CHEMISTRY ATOMIC STRUCTURE ASSIGNMENT-1 SR CO PLUS

Single answer type questions :

01. The aufbau principle implies that a new electron will enter an orbital for
which
a) m has a lower value b) l has a lower value
c) ( n + l ) value is maximum d) ( n + l ) value is minimum
02. Maximum number of total nodes is present in
a) 5s b) 5p c) 5d
d) all have same number of nodes
03. Which electronic level would allow the hydrogen atom to absorb a photon but not to emit
a photon?
(A) 3 (B) 2 (C) 1 (D) 4
04. According to Bohr’s atomic theory, which of the following is/are correct:
Z2
(I) Kinetic energy of electron α
n2
(II) The product of velocity of electron and principle quantum number ‘n’ α Z2
Z2
(III) Frequency of revolution of electron in an orbit α 3
n
Z3
(IV) Coulombic force of attraction on the electron α 4
n
(A) I, III, IV (B) I, IV (C) II (D) I
05. The incorrect statement regarding cathode rays is
(A) They travel in straight line.
(B) They depend on the nature of the gas.
(C) They are deflected by magnetic as well as electric fields.
(D) They produce mechanical effects.
06. If radius of second stationary orbit (in Bohr's atom) is R. Then radius of third orbit will
be
(A) R/3 (B) 9R (C) R/9 (D) 2.25R
07. The energy of an electron in the first Bohr orbit of H atom is - 13.6 eV . The possible
energy value of the excited state for electrons in Bohr orbits of hydrogen is:
(A) -3.4 eV (B) -4.2 eV (C) - 6.8 eV (D) + 6.8 eV
08. The radius of which of the following orbit is same as that of the first Bohr’s orbit of
hydrogen atom?
(A) He+ (n = 2) (B) Li2+ (n = 2) (C) Li2+ (n = 3) (D) Be3+ (n = 2)
09. Particle nature of electron is proved by
(A) Radioactivity (B) Cathode ray experiment
(C) Rutherford’s -scattering experiment (D) Interference of electron beams
10. What is the ninth ionization potential of fluorine atom?
(A) 13.6 eV (B) 9  13.6 eV (C) 81  13.6 eV (D) 100  13.6 Ev
11. The maximum number of spectral lines given by two Li ions in the 6th excited state is
2+

(A) 15 (B) 21 (C) 9 (D) 6

12. In which of the following transitions will the wave length be minimum?
a) n = 6 to n = 4 b) n = 4 to n = 2
c) n = 3 to n = 1 d) n = 2 to n = 1
13. Arrange the elements with the following electronic configurations in the increasing order
of electron affinity (i) 1s2 2s2 2p3 (ii) 1s2 2s2 2p4 (iii) 1s2 2s2 2p3 (iv) 1s2 2s2 2p6 3s23p4
a) i < ii < iii < iv b) iv < iii < ii < i c) iii < ii < iv < i d) ii < iii < i < iv
14. Ratio of frequency of revolution of electron in the 2nd excited state of He+ and 2nd state of
hydrogen is:
32 27
a) b) c) 1/54 d) 27/2
27 32
O
15. A photon with a wavelength of 4000 A is used to break the iodine molecule, then the %
of energy converted to the K.E. of iodine atoms if bond dissociation energy of I 2
molecule is 246.5 kJ/mol, is
a) 8% b) 12% c) 17% d) 25%
16. When lithium is irradiated with light, one finds a stopping potential of 1.83V for
o o
 = 3000 A and 0.80V for  = 4000 A . With the known charge on the electron, the
work function of lithium is
a) 4.6eV b) 10.2 eV c) 2.3 eV d) 1.2 eV
17. Maximum number of total nodes is present in
a) 5s b) 5p
c) 5d d) all have same number of nodes
18. The mass to charge ratio (m/e) for a unipositive cation is 1.5 10−8 kg / c . What is the
mass of this cation ?
a) 2.4  10−19 g b) 2.4  10−27 g c) 2.4  10−24 g d) 2.4 10−21 g
x
19. An electron in an atom jumps in a such a way that its K.E changes from x to . The
4
change in P.E will be
3 −3 3 −3
a) x b) x c) + x d) x
2 8 4 4
20. ( )
Find the value of wave number  in terms of Rydberg’s constant, when transition of
electron takes place between 2 levels of He+ ion whose sum is ‘4’ and difference is ‘2’
8R H 32R H 3R H 5R H
a) b) c) d)
9 9 4 36
nd 3+
21. No of revolutions made by the electron in one sec in 2 orbit of Be is
a) 1.311016 b) 2.13 1016 c) 1.23 1015 d) 2.68 1014
22. An electron is revolving in the 2nd orbit of He+ ion. To this, if 12.1 eV of energy
supplied, then the orbit to which it will be excited will be
a) 6 b) 8 c) 4 d) 2
23. Angular momentum of an orbit of a H like species in which the electron revolving is
4.2197 10−34 Js . The number of waves made by the electron in that orbit is
a) 6 b) 4 c) 8 d) 2
24. Consider that azimuthal quantum number (l) is having (n + 1) values instead of 0 to
 (n – 1) value for any value of principle quantum number n. If all the laws of electronic
configuration are applicable then what will be the spin only magnetic moment of Fe2+
ion.
(A) 2.82 BM (B) 4.89 BM
(C) 3.87 BM (D) 1.73 BM
25. If 1 and  2 denote the de-Broglie wavelength of two particles with same masses but
charges in the ratio of 1 : 2 after they are accelerated from rest through the same potential
difference, then
(A) 1 =  2 (B) 1   2
(C) 1   2 (D) none of these
26. Suppose a particle has four quantum numbers such that the permitted values are those as
given below :
n : 1, 2, 3….
: ( n − 1) , ( n − 3) , ( n − 5 ) ..... but no negative number
 1  1
J :  +  or  −  if the latter is not negative
 2  2
m : – J in integral steps to +J
Thus how many particles could be fitted into the n = 2 shell ?
(A) 4 (B) 6
(C) 8 (D) 12
27. Consider the following plots for 2s-orbital :

x y

r r
(I) (II)

r
(III)
x, y and z are respectively,
(A) , 2 and 4r 2R 2 (B) 2 ,  and 4r 22
(C) 4r 22 ,2 and  (D) 2 , 4r 22 and 

28. If the lowest energy X-rays have  = 4.0  10−8 m, estimating the minimum difference in
energy between two Bohr orbit, where an electronic transition would correspond to the
 emission of an X-ray, at what minimum Z (atomic number) would a transition from the
second energy level to the first result in the emission of an X-ray?
(A) Z = 2 (B) Z = 3
(C) Z = 4 (D) Z = 5
29. If a0 be the radius of first Bohr's orbit of H-atom, the de-Broglie's wavelength of an
electron revolving in the third Bohr's orbit will be
(A) 6a0 (B) 4a0
(C) 2a0 (D) a0
30. Choose the incorrect statement regarding spin quantum no.
(A)the spin of an electron is an intrinsic angular momentum which cannot spontaneously
changed or eliminated.
(B)spin is not a quantum mechanical phenomenon
(C)two type of spins can be distinguished by spin magnetic quantum number.
(D)spin quantum number describes the electron not the orbital.
31. When an excited state of H-atom emits a photon of wavelength  and returns to the
ground state, the principal quantum number of excited state is given by

(A)
( R − 1) (B) R ( R − 1)
R

R
(C) (D) R ( R + 1)
( R − 1)
32. If a certain metal was irradiated by using two different light radiations of frequency x and
2x the kinetic energy of the ejected electrons are y and 3y respectively. The threshold
frequency of the metal will be
(A) x/3 (B) x/2
(C) 3x/2 (D) 2x/3
−
33. How many times does the e go round the first Bohr’s orbit of H in one second ?
A) 9.67 1015 B) 8.06 1015 C) 6.57 1015 D) 4.34 1015
34. Two particles A and B are in motion. If the wavelength associated with particle A is
8 10−7 m , calculate the wavelength associated with particle B if its momentum is 1 4 of

that of A.
A) 32 10−7 m B) 2 10−7 m C) 4 10−7 m D) 0.5 10−8 m
35. How many photons of light having wavelength 420nm are required to raise the
temperature of 5g of H 2O by 1o ; specific heat of H 2O is 4.18JK −1 g −1 (All the light energy
is converted into heat energy) ?
A) 9.92 1019 B) 4.42 1019 C) 2.211019 D) 1.15 1019
36. The dissociation energy of H2 is 430.53KJ / mole . If H2 is exposed to radiant energy of
wavelength 253.7nm , what % of radiant energy will be converted into K.E.?
A) 8.68 B) 9.14 C) 4.36 D) 2.14
  n2 
37. If  = C2  2 
for Balmer series, what is the value of C2 ?
n − 2 
2

2 4
A) B) 2RH C) 4RH D)
RH RH
38. Alveoli are tiny sacs in the lungs whole average diameter is 5 10−10 m ; an oxygen
molecule is trapped in a sac the uncertainty in the velocity of oxygen molecule within a
sac is:-
A) 2.0m / sec B) 3.0m / sec C) 1.0m / sec D) 4.0m / sec
39. How many elements would be lie in the third period of periodic table if the spin quantum
no has the values −1 2 , 0 , +1 2 ?
A) 12 B) 8 C) 27 D) 24

40. In an oil drop experiment, the following charges ( in arbitrary units) were found on a
series of oil droplets: 2.30 10-15 ,6.90 10-15 ,1.38 10-14 ,5.75 10-15 ,3.45 10-15 ,1.96 10-14
.
The experimental value suggests the magnitude of the charge on the electron is ( in the
same arbitrary unit)
A) 2.30 10-15 B) 1.38 10-14 C) 6.90 10-15 D) 1.15 10-15

41.
For which orbital angular probability distribution is maximum at an angle to the axial direction.
A) B) C) dxy D)

42. If wavelength is equal to the distance travelled by the electron in one second ,then
(  = de-Brogli wave length )
A) B) C) D)

43. In sp3d 2 hybridization, the orbitals involved are

A) B)
and and
C) D)
and and
44.
Probability of finding an electron of s orbital doesn’t depend upon.
A) Distance from nucleus B) Energy of s orbital
C) Principal quantum number D) Azimuthal quantum number
45.
An electron is accelerated from rest and it has wavelength of by how much amount potential
should be dropped so that wavelength associated with electron becomes .
 A) 25 V B) 50 V C) 75 V D) 12.5 V
46.
Let be the frequency of the series limit of Lyman series, be the frequency of first line of Lyman
series and be the frequency of series limit of Balmer series then :
A) B) C) D)
none of these

47. For which of the following orbital, the radial, and the angular nodes as
well as number of nodal planes have all the same value ?
(a) 3px (b) 4py (c) 3s (d) 4d xy

48. A proton and an  -particle are accelerated through the same potential difference. The
ratio of the de-Broglie wave length of proton and  -particle is
1
(A) 2 (B)
2
(C) 2 2 (D) 2
49. 3h 3 h
The orbit and orbital angular momentum of an electron are and . respectively. The
2 2 
number of radial and angular nodes for the orbital in which the electron is present are
respectively
A) 0, 2 B) 2, 0 C) 1, 2 D) 2, 2

50. The spin angular momentum for the s electron in H atom is

A)
3h B)
h
C)
h
D)
3h
4 2 4 2

51. A hydrogen sample is prepared in a particular excited state A. Photons of energy 2.55
eV/atom get absorbed into the sample to take some of the electrons to a further excited
state B. Determine the number of photons when an electron in the higher excited state B
returns to the ground state.
(A) 15 (B) 10
(C) 6 (D) 3

52. Radius of 3rd orbit of Li2+ ion is x cm then de Broglie wavelength of electrons in the first
orbit is (in cm)
2x
(A) 6x (B)
9
2x 8x
(C) (D)
3 3
53. In an oil drop experiment, the following charges ( in arbitrary units) were found on a
series of oil droplets: 2.30 10-15 ,6.90 10-15 ,1.38 10-14 ,5.75 10-15 ,3.45 10-15 ,1.96 10-14
.
The experimental value suggests the magnitude of the charge on the electron is ( in the
same arbitrary unit)
A) 2.30 10-15 B) 1.38 10-14 C) 6.90 10-15 D)
1.15 10 -15

54.

55.

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KEY
Single correct answer type :
 01 D 02 D 03 C 04 A 05 B 06 D
07 A 08 D 09 B 10 C 11 C 12 C
13 C 14 A 15 C 16 C 17 D 18 C
19 A 20 B 21 A 22 A 23 B 24 A
25 C 26 B 27 B 28 A 29 A 30 B
31 C 32 B 33 C 34 A 35 B
36 A 37 D 38 A 39 C 40 D
41 C 42 A or D 43 A 44 D 45 A
46 A 47 A 48 C 49 A 50 A
51 b 52 b 53 D 54 A 55 A

HINTS

Single correct answer type :

01. D
02. Total number of nodes = n–1
03. C
04. A
05. B
06. D
07. A
08. D
09. B
10. C
11. C
12. C
13. C
14. A
12400
15. Energy of one photon =
4000
= 3.1 eV
Energy supplied by one mole photon in KJ/mole =
3.11.6 10−19 1023 10−3 = 297 kJ mol −1
297 − 246.5
 % of energy converted to K .E = = 17%
297
hC
16. = W0 + KE1
1
C
= W0 + KE2
2
  W0 = 2.3 eV
17. Total number of nodes = n–1
m
18. Mass =    e = 1.5 10−8 kg / c 1.6 10 −19 c
e
= 2.4 10−27 kg = 2.4 10−24 g
x −3x
19. Change in KE = − x =
4 4
 −3x  3x
Change in PE = −2  =
 4  2
n1 + n 2 = 4
20.
n1 − n 2 = 2
2n1 = 6
n1 = 3
n2 = 1
1 1  32R H
 =  −  R H ( 2) =
2

1 9  9
2
2
21. f = 65.5 1014  3
n
f = 13110 .1.311016
14

22. Conceptual
h
23. n  = 4.2197 10−34
2
On solving n = 4
24. Since l is having (n + 1) values  Electronic configuration of Fe will be
Fe = 1s2 1p6, 2s2 2p6 3s2 2d8
 Fe2+ ion = 1s2 1p6 2s2 2p6 2d8
 spin only = n(n + 2) = 2(4) = 8 BM
h
25. = KE = eV
2mKE
1 KE1
same mass =
2 KE1
26. n= 2
= 1
J= 1½ 1
2
m= 1 1 1 1 1 1
−1 , − , + , +1 − ,+
2 2 2 2 2 2
Total - 6
27. Plot I : x = R 2
 Plot II : y = R
Plot III : z = 4r 2 R 2
hc ( 6.63 10 )( 3 10 )
−34 8

28. E= = −18
= 5 10−18 J
 4.0 10
E H = ( 2.178 10−18 J ) = 1.63 18−18 J
3
4
E = E H .z 2
E 5.0 10−18
or z 2 = = = 3.06
E n 1.63 10−18
z=2
nh
29. mvrn = ….(i)
2
h
deBroglie equation = P = = mv …(ii)

placing the value of mv from (ii) and (i) for 3rd orbit
h 3h
r3 =
 2
 2
 =
hr3 3h
2r3
=
3
or r3 = n 2 a 0 = 9a 0
2.9a 0
so = = 6a 0
3
30. spin is purely a quantum mechanical phenomenon.
1 1 1 
31. = R − 2 
  1 n2 
R
n 22 =
R − 1

R
n2 =
R − 1
K.E1 v1 − v0
32. =
K.E 2 v 2 − v0

y x − v0
=
3y 2x − v 0

2x − v 0 = 3 ( x − v 0 )
 x
v0 =
2
33. C
v1
Hints: Number of rounds by e − in first orbit =
2 r1
by substituting all the values 6.57 1015
34. A
hA hB 1
Hints: A = B = pB = pA
pA pB 4
8  10−7 1
=  B = 32  10−7 m
B 4
35. B
Hints: E = 5  4.18 = 20.9 J
nhc x  6.626  10−34  3  108
E=  20.9 =
 420  10−9
x  4.42 10 photons
19

36. A
430.53  103
Hints: EH − H ( B.D.E ) = J = 7.15  10−19 J
6.023  1023
6.626  10−34  3  108
E photon = −9
= 7.83  10−19 J
253.7  10
Energy converted into K.E = Energy left after dissociation of bond
= ( 7.83 − 7.15) 10−19 J
= 0.68 10−19 J
0.68  10−19
% of energy converted into K .E   100  8.68%
7.83  10−19
37. D
1  n 2 − 22  1
1  22 
= = 1 − 2 
 C2  n 2  C2
Hints:
 n2 
22  1 1
=  2 − 2
C2  2 n2 
22
RH =  C2 = 4 / RH
C2
38. A
Hints: Uncertainty in position = diameter = 5 10−10 m
h
x.V 
4 m
6.626  10−34
V  = 2.0m / sec
32  10−3 −10
4  3.14   5  10
6.023  1023
39. C
 Hints: n = 3, l = 0, m = 0  −1 ,0, +1 3
2 2
l = 1, m = −1,0, +1  3  3  9
l = 2, m = −2, −1,0, +1, +2  5  3 =15  27

40.
Ans: D
1.15 10-15 , which is the largest number which divides all the given experimental values
of the charge.
The smallest charge noted is 2.30 10-15 , but this charge doesn’t seem as unit charge,
doesn’t divide others into even number of times.
Actually, it represents the charges of 2 electrons.
41. Conceptual
42. Conceptual
43. dx 2 − y 2 and dz 2 are along the axis
44. Azimutal gives shape of orbital.
45.
and
Hence potential should be dropped by 25 V.
46. Conceptual
47. SOL: (A) Radial nodes = n – l – 1
For 3p it is = 1
Angular nodes = nodal planes = l
For 3p it is = 1
h
48. =
2qVm
h
 =
2  2  V  m
h
 =
2 2 V  4
h
p =
2  1 V  m p
h
p =
2  1 V  1
P 16
=
 2
P
=2 2

49.
Orbit angular momentum,

Orbital angular momentum,

Hence electron is in 3d-orbital. For 3d-orbital, radial nodes =

Angular nodes =
50.
, one unpaired electron,

Spin angular momentum

1 1
51. 2.55 = 13.6  1   2 − 2 
 nA nB 
nA = 2, nB = 4
 no of photons emitted
43
= = 6.
2
n2
r
Z
52.
r1 n12 1 1
= = =
r3 n22 32 9
x
r1 =  r = x 
9  3
 2r = n
x
 2 = 1 
9
2x
=
9
53.
Ans: D
1.15 10-15 , which is the largest number which divides all the given experimental values
of the charge.
The smallest charge noted is 2.30 10-15 , but this charge doesn’t seem as unit charge,
doesn’t divide others into even number of times.
Actually, it represents the charges of 2 electrons.
54.

55.

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