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LOCTITE 8282 Safety Data Sheet

The document is a Safety Data Sheet for LOCTITE ABLESTIK ICP 8282, an acrylate adhesive produced by Henkel Corporation, detailing its hazards, handling, and emergency measures. It highlights potential health risks such as skin and eye irritation, and provides guidelines for first aid, firefighting, and disposal. The product contains hazardous components including silver and various acrylates, and is classified under OSHA and GHS standards.

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0% found this document useful (0 votes)
2 views5 pages

LOCTITE 8282 Safety Data Sheet

The document is a Safety Data Sheet for LOCTITE ABLESTIK ICP 8282, an acrylate adhesive produced by Henkel Corporation, detailing its hazards, handling, and emergency measures. It highlights potential health risks such as skin and eye irritation, and provides guidelines for first aid, firefighting, and disposal. The product contains hazardous components including silver and various acrylates, and is classified under OSHA and GHS standards.

Uploaded by

ugoyo.simon
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
Download as pdf or txt
Download as pdf or txt
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Safety Data Sheet

Revision Number: 004.0 Issue date: 04/28/2021

1. PRODUCT AND COMPANY IDENTIFICATION


Product name: LOCTITE ABLESTIK ICP 8282 IDH number: 2374516
Product type/use: Acrylate adhesive
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.

HAZARD CLASS HAZARD CATEGORY


SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1

PICTOGRAM(S)

Precautionary Statements

Prevention: Avoid breathing vapors, mist, or spray. Wash affected area thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Wear protective
gloves, eye protection, and face protection.
Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or
rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off
contaminated clothing.
Storage: Not prescribed
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Hazardous Component(s) CAS Number Percentage*
Silver 7440-22-4 30 - 60
Isobornyl acrylate 5888-33-5 10 - 30
hexamethylene diacrylate 13048-33-4 10 - 30
Acrylate ester 7328-17-8 1-5

IDH number: 2374516 Product name: LOCTITE ABLESTIK ICP 8282


Page 1 of 5
Reaction products of 2-
hydroxyethylmethacrylate and 1187441-10-6 1-5
diphosphorus pentaoxide

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES


Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove
contaminated clothing and footwear. Get medical attention. Wash clothing
before reuse. Thoroughly clean shoes before reuse.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Get medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel.


Never give anything by mouth to an unconscious person. Get medical
attention.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES


Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear. In case of fire, keep containers cool with water spray.

Unusual fire or explosion hazards: Closed containers may rupture (due to build up of pressure) when exposed to
extreme heat.

Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Oxides of Metals in Section 3. Hydrogen
cyanide. Isocyanates. Amines. Toxic and irritating vapors.

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and
unprotected personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Evacuate and ventilate spill area; dike spill to prevent entry into water system;
wear full protective equipment during clean-up. Refer to Section 8 "Exposure
Controls / Personal Protection" prior to clean up. Soak up with inert absorbent
material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in
a closed container until ready for disposal.

7. HANDLING AND STORAGE


Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and
clothing. Do not breathe vapor and mist. Wash thoroughly after handling.
Keep container closed.

Storage: For safe storage, store between -22 °C (-7.6 °F) and -18 °C (0.4 °F)
Keep container tightly closed and in a cool, well-ventilated place away from
incompatible materials. Keep away from heat, spark and flame. Protect from
direct sunlight. Maintain head space in storage containers to support oxygen
requirements of the inhibitor(s).

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

IDH number: 2374516 Product name: LOCTITE ABLESTIK ICP 8282


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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper
exposure controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER


0.1 mg/m3 TWA Dust 0.01 mg/m3 PEL (as
Silver None None
and fume. Ag)
Isobornyl acrylate None None None None
0.11 ppm (1 mg/m3)
hexamethylene diacrylate None None None
TWA (Skin sensitizer)
Acrylate ester None None None None
Reaction products of 2-
hydroxyethylmethacrylate and None None None None
diphosphorus pentaoxide

Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below
exposure limits.

Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed
established exposure limits exists.

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists. Safety
showers and eye wash stations should be available.

Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state: Liquid
Color: Silver
Odor: Acrylic
Odor threshold: Not available.
pH: Not available.
Vapor pressure: Not available.
Boiling point/range: Not available.
Melting point/ range: Not available.
Specific gravity: 1.9
Vapor density: Not available.
Flash point: > 100 °C (> 212°F)
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Flammability: Not applicable
Evaporation rate: Not available.
Solubility in water: Not available.
Partition coefficient (n-octanol/water): Not available.
VOC content: Not available.
Viscosity: 30 mPa.s
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY


Stability: Stable under normal conditions of storage and use.

Hazardous reactions: May occur with excessive aging, excessive heat, polymerization catalyst, inhibitor depletion,
direct sunlight and under oxygen-free atmospheres.

Hazardous decomposition Oxides of carbon. Oxides of nitrogen. Oxides of Metals in Section 3. Hydrogen cyanide.
products: Isocyanates. Amines. Toxic fumes. Irritating vapors.

Incompatible materials: Strong oxidizing agents. Strong reducing agents. Strong acids and strong bases. Free radical
initiators. Inert gases. Oxygen scavengers. Peroxides. Iron. Rust. Copper. Copper alloys.

Reactivity: Not available.

Conditions to avoid: Keep away from heat, ignition sources and incompatible materials. Protect from direct sunlight.
Loss of dissolved air. Loss of polymerization inhibitor.

IDH number: 2374516 Product name: LOCTITE ABLESTIK ICP 8282


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11. TOXICOLOGICAL INFORMATION
Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects/Symptoms

Inhalation: May cause respiratory tract irritation.


Skin contact: Causes skin irritation. May cause allergic skin reaction. Argyria (a non-toxic, cosmetic blue-gray
discoloration of the skin and mucous membranes that is irreversible).
Eye contact: Causes serious eye irritation. Redness. Tearing.
Ingestion: May cause gastrointestinal tract irritation if swallowed.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Oral LD50 (Rat) = > 5,000 mg/kg
Dermal LD50 (Rat) = > 2,000 mg/kg
Silver Allergen, Eyes, Irritant, Respiratory, Skin
Inhalation LC50 (Rat, 4 h) = 750 µg/m3
Inhalation LC50 (Rat, 4 h) = > 5.16 mg/l
Isobornyl acrylate None Irritant, Allergen
Oral LD50 (Rat) = 5 g/kg
hexamethylene diacrylate Irritant, Allergen
Dermal LD50 (Rabbit) = 3,600 mg/kg
Acrylate ester None Irritant, Allergen
Reaction products of 2-
hydroxyethylmethacrylate and None Irritant, Allergen
diphosphorus pentaoxide

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Silver No No No
Isobornyl acrylate No No No
hexamethylene diacrylate No No No
Acrylate ester No No No
Reaction products of 2-
hydroxyethylmethacrylate and No No No
diphosphorus pentaoxide

12. ECOLOGICAL INFORMATION


Ecological information: Not available.

13. DISPOSAL CONSIDERATIONS


Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

14. TRANSPORT INFORMATION


The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)


Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III
DOT Hazardous Substance(s): Silver

International Air Transportation (ICAO/IATA)


Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. (Silver, Isobornyl acrylate)
Hazard class or division: 9
Identification number: UN 3082
Packing group: III

IDH number: 2374516 Product name: LOCTITE ABLESTIK ICP 8282


Page 4 of 5
Water Transportation (IMO/IMDG)
Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Silver,
Isobornyl acrylate)
Hazard class or division: 9
Identification number: UN 3082
Packing group: III
Marine pollutant: Silver, Isobornyl acrylate

15. REGULATORY INFORMATION


United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed as active or are exempt from listing on the Toxic Substances
Control Act (TSCA) inventory.

TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.


CERCLA/SARA Section 311/312: Immediate Health
CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Silver (CAS# 7440-22-4). Acrylate ester (CAS# 7328-17-8).
CERCLA Reportable quantity: Silver (CAS# 7440-22-4) 1,000 lbs. (454 kg)

California Proposition 65: This product contains a chemical known to the State of California to cause birth defects or
other reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION


This safety data sheet contains changes from the previous version in sections: 3,7,9,13

Prepared by: Product Safety and Regulatory Affairs

Issue date: 04/28/2021

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

This Safety Data Sheet has been generated based on OSHA Hazard Communication Standard (29 CFR 1910.1200) and provides
information in accordance with U.S. federal law only. No warranty or representation of any kind is given with respect to the
substantive or export laws of any other jurisdiction or country. Please confirm that the information provided herein conforms to the
substantive export or other law of any other jurisdiction prior to export. Please contact Henkel Product Safety and Regulatory
Affairs for additional assistance.

IDH number: 2374516 Product name: LOCTITE ABLESTIK ICP 8282


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