Material Safety Data Sheet

Revision Number: 004.2 Issue date: 02/02/2012

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: BONDERITE M-CR 600RTU AERO IDH number: 594094
known as ALODINE 600 RTU
Product type: Coating
Region: United States
Company address: Contact information:
Henkel Corporation Telephone: 248.583.9300
32100 Stephenson Highway MEDICAL EMERGENCY Phone: Poison Control Center
Madison Heights, MI 48071 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Liquid HEALTH: *3
Color: Orange FLAMMABILITY: 0
Odor: Bland PHYSICAL HAZARD: 0
Personal Protection: See MSDS Section 8
DANGER–CORROSIVE!: CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
MAY CAUSE EYE, SKIN AND RESPIRATORY BURNS.
MAY CAUSE BLINDNESS.
MAY CAUSE ALLERGIC SKIN REACTION.
POSSIBLE CANCER HAZARD.

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects

Inhalation: Mists, vapors or liquid may cause severe irritation or burns. Prolonged or repeated breathing
may cause ulceration of nasal membranes.
Skin contact: Contact with broken skin may lead to formation of firmly marginated "chrome sores". Product
contains chromium, which may cause an allergic skin sensitization reaction. Massive
overexposures may lead to kidney failure and death.
Eye contact: This product is severely irritating to the eyes and may cause irreversible damage including
burns and blindness.
Ingestion: This product may produce corrosive damage to the gastrointestinal tract if it is swallowed.

Existing conditions aggravated by Eye, skin and respiratory disorders. Kidney disorders.
exposure:

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).

See Section 11 for additional toxicological information.

IDH number: 594094 Product name: BONDERITE M-CR 600RTU AERO known as ALODINE 600 RTU
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 3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous components CAS NUMBER %
Sodium borofluoride 13755-29-8 0.1 - 1
Sodium chromate 7775-11-3 0.1 - 1
Dipotassium hexafluorozirconate 16923-95-8 0.1 - 1
Sodium nitrate 7631-99-4 0.1 - 1
Chromic acid 7738-94-5 0.1 - 1

4. FIRST AID MEASURES

Inhalation: If mist or vapor of this product is inhaled, remove person immediately to fresh
air. Seek medical attention if symptoms develop or persist.

Skin contact: Remove contaminated clothing and footwear. For skin contact, flush with large
amounts of water. Seek immediate medical attention. If irritation persists,
repeat flushing and get medical attention. Discard any shoes or clothing items
that cannot be decontaminated.

Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15
minutes, and seek immediate medical attention.

Ingestion: Get immediate medical attention. Do not induce vomiting. Give one to two
glasses of water or milk. Never give anything by mouth to a victim who is
unconscious or is having convulsions.

5. FIRE FIGHTING MEASURES

Flash point: Not applicable

Autoignition temperature: Not applicable

Flammable/Explosive limits - lower: Not applicable

Flammable/Explosive limits - upper: Not applicable

Extinguishing media: Use media appropriate for surrounding material.

Special firefighting procedures: Wear full protective clothing. Wear self-contained breathing apparatus.

Unusual fire or explosion hazards: This product is an aqueous mixture which will not burn. If evaporated to
dryness, solid residue is an oxidizing agent and may cause spontaneous
ignition of combustible materials.

Hazardous combustion products: Oxides of nitrogen.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear appropriate
protective equipment and clothing during clean-up. Do not allow product to
enter sewer or waterways.

Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for
disposal. Dispose of according to Federal, State and local governmental
regulations.

IDH number: 594094 Product name: BONDERITE M-CR 600RTU AERO known as ALODINE 600 RTU
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 7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing mists or aerosols
of this product. Wash thoroughly after handling. Provide adequate ventilation.
For industrial use only. Do not take internally.

Storage: Keep container tightly closed and in a cool, well-ventilated place away from
incompatible materials.

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER

2 mg/m3 TWA
Inhalable fraction. 2.5 mg/m3 TWA
6 mg/m3 STEL (as F)
Sodium borofluoride None None
Inhalable fraction. 2.5 mg/m3 TWA
2.5 mg/m3 TWA Dust.
(as F)
0.005 mg/m3 TWA
0.0025 mg/m3
0.05 mg/m3 TWA
Sodium chromate OSHA ACT None None
(as Cr)
(SKIN)
0.1 mg/m3 Ceiling
10 mg/m3 STEL 2.5 mg/m3 TWA
(as Zr) Dust.
2.5 mg/m3 TWA 5 mg/m3 TWA (as
Dipotassium hexafluorozirconate None None
(as F) Zr)
5 mg/m3 TWA (as 2.5 mg/m3 TWA
Zr) (as F)
Sodium nitrate None None None None
0.1 mg/m3 Ceiling
0.005 mg/m3 TWA
0.05 mg/m3 TWA (SKIN)
Chromic acid None None
(as Cr) 0.0025 mg/m3
OSHA ACT
29 CFR 1910.1026

Engineering controls: Provide local and general exhaust ventilation to effectively remove and
prevent buildup of any vapors or mists generated from the handling of this
product.

Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or
vapors, appropriate NIOSH/MSHA respiratory protection must be provided.

Eye/face protection: Wear chemical goggles; face shield (if splashing is possible).

Skin protection: Wear impervious gloves for prolonged contact. Gloves should be tested to
determine suitability for prolonged contact. Use of impervious apron and boots
are recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Color: Orange
Odor: Bland
Odor threshold: Not available.
pH: <2
Vapor pressure: Not determined
Boiling point/range: > 100 °C (> 212°F)
Melting point/ range: Not determined

IDH number: 594094 Product name: BONDERITE M-CR 600RTU AERO known as ALODINE 600 RTU
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 Specific gravity: 1.01 - 1.03
Vapor density: Not determined
Flash point: Not applicable
Flammable/Explosive limits - lower: Not applicable
Flammable/Explosive limits - upper: Not applicable
Autoignition temperature: Not applicable
Evaporation rate: Not determined
Solubility in water: Complete
Partition coefficient (n-octanol/water): Not determined
VOC content: Not applicable

10. STABILITY AND REACTIVITY

Stability: Stable at normal conditions.

Hazardous reactions: Will not occur.

Hazardous decomposition products: Decomposes with heat to produce oxides of nitrogen.

Incompatible materials: Avoid contact with organic materials, oils, greases, and any oxidizable
materials.

Conditions to avoid: None identified.

11. TOXICOLOGICAL INFORMATION

OSHA Carcinogen
Hazardous components NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Sodium borofluoride No No No
Known To Be Human
Sodium chromate Group 1 Yes
Carcinogen.
Dipotassium hexafluorozirconate No No No
Sodium nitrate No No No
Known To Be Human
Chromic acid Group 1 Yes
Carcinogen.

Hazardous components Health Effects/Target Organs

Cardiac, Central nervous system, Developmental, Gastrointestinal, Irritant,
Sodium borofluoride
Kidney, Metabolic, Reproductive
Irritant, Respiratory, Central nervous system, Allergen, Liver, Kidney,
Sodium chromate
Developmental, Reproductive, Corrosive, Carcinogen, Mutagen, Blood
Allergen, Blood, Cardiac, Central nervous system, Corrosive, Gastrointestinal
Dipotassium hexafluorozirconate tract, Irritant, Kidney, Lung, Metabolic, Muscle, Teeth, Less weight gain and
food intake.
Sodium nitrate Blood, Central nervous system, Corrosive, Gastrointestinal, Irritant
Allergen, Blood, Carcinogen, Central nervous system, Corrosive,
Chromic acid Developmental, Eyes, Gastrointestinal, Irritant, Kidney, Liver, Mutagen,
Reproductive, Respiratory

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

IDH number: 594094 Product name: BONDERITE M-CR 600RTU AERO known as ALODINE 600 RTU
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 13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: This product contains chromium which is a hazardous waste (D007).

14. TRANSPORT INFORMATION

The shipping classification in this section are for bulk packaging only. Shipping classification may be different for non-bulk packaging
as exceptions may apply. Refer to shipping documents for package specific transportation classification.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Environmentally hazardous substances, liquid, n.o.s.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III
DOT Reportable quantity: Sodium bichromate, Chromic acid

International Air Transportation (ICAO/IATA)

Proper shipping name: Environmentally hazardous substance, liquid, n.o.s.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III

Water Transportation (IMO/IMDG)

Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III
Additional information: IMDG-Code: Segregation group 1- Acids

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12(b) Export Notification: Sodium chromate (CAS# 7775-11-3).Chromic acid (CAS# 7738-94-5).

CERCLA/SARA Section 302 EHS: None above reporting de minimus

CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Sodium chromate (CAS# 7775-11-3). Chromic acid (CAS# 7738-94-5).
CERCLA Reportable quantity: Chromic acid (CAS# 7738-94-5) 10 lbs. (4.54 kg)
Sodium chromate (CAS# 7775-11-3) 10 lbs. (4.54 kg)

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.
WHMIS hazard class: D.2.A, D.2.B, E

16. OTHER INFORMATION

This material safety data sheet contains changes from the previous version in sections: New information added in
Section(s): 1, 5, and 13.

IDH number: 594094 Product name: BONDERITE M-CR 600RTU AERO known as ALODINE 600 RTU
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 Prepared by: John DiCerbo, Sr. Regulatory Affairs Specialist

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 594094 Product name: BONDERITE M-CR 600RTU AERO known as ALODINE 600 RTU
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