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Problem Set For LE2

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Problem Set For LE2

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mhsandoy
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Problem Set for LE2 Chem 16 plsdanan

Directions: Place your answers in a bluebook. Show ALL solutions and BOX your final answers. To be submitted
on 29 Oct 2024.
Multiple Choice
1. Which will have the highest concentration of potassium ion:
a) 0.20 M KCl c) 0.080 M K3PO4
b) 0.15 M K2CrO4 d) 0.27 M KOH

2. Which of the following statements is/are FALSE?


I. The Earth is an open system
II. A closed system has no interaction with its surroundings
III. The coffee-cup calorimeter is an isobaric system
IV. An isolated system is an adiabatic system
a) II and III c) I and IV
b) I and II d) II only

3. Which of the following is a characteristic of all exothermic reactions?


a) ∆H is negative.
b) An explosion occurs.
c) A decomposition or substitution reaction occurs.
d) ∆S is negative.

4. Which of the following changes would always result in a negative ∆E?


a) The system gives off heat and does work.
b) The system absorbs heat and does work.
c) The system gives off heat, and work is done on it.
d) The system absorbs heat, and work is done on it.

5. A 15.3-g metallic solid with an initial temperature of 585.31 K was placed in 75.0 g of water with an initial
temperature of 316.52 K. After reaching thermal equilibrium, the final temperature of the solid and water is
318.20 K. What is the probable identity of the solid? (cwater = 4.184 J/g-K)
a) Cadmium (c = 0.231 J/g-K) c) Lead (c = 0.129 J/g-K)
b) Copper (c = 0.385 J/g-K) d) Steel (c = 0.466 J/g-K)

6. The combustion of a 24-g sample was carried out in a bomb calorimeter, and resulted in a temperature
increase of 3 oC. If the heat capacity of the calorimeter was 4.0 kJ/oC, what is the heat of combustion of the
sample in J/g?
a) 5 J/g c) 0.5 J/g
b) 500 J/g d) 50 J/g

7. The temperature of a 250 mL sample of water changed from 28.6 oC to 36.4 oC. Which of the following
statements best describes the scenario? Density of water = 1.00 g/mL, specific heat capacity = 4.184 J/g-oC
a) The water absorbed 8.16 kJ of heat.
b) The water released 32.6 kJ of heat.
c) The water performed 8.46 kJ of work.
d) The enthalpy change is 4.08 kJ/mol.
Problem Set for LE2 Chem 16 plsdanan
Problem Solving
1. Ron wanted to know the complete chemical formula of a hydrated sodium carbonate. He used 104.5 g of the
hydrated compound with a purity of 94.0%. He heated the sample to remove all the water and volatile
impurities which resulted to a 36.4-g pure sodium carbonate. (7 pts overall)
a. From the sample, calculate the total mass of pure hydrated sodium carbonate? (1 pt)
b. How many moles of water was in the sample? (2 pts)
c. How many moles of sodium carbonate was in the sample? (2 pts)
d. Give the chemical formula of the hydrated sodium carbonate. (2 pts)

2. Given the following thermodynamic data, calculate the ∆H, ∆G, and ∆S of the reaction:
4𝐶𝑟(𝑠) + 3 𝑂2 (𝑔) → 2𝐶𝑟2 𝑂3 (𝑠)

3. Arrange the following in increasing entropy: (1 pt each)


a. CO2(g), H2O(l), SiO2(s)
b. I2(g), Br2(g), Cl2(g)

4. Predict whether entropy increases or decreases or whether the outcome is uncertain in each of the following
reactions. (1 pt each)
a. Zn(s) + Ag2O(s) → ZnO(s) + 2Ag(s)
b. 2Cl–(aq) + 2H2O(l) → 2OH-(aq) + H2(g) + Cl2(g)

5. Determine at what temperature the following reactions are spontaneous (at low temp, at high temp, at all
temp): (1.5 pts each)
a. N2(g) + 3H2(g) → 2NH3(g) ∆H° = -92.22 kJ
b. 2C(graphite) + 2H2(g) → C2H4(g) ∆H° = 52.26 kJ

6. Determine ∆G at 298.15K for the reaction. Is it spontaneous? ∆H = -1141.1 kJ, ∆S = -146.5 J/K (2 pts for ∆G, 1
pt for spontaneity)
2NO(g) + O2(g) → 2NO2(g)

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