)/2021 10
33. For a reaction:



2A  g   B  g  
 C  g   3D  g 
at 300 K, Kc = 2 mol L1, what must be the volume of the container, if 2 mole each of A, B, C and
D are present at equilibrium:
(A) 4 litre
(B) 1 litre
(C) 0.5 litre
(D) 8 litre
34. What will be the concentration of F ion in saturated solution of CaF2? If Ksp of CaF2 is 32  1012
mol3 L3
(A) 2  104 mol/lit
(B) 4  104 mol/lit
(C) 8  104 mol/lit
(D) 4  102 mol/lit
35. For the first order reaction: A  2B, following graph is observed, time required for 75%
completion of reaction would be
Product
Concentration
Reactant
20
Time (minutes)
(A) 40 min
(B) 34.19 min
(C) 68.38 min
(D) 80 min
(Given log 2 = 0.301, log 3 = 0.477)
36. 0.1 mole of 92U238 undergo radioactive decay to form 82Pb206 by emitting  and  particles. The
number of moles of  - particles emitted in two half life would be
(A) 0.9
(B) 0.45
(C) 1.2
(D) 0.6
37. An element ‘X’ has IE1, IE2 and IE3 are 738 kJ/mol, 1451 kJ/mol and 7733 kJ/mol respectively. ‘X’
would be (I.E. = Ionization energy)
(A) Na
(B) Mg
(C) Ne
(D) F
11 AITS-PT-I-PCM-JEE(Main)/2021
38. The following equation are given:

1 3

N2  H2  
 NH3 ; K1 .... i 
2 2

2NO  
 N2  O 2 ; K2 .... ii 


2H2  O 2 
 2H2 O; K3 ....  iii 
What will be equilibrium constant (K) for following reaction:
5

2NO  3H2O   2NH3  O2 ; K ...  iv 
2
2 3/2
(A) K1 .K 2 .K 3
(B) K 2 .K 1/ 2 3/2
1 .K 3
K12 .K 2
(C)
K 33 / 2
K 33 / 2 .K 2
(D)
K12
39. Which of the following solution cannot act as buffer solution when equal volume of each is mixed?
(A) 0.1 M CH3COONa + 0.12 M CH3COOH
(B) 0.2 M CH3COONa + 0.1 M HCl
(C) 0.1 M CH3COONa + 0.2 M HCl
(D) 0.1 M NH3 + 0.1 M CH3COOH
40. For the following reaction:

BaCl2  Na3PO4   Ba3 PO4 2  NaCl
Minimum number of moles of BaCl2 required for complete consumption of 1 mole of Na3PO4
2
(A)
3
3
(B)
2
(C) 2
(D) 1
41. Choose the correct option for following statements:

(I) CaC2 on hydrolysis produce acetylene
(II) Al4C3 on hydrolysis produces propyne
(III) Al2(CH3)6 has 3 – centre, 2 – electron bond
(IV) Al4C3 on hydrolysis produces methane
(A) I, II and III are correct statements
(B) only I and IV statements are correct
(C) I, III and IV statements are correct
(D) II and III statements are incorrect
42. Choose incorrect statement:

(A) S has a lower electron gain enthalpy than Cl
(B) B has lower ionization energy than Be
(C) Cl has lower ionization energy than F
(D) P has lower ionization energy than S
43. Which of the following pair are isotones?

14
(A) 6C and 7N14
(B) 32 Ge76 and 33 As77
AITS-PT-I-PCM-JEE(Main)/2021 12
(C) 26 Fe58 and 27 Ni58

(D) 16 S32 and 16 S 34
44. Temperature coefficient for a first order reaction is 2. If the half life for the reaction at 25C is
10 min, what would be half life of same reaction at 45C?
(A) 20 min
(B) 5 min
(C) 150 seconds
(D) 120 seconds
45. For the following equilibrium reaction:



CO  g   2H2  g  
 CH3 OH  g 
CH3OH(g) will be consumed when
(A) pressure of the system is increase
(B) volume of the system decreased
(C) Ar gas is added of constant volume
(D) Ar gas is added at constant pressure
SECTION – B
(Single digit integer type)
This section contains 02 questions. The answer to each question is a single Digit integer ranging from 0
to 9, both inclusive.
46. The ratio of wave numbers associated with longest wave length of Paschen series for Li2+ ion to
the shortest wavelength of Brackett series of H – atom would be.
47. How many of the following molecules have zero dipole moment:
CHCl3, CH2Cl2, SF4, SF6, BF3, NH3, PCl3F2, PCl2F3
Cl OH
Cl OH
SECTION – C
48. For the following reaction:

Cu  HNO3   Cu NO3 2  NO2  H2O
What will be the ratio of stoichiometric coefficient of HNO 3 to NO2 in balanced reaction?
49. Acetic acid (100 ml, 0.1 M) is titrated with 0.1 M NaOH. What will be the difference in pOH
reading, when 80 ml NaOH is added and when 100 ml NaOH is added?
(Given pKa (CH3COOH) = 5, log 2 = 0.3)
50. Equal volume of 0.1 M weak acid HA (Kb of A = 5  1010) and NaOH (0.1 M) is mixed, what will
be the percentage of hydrolysis of NaA formed at 298 K?
AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/2021 8
SECTION – A
19. In the following reaction

C6H5 OH
H SO
N 
2 4
 P
Major product 
CH3CH2
The major product (P) is
O
||
(A) C6H5  C NH  CH2CH3
O
||
(B) C6H5  NH  C CH2CH3
(C) C6H5  CH  N  CH2 CH3
(D) C6H5  N  CH  CH2 CH3
20. Which among the following compounds is most basic?

H3C
(A) NH
H3C
H3C
(B) NH
H2N
H2N
(C) NH
H2N
Cl
(D) NH
Cl

O
CH CO H
H3C O C Ph 
3 3
 P
The major product (P) is
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9 AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/2021
O
(A) HO C Ph
O
(B) H3C O C OH
O
(C) H3C O O C Ph
O
(D) H3C O C O Ph
22. Which of the following would give positive Fehling solution test?
(A)
O Ph
(B)
O OH
O
(C)
CH3
(D)
O OCH3
23. In the given reaction

D
i BH3 /THF
 
ii H2O2 /OH
D
The major product is
H
(A) H
D
H
D
(B) D
OH
D
H
(C) D
OH
H
(D) OD
24. For the following reaction

O
NaBH4
O C OCH 3   Q
The major product (Q) is
(A)
HO CH2OH
(B)
O CH2 OH
O
(C)
HO C OCH 3
O
(D)
O C OH

25. Which of the following compounds show geometrical isomerism?

Br
Cl
C
(A) Cl
Br
(B) CH3  N  N  CH3
H3C CH3
(C) C C C
Cl Cl
(D)
Br Br
26. OH
CH2OH CH2OH
O O
O OH
HO HO
OH OH
Compound (P)
Which of the following statement (s) is/are correct about compound (P)?
(A) Compound (P) is Maltose
(B) Compound (P) on hydrolysis produces D-galactose and D-glucose.
(C) Compound (P) is a reducing sugar.
(D) Compound (P) shows mutarotation.
27. Which of the following statement(s) is/are correct about polymers?

(A) Neoprene is a polymer of isoprene.
(B) Glyptal is a condensation polymer of ethylene glycol and phthalic acid.
(C) Terylene is a condensation polymer of ethylene glycol and terephthalic acid.
(D) Nylon-6,6 is a condensation polymer of hexamethylenediamine and adipic acid.
28. Which of the following group(s) is/are ortho-para directing and deactivating for electrophilic
aromatic substitution reaction?
(A) CH  CH  NO2
(B) Cl
(C) SO3H
(D) CN
29. The reaction(s) which correctly match with their major product is/are
CCl3 CCl3
(A) 
HBr

Br
(B) OH
i BH3  THF

ii CH3COOH

CH3 CH3
(C) 
Cl OH
H O
2
2
Cl
CH3 CH3
OCH3
(D) i HgOAc 2 ,CH3OH
  
ii NaBH4 , OH
30. In which of the following reaction (s) the configuration of the chiral carbon is retained in the
product?
C2H5
1 Na
(A) H OH 
2 CH3Br

C 2H 5
1 TsCl
(B) H OH  
 2 CH3ONa
D
C2H5
SOCl
(C) H OH  2
Pyridine

C2H5
CH MgBr
(D) H OH 
3

SECTION – C
31. The observed rotation of 2 gram of a compound in 10 ml of solution in polarimeter tube of 25 cm

long is +24.6o. The specific rotation of the compound (in degree) is
32. The relative reactivity of 1o : 2o : 3o hydrogen to bromination is 1 : 82 : 1600. In the following

reaction
Br
CH3  CH2  CH3 
h  H3C
2
CH CH3  CH3 CH2CH2Br
Br
the percentage yield of 2-Bromopropane is

O
 
 Ph3 P CH2 
 R  Ph3PO
Product 
the percentage mass of hydrogen in the product (R) is
1 O3 dil.NaOH

 2 Zn/H2O
 A   B
x
the molecular weight of the major product (B) is x. The value of is
5
35. When formaldehyde is treated with ammonia a crystalline compound urotropine is formed. If the
number of carbon atoms and nitrogen atoms in the compound are x and y respectively then the
x
value of is
y
36. The weight of CH4 (in grams) produced by reacting 4.6 grams of glycerol with excess of CH3MgBr
is
SECTION – A
19. In the following reaction, the product (s) formed is/are
 Product  s 
CHCl NaOH

3
N
H
(A)
CHO
N
(B)
Cl
N
Cl
(C)
N
Cl
(D)
N
20. Which of the following compound(s) form yellow precipitate on reaction with I2 and NaOH
solution?
CH3
(A) H3C
OH
CH3
(B) H3C
O
(C) CH3 – CH2 – OH
(D) H3C CH3

O
21. Which of the following compound (s) is/are optically inactive?

(A)
Br Cl
H3C CH3
(B) C C C
H2N NH2
NO 2 HOOC
(C)
NO 2 O 2N
O
CH3 H
O
(D)
H O H3C
22. The reaction (s) which correctly match with their major product is/are
H O

3
(A)
OH
Br
Br2
(B) 
CCl4 
Br
OH
cold aq.KMnO4
(C) 
OH

OH
OH OH
Br Br
Br /H O

2 2

(D)
Br
23. Which of the following compounds will be oxidized by HIO 4?

(A) H 2C OH
HC OH
CH3
(B) H2C OCH 3
HC OH
CH3
(C) CH 2OH
CH 2
CH 2OH
(D) CH2OH
C O
CH2OH
24. Which of the following compound(s) will liberate CO2 on reaction with NaHCO3?
(A) HO O
HO O
(B) OH
O 2N NO2
NO2
(C) COOH
NO2
(D) COOH
OCH3
SECTION – B
(Single Digit Integer Type)
This section contains 06 questions. The answer to each question is a Single Digit integer ranging from
0 to 9, both inclusive.
25. Total number of structural isomers of molecular formula C4H6 is
26. The total number of cyclic structural isomers of molecular formula C 4H7Cl is
27. The total number of aromatic molecules/ions among the following is
O
CH3
B N
N
N O
H
28. In the following sequence of reactions

O
OC2H5
C H ONa  H O/H

2 5
 A 
2
 B  C
OC2H5
O
Degree of unsaturation in the product (C) is
29. The number of moles of formic acid formed by the oxidative cleavage of one mole of D-Glucose
by excess of HIO4 is
30. Among the following the number of compounds which are more basic than aniline is
NH2 NH2
OCH3 N N
NO2 H
NH2 NH2 NH2

OCH3
OH
SECTION – C
31. The pKa values for the three ionisable groups x, y and z of Lysine are 2.2, 9.0 and 10.5
respectively.
H3N CH2 CH2 CH2 CH2 CH COOH
(z) NH3 (x)
(y)
The isoelectric point of Lysine is

NH2
 CHCl3  3KOH 
 P  3KCl  3H2O
Pr oduct 
R 
the percentage yield of the product (P) is 100%. The weight in grams of the product (P) formed by
completely reacting 21.25 grams of reactant (R) is
33. Specific rotation of     2  butanol is 12.5o . A sample of 2-butanol containing both the
enantiomers was found to have specific rotation value of – 2.8. The percentage of
    2  butanol in the sample is
34. n-Butane is produced by monobromination of ethane followed by the Wurtz reaction. The weight
of ethane (in grams) required to produce 7.25 g of n-Butane if the bromination and Wurtz reaction
take place with 100% yield is [Atomic weight of Br = 80].

Cl
AlCl
Zn Hg/HCl
O 
3
P   Q
the percentage yield of the product Q is 100%. The molecular weight of product (Q) is x. The
x
value of is
8
36. OH
MnO

2

 P
OH
R 
In this reaction the percentage yield of the product (P) is 100%. The weight in grams of the
product (P) formed by completely reacting 22.8 grams of the reactant (R) is
9 AITS-PT-II-PCM-JEE(Main)/2021
SECTION – A
26. In the elimination of given vicinal dihalide with Zn/CH3COOH, which conformation leads to
formation of cis – 2 – butene?
(A) H (B) H
Cl H Cl H
CH3 Cl Cl CH3
CH3 CH3
(C) CH3 (D) CH3
Cl H Cl H
H Cl Cl H
CH3 CH3
27.
Ph

Et 
H
The major prdoduct is
OH
AITS-PT-II-PCM-JEE(Main)/2021 10
(A) Ph (B)
Et Ph
Et
(C) (D)
Ph
Et
Et
Ph
28. The energy profile diagram that corresponds to COOH – CH2 – CH2 – COOH for rotation around
C2 – C3 bond in acidic medium is:
(A) (B)
PE PE
0 60 120 180 0 60 120 180

 
(C) (D)
PE PE
0 60 120 180 0 60 120 180

 
29. The major product of the following reaction is

O
Br

NaBH4
MeOH, 250 C
 P.
(A) O (B) OH
H
(C) OH (D) OH
Br Br
30. The major product formed in the following reaction sequence is:
O 
O3 / Zn
low temperature
 
PhNH2
 Pr oduct  Major  among the following is
O
O O
(A) N Ph (B) Ph
O N OH
H
O
(C) Ph – N = CH – CH2 – COOH (D)
H2C CH CH2 C NH Ph
31. Which of the following tests do not confirm the presence of carbohydrate molecules?
(i) Xanthoprotic test (ii) Molisch test
(iii) Biuret test (iv) Barfoed test
(A) (i), (ii), (iii)
(B) (i), (iii), (iv)
(C) (i), (iii)
(D) (i), (ii), (iii), (iv)
32. The type of forces present is cis – polyisopropene molecule that held them together are
(A) Weak vander Waal’s
(B) H – bonding
(C) Dipole – dipole
(D) Ion – dipole
33. For the reaction:



HX  aq  H2 O    
 H3 O  aq   X  aq
 
The highest value of [X] (aq), when X is

(A) F
(B) Cl
(C) NO2
(D) I
34. The major product in the following reaction is:

O
i  CH  CuLi
OTBs 
3 2
 ii H2O
TBS = Si(CH3)2t – C4H9

(A) HO OTBS (B) O OTBS
(C) O OTBS (D) HO OTBS
35. The major product in the following reaction is:

 1 NaOH, iso Pr  CHO
NO2 
 2  
(A) NO2 (B) OH
OH
(C) NO2 OH (D)
36. Ph

2 CH3 C CH2 
H
Major product is :
(A) Ph (B)
Ph
(C) (D)
C CH C
Ph
Ph
37. High blindness is caused by deficiency of

(A) Vitamin A
(B) Vitamin B2
(C) Vitamin C
(D) Vitamin D
38. For the given reaction
1 NaOBr
O 
 2 H / 
P
O
NH2
The correct statement regarding major product P is
(A) P has an acidic group (COOH)
(B) P has an amine group (NH2)
(C) P has both (COOH) and (NH2) group present
(D) P on hydrolysis produce a molecule with both (COOH) and (NH2) group present
39. NH2
OH
X
HNO2
  A. X= OCH 3
H CH3
Ph
Major product A in the above reaction is
(A) O H3C (B) O H
H CH3
Ph C C Ph C C
X X
(C) O H3C (D) O H

H CH3
Ph C C Ph C C
Ph Ph
40. The product(s) of which of the following reaction (s) is/are incorrect?
(i) CH3
CH3 C CH2 CH3
anhy. FeBr3
H3C C CH2 Br   CH3
CH3
(ii) Br
O

Br2 / CCl4

OH
(iii) OH

H3 O
 
(A) (i), (iii)

(B) (ii), (iii)
(C) only (i)
(D) only (iii)
41. O
 i LiAlH

ii H2 O  The major product is
4
(A) (B) OH
OH
(C) (D)
42. O
Me O

TsOH
acetone
 The major product
OH
(A) O (B) O
Me O Me O
OTs
(C) O (D) O
Me Me
OH
43.
 3
i CH I excess 

 ii H2 O /   P
NH2
The correct statement about product P is
(A) The product is formed in according to Satzeff rule
(B) The mechanism followed is E1
(C) The product has 1 degree of unsaturation and OH group
(D) The mechanism followed is E2
44. O
 2
i Me CuLi

 ii R  X  The major product is
(A) HO Me (B) O
R R
(C) O (D) O
R Me
Me R
45. Sodium nitroprusside is used to confirm the presence of which element is organic compound?
(A) Nitrogen
(B) Nitrogen and sulphur
(C) Sulphur
(D) Halogen
SECTION – B
46. The total number of cyclic isomer (position and optical) of a compound having molecule formula
C3H2Br2 is
47. If the following compound is treated with Pd/C in excess of H2 gas, how many stereoisomerism of
the product will be obtained?
SECTION – C
48. The isoelectric point for the given amino acid is:
pk a  8.90  H2N CH COOH pk a  2.20 
(H2C)4 NH2
pk a  10.28 
49. H2C OH
C O
HC OH

5HIO4
Pr oduct  s 
HC OH
HC OH
H2C OH
The ratio of number of moles of CO2 produced by HCOOH produced in the reaction is.
50. Considering the following polymers, if X is the number of addition polymer and Y is the number of
X
condensation polymer, then calculate ?
Y
Dacron, Nylon 6, 6, Nylon-6, Teflon, Polyacrylonitrile
AITS-PT-III (Paper-1)-PCM-JEE(Advanced)/2021 6
SECTION – A
(MCQ Single Correct type)
This section contains 06 questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.
19. The geometry of Ni  CO  4 and Ni PPh3 2 Cl2  are respectively:

(A) Both square planar
(B) Tetrahedral and square planar respectively
(C) Both tetrahedral
(D) Square planar and tetrahedral respectively
20. The chemical composition of ‘slag’ formed during smelting process in the extraction of copper is
(A) Cu2O  FeS
(B) CuSiO3
(C) FeSiO 3
(D) CuFeS 2
21. Which of the following reaction is taking place in the final step of metallurgical extraction of Cu
metal from copper pyrite in Bessemer furnace?
4Cu2 O  FeS   8Cu  FeSO4
(A)
(B) Cu2S  O2   2Cu  SO2
(C) Cu2 S  2FeO 
 2Cu  2Fe  SO2
(D) 2Cu2O  Cu2S 
 6Cu  SO2
22. Which of the following compounds dissolves in a mixture of NaOH/H 2O2 and undergoes
oxidation?
(A) BeO
(B) Cr(OH)3
(C) ZnO
(D) Al(OH)3
23. Which of the following is correct match?

(A) Both XeOF4 and BrF5 contains same number of valence electrons and are square
pyramidal
(B) Both XeOF4 and XeO 46  contains same number of valence electrons and are octahedral
(C) Both XeO 46  and BrF5 contains same number of valence electrons and are square
pyramidal
(D) Both XeOF4 and BrF5 contains same number of valence electrons and are octahedral
24. A salt on treatment with dilute H2SO 4 liberates a colourless gas, the gas gives following
observations
(i) White turbidity with Baryta water
(ii) Turns acidified dichromate solution green
(iii) Gives yellowish white turbidity with H2S
The anion in the salt is
(A) CO 32 
7 AITS-PT-III (Paper-1)-PCM-JEE(Advanced)/2021
(B) C 2 O 24 
(C) SO32 
(D) NO2
This section contains 06 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
25. Coordination compounds have great importance in biological systems. Which of the following
statement(s) is/are correct?
(A) Chlorophyll is a green pigments in plants and contain calcium
(B) Cyanocobalamin is vitamin-B12 and contains cobalt
(C) Carboxypeptidase-A is an enzyme and contains zinc
(D) Haemoglobin is the red pigment of blood and contains iron
26. A blue colouration or blue ppt. is obtained when

(A) NH3 is mixed in CuSO 4 solution
(B) FeCl3 reacts with K 4 Fe  CN 6 
(C) FeCl2 reacts with K 3 Fe  CN 6 
(D) Alkali metal dissolve in NH3 to form dilute solution
27. XeF4 can act as

(A) Flouride ion donor
(B) Reducing agent
(C) Oxidising agent
(D) Flouride ion acceptor
28. A binary solution of liquid ‘A’ and ‘B’ will show negative deviation from Roult’s law if it fulfills the
following condition(s):
(A) PA  PAo X A and PB  PBo XB
(B) The intermolecular forces of A – B > A – A and B – B
(C) H of mixing is negative
(D)  S of mixing is positive
29. A solid mixture of NaCl and K 2 Cr2 O7  s  is gently warmed with conc. H2SO 4 . Which of the
following observation(s) is/are correct?
(A) Deep red vapour is evolved
(B) Chlorine gas is formed as one of the major product
(C) These deep red vapours on dissolving in NaOH and followed by the mixing of AgNO3 in
solution, a brick red ppt. obtained
(D) Yellow solution obtained on mixing red vapours in NaOH, gives yellow ppt. with
Pb  CH3 COO 2
30. If we dilute a solution containing non-volatile solute, on adding water. Which of the following
observation is/are correct?
(A) Vapour pressure decreases
(B) Its osmotic pressure decreases
(C) Boiling point decreases
(D) Freezing point decreases
SECTION – C
31. A substance form face-centred cubic crystals its density is 1.95 gm/cc and edge length of the unit
cell is 625 pm. Calculate the molar mass of the substance (g/mole).
32. A solution containing 0.012 kg of Ba NO3 2 in 0.1 kg of water boils at 100.57oC. Calculate the
degree of ionization of the salt K b  water   0.52 K kg mol1 (Atomic mass of barium = 137.3)
33. Determine the magnitude of the EMF of the following cell at 298 K if pH = 6.0
Pt | Q,QH2 ,H || KCl 1 M | Hg2Cl2  s  | Hg 1 | Pt
(Answer must be given in mili volt)
Where Q is quinone
O
OH
Where QH2
OH
o
ECl |Hg Cl  0.280 V and EoQ ,QH ,H |Pt  0.6996 V
2 2 |Hg 2
34. Henry’s law constants as defined by the relation K H  PA / X A of oxygen and nitrogen dissolved in
water at 273 K are 2.53  109 Pa and 5.47  10 9 Pa, respectively. A sample of water at a
temperature above 273 K was equilibrated with air 18% O2 and 82% N2  at 1 atm. The dissolved
gas was separated from a sample of this water and then dried. Calculate the % of N 2 in this dried
sample 1 atm  1.01 105 Pa 
35. 0.5 mol of an ideal gas ‘A’ is present in a chamber and 0.5 mol an ideal gas ‘B’ is present in an
other identical chamber. Both the chambers are connected through a valve. Both the gases are at
1 atm pressure and same temperature. What will be the total change in entropy (in J/K) when
valve is opened between the chambers?
36. Pt  s  | H2  g1 atm | HCl  aq | AgCl  s  | Ag  s 

if the cell potential for HCl is 493 mv, What is the pH of the solution in which the electrodes are
immersed? Eocell  0.222 
SECTION – A
This section contains 06 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
19. Which of the following is/are square planar in shape?

PdCl4 
2
(A)
2
(B) Ni  CN 4 
2
(C) Pd  CN4 
NiCl4 
2
(D)
20. The ratio of average kinetic energy of triatomic gas and monoatomic gas at same temperature
is/are? [Neglect vibrational degree of freedom]
(A) 2
3
(B)
2
5
(C)
6
5
(D)
3
21. The mean free path of the molecule of a certain gas at 300 K is 3.5  10 5 m. The collision
diameter of the molecule is 0.25 nm which of the following is/are correct?
(A) Pressure  4.2  10 3 atm
(B) Number of molecules per unit volume of gas is 1.03  10 23 m 3
(C) Pr essure  4.26  10 2 Pa
(D) A and B only
22. Which of the following statement(s) for crystal having Frankel defect is/are correct?
(A) Frenkel defects are observed where the difference in sizes of cations and anions is large.
(B) Pure/Ideal alkali metal halides do not have Frenkel defect
(C) The density of crystals having Frenkel defect is lesser than that of a pure/ideal crystal.
(D) An ionic crystal may have Frenkel defect along with Schottky defect.
23. Which of the following statement(s) is/are correct?

(A) The co-ordination number of each type of ion in CsCl crystal is 8.
(B) Rhombohedral crystals have only one Bravais lattice.
(C) In cubic close packed structures effective number of octahedral voids and effective
number of spheres per unit cell is same.
(D) The hcp and ccp structure for a given element have same packing fraction.
24. Which of the following are correct?

(A) Adsorption is accompanied by decrease in enthalpy.
(B) Fog is aerosol
(C) The critical micellization concentration (CMC) is the concentration at which micellization
begins
(D) Purple of cassius is colloidal solution of gold
7 AITS-PT-III (Paper-2)-PCM-JEE(Advanced)/2021
SECTION – B
25. 1.1 gm CoCl3 .6NH3 was dissolved in 100 gm of water. The freezing point of solution was
– 0.383oC. How many moles of solute particles exist in solution for each mole of solute
introduced? [Given K f of H2 O  1.86 K mol1 kg , molar mass of Co = 58.9, Cl = 35.5, NH3 = 17]
(Assume complete ionization of solute and assume the solute to be non-volatile).
26. If the number of moles of electrons lost by one mole of ferrous thiosulphate in its reaction with
chlorine water are x, then the value of ‘x’ is……..
27. P4  OH 
x  y
If sum of the oxidation number of phosphorus in x and y is equal to  z  then z is
28. Which of the following halides are not colourless (white)

AgI, PbI2 , Hg2I2 , HgI2 ,AgCl, PbCl2 , Hg2Cl2 , AgBr
29. The unit cell of aluminium (Molar mass of Al = 27.0 gm/mol) is a cube with edge length 404 pm.
The density of aluminium is 2.70 gm/cm3. What are the effective number of atoms (or Rank of unit
cell) per unit cell? Nav  6.022  10 23 
30. A compound xy has a rock salt type structure with x : y = 1 : 1 the formula weight of xy is 6.023 A
amu and the closest x – y distance is A 1/ 3 nm. Find the density of lattice (in kg/m3)
Nav  6.023  10 23 
SECTION – C
31. Dry air was passed successively through a solution of 6 gm of a solute in 185 gm of water and
then through pure water. The loss in weight of solution was 2.6 gm and that of pure solvent was
0.4 gm. What is the molecular mass of the solute (g/mole)? (Assume solute to be non-volatile and
non-electrolyte)
32. A non-volatile and non-electrolyte solute is dissolved in 55.4 cc of benzene (density

0.889 gm cm 3 ) at room temperature, vapour pressure of this solution is 95.85 mm Hg while that
of pure benzene is 100 mm Hg. If the freezing temperature of this solution is 0.60 degree lower
than that of benzene, what is the value of molal freezing point depression constant of benzene.
(in K kg mol-1)
33. For a saturated solution of AgCl at 25oC, specific conductance is 3.32  10 6 ohm 1 cm 1 and
that of water used for preparing the solution was 1.5  10 6 ohm 1 cm 1 . If the solubility product of
AgCl is x  10 10 , then the value of x is…..
[Given  eqv  AgCl  138.3 ohm1 cm2 eqv 1 ]
34. EMF of the following cell is 0.58 V at 298 K

Pt | H2 1 atm | H PH  x  || KCl 1 N | Hg2Cl2  s  | Hg
Calculate pH of the anode compartment.
Given E oCl |Hg Cl |Hg  0.28 V
2 2
35. Calculate the free energy change at 298 K for the reaction
Br2     Cl2  g 
 2BrCl  g
For the reaction Ho  25.7kJ and the standard entropies of Br2    , Cl2  g and BrCl  g at the
298 K are 151.3, 221.0, 238.9 J mol-1 K-1 respectively. If Go of the reaction is – x Joule then
x
is…..
100
36. A compound AB crystallizes as CsCl lattice with unit cell edge length of 485 pm. If the radius of
B  is 235 Pm, then what will be the radius of A  (in pm)
AITS-PT-III-PCM-JEE(Main)/2021 8
SECTION – A
26. Which of the following is not a detergent?

(A) Cetyltrimethylammonium bromide
(B) Sodium dodecylbenzene sulphonate
(C) Sodium lauryl sulphate
(D) Sodium stearate
27. Identify the correct statement from the following:

(A) Vapour phase refining is carried out for nickel by Van Arkel method
(B) Pig iron can be moulded into a variety of shapes
(C) Wrought iron is impure iron with 4% C
(D) Blister copper has blistered appearance due to evolution of CO 2
28. Measuring zeta potential is useful in determining which property of colloidal solution?
(A) Stability of the colloidal particles
(B) Size of the colloidal particles
(C) Viscosity
(D) Solubility
29. Which of the following is the correct order of increasing field strength of ligands to form
coordination compounds?
(A) F  SCN  C2 O42  CN
(B) CN  C2O42  SCN  F
(C) SCN  F  C2 O42  CN
(D) SCN  F  CN  C2O42
30. The mixture which shows positive deviation from Raoult’s law is
(A) Acetone + Chloroform
(B) Chloroethane + Bromoethane
(C) Ethanol + Acetone
(D) Benzene + Toluene
31. The correct option for free expansion of an ideal gas under adiabatic condition is
(A) q  0, T  0,w  0 and Ssystem  0
(B) q  0, T  0,w  0 and Ssystem  0
(C) q  0, T  0,w  0 and Ssystem  0
(D) q  0, T  0,w  0 and Ssystem  0
32. The percentage composition by weight of an aqueous solution of a non-electrolyte solute (Molar

mass = 150) which boils at 373.52 K is: Given K b for H2O  0.52 K kg mol1 
(A) 20%
(B) 13%
(C) 7%
(D) 25%
9 AITS-PT-III-PCM-JEE(Main)/2021
33. Which of the following statements regarding sulphur is not correct?

(A) Both rhombic and monoclinic sulphur are soluble in CS2
(B) Both rhombic and monoclinic sulphur have S8 molecules
(C) The stable form at room temperature is rhombic sulphur
(D) Monoclinic sulphur transforms to rhombic form when heated above 369 K
34. Which of the following statement is not correct?

(A) Catalyst is not involved in the reaction
(B) NO acts as homogeneous catalyst in the oxidation of SO2 int o SO3
(C) Positive catalyst operates by providing alternate path for the reaction that involves a
lower energy of activation
(D) Catalyst does not affect G of the reaction
35. Find vapour pressure of 10 M C2H5 OH  aq  solution at 300 K. (Assume ideal solution)
Given
dsolution  1 g / mL
PCo2H5 OH  40 mm of Hg
PHo2O  20 mm of Hg
(A) 25 mm of Hg
(B) 30 mm of Hg
(C) 27.5 mm of Hg
(D) 32.5 mm of Hg
36. In the metallurgy of Cu, the material obtained from bottom of blast furnace after smelting, which is
further subjected for bessemerization, is:
(A) Slag
(B) Impure Cu
(C) Matte
(D) Cuprous oxide
37. 25 mL sample of ozonized oxygen at NTP was passed through a solution of KI. The liberated
iodine required 15 mL of 0.08 N Na2S2O3 solution for complete titration. Calculate the volume of
ozone at NTP in the given sample.
(A) 15.44 mL
(B) 13.44 mL
(C) 14.44 mL
(D) 5 mL
3
38. The total number of isomers for the complex Co NO2 6  will be
(A) 8
(B) 10
(C) 1
(D) 2
39. Calculate the standard voltage that can be obtained from ethane-oxygen fuel cell at 25o C
7
C2H6  g   O2  g  
 2CO2  g  3H2O    , Go  1229.41 kJ / mol
2
(A) + 0.91 V
(B) + 0.54 V
(C) + 0.72 V
(D) + 1.08 V
AITS-PT-III-PCM-JEE(Main)/2021 10
40. For the reaction

2O3  g   3O 2  g , H, S and G are respectively
(A) +ve, +ve, +ve
(B) –ve, +ve, –ve
(C) –ve, –ve, +ve
(D) +ve, –ve, –ve
41. A certain gas effuses out of two different vessels A and B. A has a circular orifice while B has a
square orifice of length equal to the radius of the orifice of vessel A. The ratio of rate of effusion of
the gas from vessel A to that from vessel B is (Assuming all other conditions to be same):
(A)  :1
(B) 1: 
(C) 1:1
(D) 3:2
 PV 
42. Compressibility factor  Z  is plotted against pressure
 nRT 
N2
H2
CH4
CO2
Ideal gas
Z
P
What is the correct order of liquefiability of the gases shown in the above graph?
(A) H2  N2  CH4  CO 2
(B) CO2  CH4  N2  H2
(C) H2  CH4  N2  CO 2
(D) CH4  H2  N2  CO2
43. An ideal mixture of liquids A and B with 2 moles of A and 2 moles of B has a total vapour
pressure of 1 atm at a certain temperature. Another mixture with 1 mole of A and 3 moles of B
has a vapour pressure greater than 1 atm. But if 4 moles of liquid C are added to the second
mixture, the vapour pressure comes down to 1 atm. Given vapour pressure of C, PCo  0.8 atm.
Calculate the ratio of vapour pressures of pure A and pure B.
(A) 2
1
(B)
2
7
(C)
3
3
(D)
7
11 AITS-PT-III-PCM-JEE(Main)/2021
44. Example of – vely charged colloid is

(A) As2S3
(B) Fe  OH3
(C) TiO2
(D) Basic dyestuff
45. Which of the following is incorrect?

(A) Fe3  K 4 Fe  CN6  
 Blue colour
(B) Fe2  K 3 Fe  CN6  
 Blue colour
(C) Fe2  K 4 Fe  CN6  
 Blue colour
(D) Cu2  K 4 Fe  CN6  
 Re d brown ppt.
SECTION – B
46. How many of the following are oxide ores?

Chalcopyrites, Bauxite, Limonite, Siderite, Pyrolusite, Rutile, Cassiterite, Calamine, Cuprite,
Chalcocite, Argentite, Cinnabar.
47. How many of the following species have at least one bond angle less than 100o?
H2O, H2 S, ClF3 , IF7 , XeF2 , SF6 ,  TeF5  , XeF4 , O3 , SO2 , SO3 .

SECTION – C
1
. The value of   CP,m / Cv,m  will be

48. A gas expands adiabatically reversibly such that T  V 2
49. The standard free energy change for the following reaction is – 120 kJ/mol. What is the standard
cell potential?
2H2 O2  aq.  2H2 O     O 2  g 
50. A 0.745% (w/V) KCl solution is ionized to the extent of 80%. The osmotic pressure at 27o C of
the solution will be (in atm): (Take R = 0.082 atm L K-1 mol-1), (Atomic mass of K and Cl = 39 and
35.5 respectively)

Class 12 Part Test

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Class 12 Part Test

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7 AITS-PT-I (Paper-1)-PCM-JEE (Advanced)/2021

20. For an elementry reaction

22. Which of the following is the correct statement?

23. The correct order second ionization potential of C, N, O and F is

(One or More than one correct type)

25. Choose the correct statement(s)

28. Which of the following statements are correct?

29. Identify the correct statement

30. Which are correct for radio activity?

36. For a substance P undergoing parallel reaction

K1  0.372min1 and K 2  0.321 min1

19. Select the correct statement with respect to Na2 O2

20. Which of the following disproportionate on heating with NaOH?

21. Which of the following are correct regarding s-Block elements

22. Which of the following are correct regarding Si compounds?

23. Which of the following statement are correct?

24. Which of the following are polar?

25. xU  SO 4 2  yKMnO 4  zH2O  H2SO4  K 2SO 4  MnSO 4  UO2 SO 4

28. For the following reaction

Reaction 2: 2NO2  g  

36. In the following reaction started only with A

26. Which of the following statements is not true about BeH2?

27. Choose the correct statement from following:

28. Choose the incorrect statement.

29. The most basic oxide among the following is

31. Choose the correct statement:

33. For a reaction:

38. The following equation are given:

40. For the following reaction:

41. Choose the correct option for following statements:

42. Choose incorrect statement:

43. Which of the following pair are isotones?

(C) 26 Fe58 and 27 Ni58

45. For the following equilibrium reaction:

48. For the following reaction:

19. In the following reaction

20. Which among the following compounds is most basic?

21. In the following reaction

The major product (P) is

23. In the given reaction

24. For the following reaction

(One or More than one correct type)

25. Which of the following compounds show geometrical isomerism?

(B) CH3  N  N  CH3

27. Which of the following statement(s) is/are correct about polymers?

31. The observed rotation of 2 gram of a compound in 10 ml of solution in polarimeter tube of 25 cm

32. The relative reactivity of 1o : 2o : 3o hydrogen to bromination is 1 : 82 : 1600. In the following

33. In the following reaction

34. In the following reaction

19. In the following reaction, the product (s) formed is/are

(C) CH3 – CH2 – OH

(D) H3C CH3

21. Which of the following compound (s) is/are optically inactive?

23. Which of the following compounds will be oxidized by HIO 4?

25. Total number of structural isomers of molecular formula C4H6 is

27. The total number of aromatic molecules/ions among the following is

28. In the following sequence of reactions

NH2 NH2 NH2

32. In the following reaction

35. In the following reaction

(C) CH3 (D) CH3

0 60 120 180 0 60 120 180

0 60 120 180 0 60 120 180

29. The major product of the following reaction is

33. For the reaction:

The highest value of [X] (aq), when X is

34. The major product in the following reaction is:

TBS = Si(CH3)2t – C4H9

(C) O OTBS (D) HO OTBS

35. The major product in the following reaction is:

(C) NO2 OH (D)

37. High blindness is caused by deficiency of

38. For the given reaction

(C) O H3C (D) O H

(A) (i), (iii)

19. The geometry of Ni  CO  4 and Ni PPh3 2 Cl2  are respectively: