PHYSICAL CHEMISTRY

11 th
JEE
PARAKRAM
QUESTION BANK

ATOMIC STRUCTURE

CG Tower-2 A-51(A), Road 3, Behind City Mall, Indraprastha

Industrial Area, Kota, Rajasthan 324005, Mo. +917017243492
 1

VIDYAPEETH
Atomic Structure
SINGLE CORRECT QUESTIONS
1. A 5g orbital has 8. The increasing order for the values of e/m
(A) Zero angular node and zero radial node (charge/mass) is :
(B) Zero radial node and two angular nodes (A) e, p, n,  (B) n, p, e, 
(C) 4 radial nodes and 4 angular nodes (C) e, , e (D) n, , p, e
(D) Zero radial node and 4 angular nodes
9. An electron in an atom jumps in such a way that its
2. The threshold wavelength (0) of sodium metal is
x
6500Å. If UV light of wavelength 360Å is used, kinetic energy changes from x to . The change
what will be kinetic energy of the photoelectron in
4
ergs? in potential energy will be :
(A) 55.175 × 10–12 (B) 3.056 × 10–12 3 3
(A) + x (B) − x
(C) 52.119 × 10–12 (D) 48.66 × 10–10 2 8
3 3
(C) + x (D) − x
3. An electron beam can undergo diffraction by 4 4
crystals. Through what potential should a beam of
electrons be accelerated so that its wavelength 10. What atomic number of an element “X” would have
becomes equal to 1.54 Å? to become so that the 4th orbit around X would fit
(A) 54.3 volt (B) 63.3 volt inside the 1st Bohr orbit of Hydrogen?
(C) 66.2 volt (D) None of these (A) 3 (B) 4
(C) 16 (D) 25
4. Radiation corresponding to the transition n = 4 to
n = 2 in hydrogen atoms falls on a certain metal 11. In any subshell, the maximum number of electrons
(work function = 2.5 eV). The maximum kinetic having same value of spin quantum number is :
energy of the photo-electrons will be :
(A) 0.55 eV (B) 2.55 eV
(A) ( + 1) (B)  + 2
(C) 4.45 eV (D) None of these (C) 2 + 1 (D) 4 + 2

5. Calculate the number of photons emitted by a 100

12. Maximum number of total nodes is present in :
W yellow lamp in 1.0 s. Take the wavelength of
yellow light as 560 nm and assume 100 percent (A) 5s
efficiency. (B) 5p
(A) 6.8 × 1020 (B) 4 × 1012 (C) 5d
(C) 4 × 1020 (D) 2.8 × 1020 (D) All have same number of nodes
13. The possible set of quantum no. for the unpaired
6. If the value of En = – 78.4 kcal/mole, the order of electron of chlorine is :
the orbit in hydrogen atom is : n  m
(A) 2 (B) 3
(A) 2 1 0
(C) 1 (D) 4
(B) 2 1 1
(C) 3 1 1
7. In what region of the electromagnetic spectrum
(D) 3 0 0
would you look for the spectral line resulting from
the electronic transition from the tenth to the fifth
electronic level in the hydrogen atoms? 14. The angular velocity of an electron occupying the
(RH = 1.10 × 105 cm–1) second Bohr orbit of He+ ion is (in sec–):
(A) Microwave (B) Infrared (A) 2.067 × 1016 (B) 3.067 × 1016
(C) Visible (D) Ultraviolet (C) 1.067 × 1018 (D) 2.067 × 1017
 2

15. An excited state of H-atom emits a photon of 21. Calculate the minimum and maximum number of
wavelength  and returns in the ground state, the electrons which may have magnetic quantum
principal quantum number of excited state is given number, m = +1 and spin quantum number,
by : s = –1/2 in chromium (Cr) :
R (A) 0, 1 (B) 1, 2
(A) R(R −1) (B)
(R − 1) (C) 4, 6 (D) 2, 3
(R − 1)
(C) R(R −1) (D) 22. The species which has its fifth ionisation potential
R
equal to 340 V is
(A) B+ (B) C+
16. Light of wavelength  strikes a metal surface with
intensity X and the metal emits Y electrons per (C) B (D) C
second of average energy Z. What will happen to Y
and Z if X is halved ? 23. S1 : Bohr model is applicable for Be2+ ion.
(A) Y will be halved S2 : Total energy coming out of any light source is
(B) Y will double integral multiple of energy of one photon.
(C) Y will be remain same S3 : Number of waves present in unit length is
(D) Z will be halved wave number.
S4 : e/m ratio in cathode ray experiment is
17. Neutron scattering experiments have shown that the independent of the nature of the gas.
radius of the nucleus of an atom is directly
(A) F F T T (B) T T F F
proportional to the cube root of the number of
(C) F T T T (D) T F F F
nucleons in the nucleus. From 37 Li to 189
76 Os , the
radius is : 24. If uncertainties in the measurement of position and
(A) Halved (B) The same momentum are equal for electron, calculate
(C) Doubled (D) Tripled uncertainty in the measurement of velocity? (Given
h
18. The nucleus of an atom is located at x = y = z = 0. that : = 0.726 × 10–17)
4
If the probability of finding an electron in orbital in
(A) 7.98 × 1012 ms–1
a tiny volume around x = a, y = 0, z = 0 is 1 × 10–5,
what is the probability of finding the electron in the (B) 7.98 × 1010 ms–1
same size volume around x = 0, y = a, z = 0? (C) 8.42 × 1012 ms–1
(A) 1 × 10–5 (B) 1 ×10–5 × a (D) 6 × 106 ms–1
(C) –1 × 10–5 × a (D) zero
25. Which of the d orbitals not lies in the xy-plane.
19. The energy of I, II and III energy levels of a certain (A) dx2 − y2 (B) dxy
atom are E, 4E/3 and 2E respectively. A photon of
(C) dxz (D) dxy and dx2 − y2
wavelength  is emitted during a transition from III
to I. What will be the wavelength of emission for
transition II to I ? 26. Which of the following elements is represented by
(A) /2 (B)  the electronic configuration?
(C) 2 (D) 3
20. A compound of vanadium has a magnetic moment
of 1.73 BM. What will be the electronic
configurations:
(A) 1s2 2s2 2p6 3s2 3p6 3d1
(B) 1s2 2s2 2p6 3s2 3p6 3d2
(C) 1s2 2s2 2p6 3s2 3p6 3d3 (A) Nitrogen (B) Fluorine
(D) 1s2 2s2 2p6 3s2 3p6 3d4 (C) Oxygen (D) Neon
 3

27. Among the following series of transition metal 30. The Schrodinger wave equation for hydrogen atom is
ions, the one where all metal ions have same 3d 3/2
1 Z
electronic configuration is: (radial) =   [( –1)(s2 –8 + 12)]e–/2
16 4  a 0 
(A) Ti2+, V3+, Cr4+, Mn5+
(B) Ti3+, V2+, Cr3+, Mn3+ where a0 and Z are the constant in which answer can
(C) Ti+, V4+, Cr6+, Mn7+ 2Zr
be expressed and  = minimum and
(D) Ti4+, V3+, Cr2+, Mn3+ a0
maximum position of radial nodes from nucleus are
28. Which of the following has the maximum number ……. Respectively.
of unpaired electrons? a 3a a0 a0
(A) 0 , 0 (B) ,
(A) Mn (B) Ti Z Z 2Z Z
(C) V (D) Al a 3a a 4a
(C) 0 , 0 (D) 0 , 0
2Z Z 2Z Z
29. Wave function of an orbital is plotted against the
distance from nucleus. The graphical representation
is of:

(A) 1s (B) 2s
(C) 3s (D) 2p

MORE THAN ONE CORRECT QUESTIONS

33. Identify the correct statement(s) :
31. Which is/are true about an electron?
(A) Wavelength associated with a 1 kg ball
–28
(A) Rest mass of electron is 9.1 × 10 g moving with the velocity 100 m/s can’t be
calculated.
(B) Mass of electron increases with the increase in
(B) Wave nature of the running train is difficult to
velocity observe because wavelength is extremely
(C) Molar mass of electron is 5.48 × 10–4 g/mole small.
(C) Wavelength associated with the electron can
(D) e/m of electron is 1.7 × 108 coulomb/g
h
be calculated using the formulae E =

(D) If an electron is accelerated through 20 V
32. Many elements have non-integral atomic masses
potential difference if it has already 5eV
because kinetic energy then wavelength of the electron
is approximately Å.
(A) they have isotopes

(B) their isotopes have non-integral masses 34. d Z 2 orbital has:

(C) the constituents, neutrons, protons and (A) Two lobes along z-axis
electrons combine to give fractional masses (B) Ring along yz-plane
(C) Ring along xy-plane
(D) none of these
(D) Ring along x axis
 4

35. Consider the following six electronic 39. Which of the following sets of quantum number
configurations (remaining inner orbitals are is(are) incorrect:
completely filled) and mark the correct option. 1
(A) n = 5, l = 4, m = 0, s = +
2
1
(I) (B) n = 3, l = 3, m = +3, s = +
2
1
(II) (C) n = 6, l = 0, m = +1, s = –
2
(D) n = 4, l = 2, m = +2, s = 0
(III)
40. Which of the following species has (have) five
unpaired electrons?
(IV) (A) Cr (B) Mn
2+
(C) Mn (D) Fe2+
(V)
41. Select the correct statement(s):
(A) All electromagnetic radiation travel with
(VI) speed of light in vacuum.
(A) Stability order : II > I > IV > III (B) Energy of photon of UV light is lower than
(B) Order of spin multiplicity : IV > III = I > II that of yellow light.
(C) V does not violate all the three rules of (C) He+ and H have similar spectrum.
electronic configuration (D) The total energy of an electron in unelectronic
species is greater than zero
(D) If VI represents A and A+ when kept near a
magnet, acts as diamagnetic substance.
42. Choose the incorrect statement(s) :
(A) Increasing order of wavelength is
36. Choose the correct statement(s) : Micro waves > Radio waves > IR waves >
(A) The shape of an atomic orbital depends upon visible waves > UV waves
azimuthal quantum number (B) The order of Bohr radius is (rn: where n is orbit
(B) The orientation of an atomic orbital depends number for a given atom)
upon the magnetic quantum number r1 < r 2 < r3 < r4
(C) The energy of an electron in an atomic orbital (C) The order of total energy is (En : where n is
of multi-electron atom depends upon principal orbit number for a given atom)
quantum number only E1 > E2 > E3 > E4
(D) The number of degenerate atomic orbitals of (D) The order of velocity of electron in H, He+,
one type depends upon the value of azimuthal Li+, Be3+ species in second Bohr orbit is
quantum number Be3+ > Li+2 > He+ > H

43. Among the following representation of excited

37. For radial probability curves, which of the
states of atoms which is/are possible?
following is/are correct ?
(A) 1s1 2s1
(A) The number of maxima in 2s orbital are two
(B) [Ne] 3s2 3p3 4s1
(B) The number of spherical or radial nodes is
(C) 1s2 2s2 2p4 3s2
equal to n –  – 1 (D) [Ne] 3s2 3p6 4s3 3d2
(C) The number of angular nodes are ‘’
44. The angular momentum of electron can have the
(D) 3dz2 has 3 angular nodes
value
h h
38. For an electron, magnetic quantum number m = +2. (A) 2.5 (B)
2 0.5
The electron may be present in
h h
(A) 5s-sub-shell (B) 5d-sub-shell (C) (D) 0.5
(C) 5p-sub-shell (D) 5f-sub-shell
 
 5

45. Select the incorrect statement (s): 48. Which is /are correct statement?

(A) Radial distribution function indicates that (A) Energy of photon is related with wave number
there is a higher probability of finding the 3s E = hcv
electron close to the nucleus than for the 3p (B) Mathematical expression of Heisenberg
and 3d orbitals
h
uncertainty principle is x.p 
(B) Energy of 3s orbital is less than for the 3p and 4
3d orbitals for H– atom.
1 1
(C) v = 109677  2
− 2  is called as Rydberg
(C) At the node, the value of the radial function
 1 n2 
n
changes from positive to negative
formula
(D) The radial function depends upon the quantum
h
numbers m and I (D) de-Broglie relation is  =
p

49. The photoelectric effect supports quantum nature of

th
46. In H-atom sample electrons are de-excited 5 state
light because –
to ground state. Which is/are correct statement
(A) There is a minimum frequency of light below
(A) One line observed in Brackett series.
which no photoelectrons are emitted
(B) 4 line in UV –region and 3 line in visible
(B) The maximum kinetic energy of
region observed.
photoelectrons depends only on the frequency
(C) Total ten lines observed in spectrum.
of light are not
(D) No line observed in P-fund series.
(C) Even when metal surface is faintly illuminated

47. If in Bothr’s model, for unelectronic atom the photoelectrons leave the surface

following symbols are used immediately

rn,z → Radius of nth orbit with atomic number Z (D) Electric charge of photoelectrons is quantised

Un,z → Potential energy of e− ; Kn,z → Kinetic

50. dz2 - orbital has:
−
energy of e ;
(A) A lobe along z-axis and a ring along xy-plane
Vn,z → Velocity of e− ; Tn,z → Time period of
(B) A lobe along z-axis and a lobe along xy-plane
revolution

Then select the correct statement (s) (C) It has two angular nodes .

(A) U 1,2 :K1,1 = –8 :1 (B) r2,1 : r1,2 = 8 : 1 (D) It has two radial nodes

(C) V1,3 : V3,1 = 1 : 8 (D) T1, 2 : T2, 2 = 9 : 1

 6

MATCH THE COLUMN

51. Match each Column-I with an appropriate pair of 54. Match the column
characteristics from Column -II and select the Column-I Column-II
correct answer using the code given below the
lists. Analysis of Characteristics
Column-I Column-II Atoms
(A) Lyman series (P) maximum (A) 2s (p) n = 4, l = 2, m = 0
number of (B) 2pz (q) n = 4, l = 2, m = –2
spectral line or +2
observed = 6 (C) 4d 2 2 (r) n = 2, l = 1, m = 0
(B) Balmer series (Q) maximum x −y

number of (D) 4dz2 (s) n = 2, l = 0, m = 0

spectral line
observed = 2 (t) Number is less
than the number of
(C) In a sample of H- (R) 2nd line has wave fully filled orbitals
atom for 5 upto 2 8R in 18Ar atom
transition number
9
55. Match the column
Column-I Column-II
(D) In a single (S) 2nd line has
isolated H-atom wave number Analysis of Characteristics
for 3 upto 1 3R Atoms
transition. 16 (A) Total number (p) Number is even
52. of filled
Column–I Column–II
(A) 4 (P) Number of node in 3s orbitals with
(B) 5 (Q) Number of sub-shell in third m = 0 in 30Zn
energy level atom
(C) 3 (R) Number of unpaired
electrons in Fe3+ (B) Total number (q) Number is odd
(D) 2 (S) Number of electrons with ml of electrons
1
= 0 and ms= + in an atom with  = 0
2
of phosphorus in 12Mg atom
(C) Maximum (r) Number is same as
53.
number of the number of
Column–I Column–II electrons with unpaired electrons
(A) Electron (P) Radius of orbit in
+m=0 in 25Mn2+ ion
moving in 2nd which electron is
orbit in moving is 0.529 Å
+ in 17Cl atom
He ion
(B) Electron (Q) Total energy of (D) Total number (s) Number is greater
moving in 3nd electron is (–) of electrons than 5
orbit in H- 13.6× 9 eV
atom With
(C) Electron (R) Velocity of anticlockwise
moving in 1st electron is
spin in 10Ne
orbit in Li +2
2.188 106
ion m/sec atom
3
(D) Electron (S) De-broglie (t) Number is less than
nd
moving in 2 wavelength of the number of fully
orbit is Be+3 electron is 150 o filled orbitals
A
ion 13.6
in 18Ar atom
 7

PARAGRAPH TYPE QUESTIONS

56. Werner Heisenberg considered the limits of how 58. The only electron in the hydrogen atom resides
precisely we can measure the properties of an under ordinary conditions on the first orbit. When
electron or other microscopic particle. He energy is supplied, the electron moves to higher
determined that there is a fundamental limit to energy orbit depending on the amount of energy
how closely we can measure both position and absorbed. When this electron returns to any of the
momentum. The more accurately we measure the lower orbits, it emits energy. Lyman series is
momentum of a particle, the less accurately we formed when the electron returns to the lowest
can determine its position. The converse is also orbit while Balmer series is formed when the
true. This is summed up in what we now call the electron returns to second orbit. Similarly,
Heisenberg uncertainty principle. paschen, Brackett and P-fund series are formed
h when electron returns to the third, fourth and fifth
The equation is x.(mv) 
4 orbits from higher energy orbits respectively.
The uncertainty in the position or in the Maximum number of lines produced when an
momentum of a macroscopic object like a electron jumps from nth level to ground level is
baseball is too small to observe. However, the n ( n − 1)
equal to . For example, in the case of
mass of microscopic object such as an electron is 2
small enough for the uncertainty to be relatively n = 4, number of lines produced is 6. (4 →3,
large and significant.
4 →2,4 →1,3 →2,3 →1,2 →1). When an electron
returns from n2 to n1 state, the number of lines in
(i) If the uncertainty in velocity and position is same,
the spectrum will be equal to
then the uncertainty in momentum will be:
hm h
( n2 − n1 )( n2 − n1 +1)
(A) (B) m 2
4 4
If the electron comes back from energy level
h 1 h
(C) (D) having energy E2 to energy level having energy
4 m m 4
E1, then the difference may be expressed in terms
of energy of photon as:
(ii) What would be the minimum uncertainty in de-
hc
Broglie wavelength of a moving electron E2 – E1 E,  =
accelerated by potential difference of 6 volt and E
7 Since h and c are constants, E corresponds to
whose uncertainty in position is nm ? definite energy; thus each transition from one
22
(A) 6.25 Å (B) 6 Å energy level to another will produce a light of
(C) 0.625 Å (D) 0.1325 Å definite wavelength. This is actually observed as
a line in the spectrum of hydrogen atom.
Wave number of line given by the formula
57. 1g–ion of He+ ion is excited. Spectral analysis
showed the existence of 50% ions in 3rd level, 1 1
v = R 2 − 2 
25% in 2nd level and remaining 25% in ground  n1 n 2 
state. ionization energy of He+ is 54.4 eV; where R is a Rydberg’s constant (R = 1.1×107 m–1)
(NA = 6 × 1023) (i) The energy photon emitted corresponding to
transition n = 3 to n = 1 is [ h = 6 × 10–34J-sec.]
(i) No. of He+ ions present in 3rd level (A) 1.76 × 10–18J (B) 1.98 × 10–18J
(A) NA/2 (B) NA/2 (C) 1.76 × 10–17J (D) None of these
NA
(C) (D) N A 4
3 (ii) In a collection of H-atom electrons make
(ii) Calculate total energy evolved when all the ions transition from 5th excited state to 2nd excited
return to ground state. state then maximum number of different types of
(A) 3.31 × 105J (B) 3.31 × 106 J photons observed are
(C) 1.1 × 106 J (D) None of these (A) 3 (B) 4
(C) 6 (D) 15
 8

59. If hydrogen atoms (in the ground state) are passed 60. Quantum numbers are assigned to get complete
through an homogeneous magnetic field, the information of electrons regarding their energy,
beam is split into two parts. This interaction with angular momentum, spectral lines etc. Four
the magnetic field shows that the atom must have quantum numbers are known i.e. principal
magnetic moment. However, the moment cannot quantum numbers which tell the distance of
be due to the orbital angular momentum since l = electron from nucleus, energy of electron in a
0. Hence one must assume existence of intrinsic particular shell and its angular momentum.
angular momentum which as the experiment Azimuthal quantum number tells about the
shows, has only two permitted orientations. subshells in a given shell and of course shape of
Spin of the electron produce angular momentum orbital. Magnetic quantum number deals with
h 1 study of orientations or degeneracy of a subshell.
equal to S = s(s + 1) where S = + .
2 2 Spin quantum number which defines the spin of
n n 1 1
Total spin of an atom = + or − electron designated as + or – represented
2 2 2 2
Where n is the number of unpaired electrons. by and respectively. Electron are filled in
The substance which contain species with orbitals following Aufbau rule. Pauli's exclusion
unpaired electrons in their orbitals behave as principal and Hund's rule of maximum
paramagnetic substances. The paramagnetism is multiplicity. On the basis of this answer the
expressed in terms of magnetic moment. The following questions.
magnetic moment of an atom

eh n  n  eh n (i) Two unpaired electrons present in carbon atom

s s(s − 1) = +1 s=
2mc 2  2  2mc 2 are different with respect to their
 s = n(n +1)B.M. (A) Principle quantum number
(B) Azimuthul quantum number
n = number of unpaired electrons
(C) Magnetic quantum number
eh
1. B.M. (Bohr magneton) =
4mc (D) Spin quantum number

If magnetic moment is zero the substances is

diamagnetic. (ii) Number of electron having the quantum numbers
1
n = 4,  = 0, s = – in Zn+2 ion is/are :
2
(i) Which of the following ion has lowest magnetic
moment? (A) 1 (B) 0
(A) Fe2+ (B) Mn2+ (C) 2 (D) 5
(C) Cr3+ (D) V3+
(iii) Spin angular momentum for unpaired electron in
(ii) If an ion of 25Mn has a magnetic moment of 3.873 sodium (Atomic No. = 11) is:
B.M. Then oxidation state of Mn in ion is: 3
(A) (B) 0.866 h/2
(A) +2 (B) +3 2
(C) +4 (D) +5 3 h
(C) – (D) None of these
2 2π
 9

INTEGER TYPE QUESTIONS

61. When a certain metal was irradiated with light 66. What is the maximum possible number of electrons
frequency 1.6 × 1016 Hz, the photo electrons in an atom with (n +  = 7)?
emitted had twice the kinetic energy as did
photoelectrons emitted with frequency 1 × 1016 Hz
when the same metal was irradiated with light, then 67. Find the value of x + 2y + z
threshold frequency x × 1015 Hz. Find "x". x = no. of radial nodes in 3px
y = no. of angular nodes in 6s
62. The uncertainty in position and velocity of the
z = the maximum no. of electrons in 24Cr with
particle are 0.1 nm and 5.27×10–27 ms–1
1
respectively. Then the mass of the particle in grams n = 3 and s = + and orbital angular momentum 6
2
is : (h = 6.625 × 10–34Js). Represent answer by
dividing with 10.
68. The wave motion of an electron in a Bohr’s orbit of
Hydrogen atom is as shown in diagram. The orbit
63. In all how many nodal planes are there in the atomic
number is:
orbitals for the principal quantum number n = 3

n+ +m
64. What is the value of   for all possible
 2 
orbitals with number of radial nodes = 1 and where h
69. Orbital angular momentum of an electron is 3
n  3. 
then the number of orientations of this orbital in
65. In a sample of hydrogen atom containing 1 mole H space are:
atoms, electrons in 30% of H-atoms are in 1st
excited state and remaining are in 2nd excited state 70. In one experiment, a proton having initial kinetic
and ground state. If the total energy emitted when energy of 1 eV is accelerated through a potential
all electrons return to ground state is 642.24 kJ, find difference of 3V. In another experiment, an
% of electrons in 2nd excited state. -particle having initial kinetic energy 20 eV is
Energy level in H atom retarded by a potential difference of 2V. Calculate
= E1 = – 13.6 eV, E2 = – 3.4 eV, E3 = – 1.5 eV and the ratio of de-Broglie wavelengths of proton and
(1 eV/species = 96 kJ/mole) 𝛼-particle.
 10

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. D C B D D A B B A C C D C A B
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. A D A D A D B C A C D A A C C
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. A,B,C,D A,B,C B,D A A,B,C A,B,D A,B,C B,D B,C,D B,C A,C A,C A,B,C B,C,D B,D
Que. 46 47 48 49 50 51 52
Ans. A,B,C,D A,B,C,D A,B,C,D A A,C A-R; B-S; C-P; D-Q A-R; B-S; C-Q; D-P
Que. 53 54 55
Ans. A-S; B-R; C-Q; D-P A-S; B-R; C-Q; D-Q A–q,s,t; B–p,s,t; C–p,s; D–q,r,t
Que. 56 57 58 59 60 61 62 63 64
Ans. (i)-A (ii)-C (i)-A (ii)-B (i)-A (ii)-C (i)-D (ii)-C (i)-C (ii)-B (iii)-B 4 10 11 7
Que. 65 66 67 68 69 70
Ans. 30 32 6 3 7 4

HINTS & SOLUTION

1. (D) 4. (D)
Total number of nodes = n – 1 = 5 – 1 = 4 13.6 13.6
En = – 2
eV; E2 = 2
Angular node =  = 4. n 2
Zero radial node and 4 angular nodes. 13.6
E4 = – eV/atom
42
2. (C) E = E4 – E2 = 2.55 eV
The threshold frequency (0) corresponding to the Absorbed energy = work function of metal + K.E.
wavelength 6500 Å is c/0. 2.55 = 2.5 + K.E. ; K.E. = 0.05 eV
Therefore, the threshold energy = h0 = hc/0.
5. (D)
Substituting for h, c and 0 we get, threshold
The number of photon is
energy = 3.056 × 10–12 ergs.
E PΔt λPΔt
The energy of the incident photons is given by E N= = =
hν h(c / λ) hc
= hc/0, since incident wavelength  = 360 Å.
Substitution of the data gives
Therefore, incident energy = 55.175 × 10–12 ergs.
(5.60×10-7 m) × (100Js-1 ) × (1.0s)
The kinetic energy of the photoelectrons will be N=
the difference of incident energy and threshold (6.626×10-34 s) × (3×108 ms-1 )
energy, = 2.8 × 1020
 KE = h – h0 = (55.175 × 10–12) –
(3.056 × 10–12) ergs. = 52.119 × 10–12 ergs 6. (A)
En = – 78.4 kcal/mole = – 78.4 × 4.2
3. (B) = – 329.28 kJ/mole
h 329.28
For an electron mu2 = eV and  = =– eV = – 3.4 eV.
mu 96.5
1 h2 (energy of II orbit of H atom).
Thus, m × 2 2 = eV
2 m λ
7. (B)
1 h2
or V = Wave numbers are the reciprocals of wavelengths
2 mλ 2 e
1
1 (6.62 10−34 )2 and are given by the expression v = .
= 
2  9.108 10 (1.54 10−10 )2 1.602 10−19
−31
1 1
1
_ = 1.1 × 105  – 
= 63.3 volt.   1
n n2
 11

8. (B) 16. (A)

Charge/mass for n = 0, for  = 2/4, for p = 1/1, Number of emitted electron  Intensity of
1 incident light.
for e– = ss
1/1837
9. (A) 17. (D)
2x 3 1/3
Change in P.E. = − + (2 x)  x ROs  189 
= =3
4 2 RLi  7 

10. (C) 18. (A)

n2 It would be same in x and y axis for dX2–y2.
r1 = 0.529 Å; r4(X) = r1 × ;
Z
0.529  (4)2 19. (D)
r4( x)  ; Z = 16 For II to I transition,
Z
4E hc E hc
E = −E= ; =
11. (C) 3  II →I 3  II →I
Maximum number of electrons with same spin is For  to  transition,
hc hc
equal to maximum number of orbitals, i.e., E = 2E − E = orE =
(2 +1).  
hc hc
 =  II − I = 3
3    II − I
12. (D)
Total nodes = n – 1. 20. (A)
Number of unpaired elecron are given by
13. (C) Magnetic moment = [n(n + 2)] where n is
Cl17 : [Ne] 3s2 3p5. number of unpaired electrons or
Unpaired electron is in 3p orbital. 1.73 = [n(n + 2)] or 1.73 × 1.73 = n2 + 2n
 n = 3,  = 1, m = 1, 0, – 1.  n = 1.
Now vanadium atom must have one unpaired
electron and thus its configuration is :
14. (A) 4+ 2 2 6 2 6 1
23V : 1s 2s 2p 3s 3p 3d
Velocity of an electron in He+ ion in an orbit
2Ze2 21. (D)
= .....(i)
nh
Radius of He+ ion in an orbit
n2h2
= ....(ii)
42me2 Z
By equations (i) and (ii), Out of 6 electrons in 2p and 3p must have an
u 8 Z me
3 2 4 electron with m = + 1 and s = ½ but in 3d-subshell
Angular velocity () = = ....(iii) an orbital having m = + 1 may have spin quantum
r n3h3
no. – 1/2 or + 1/2. Therefore, minimum and
8  (22 / 7)3  (2)2  (9.108  10−28 )  (4.803  10−10 )4 maximum possible values are 2 and 3
=
(2)3  (6.626  10−26 )3 respectively.
= 2.067 × 1016 sec–1. 22. (B)
I.P. = 340 V so, I.E. = 340 eV
15. (B) Z2
= 13.6 2
1  1 1  (1)
= R  2 − 2  ; n1 = 1, n2 = ?
  n1 n2  so, Z2 = 25 so, Z=5
Therefore, (B) is correct option.
1 1 1  R
= R  − 2   n22 =
  1 n2  R − 1 23. (C)
S1 : Be2+ ion has 2 electron so Bohr model is not
R
 n2 = applicable.
R − 1 S2, S3 and S4 are correct statement.
 12

24. (A) 31. (A, B, C, D)

By Heisenburg’s uncertainty principle me = 9.1 × 10–31 kg = 9.1 × 10–28 g.
h m0
x.p > m= (m0: rest mass ; m: dynamic mass).
4
v2
1– 2
Given x = p, c

Hence x = p =
h
= 0.726 × 10–17  v2 
4 As v  1 – 2  ,   m
 c 
h
Also, x. > thus Molar mass of e = 9.1 × 10–28 × 6.023 × 1023
4m
= 5.48 × 10–4 g/mole.
h
 = /x in a limiting case e 1.6 10−19
4m For electron, = = 1.7 × 108 c/g.
−28
m 9.1  10
h h h 1 0.72  10−17
= / = × =
4m 4 4 m 9.1 10−31
32. (A, B, C)
= 7.98 × 1012 ms–1.
Non-integral atomic masses of elements are due
25. (C)
to existence of isotopes of that element which
The dx2 − y2 , dxy orbital lies in the xy plane.
have different masses.
33. (B, D)
26. (D) (A)  can be calculated as :
2 2 6
[Ne] = 1s 2s 2p h 6.626  10−34
= = = 6.626 × 10–36 m.
mv 1 100
27. (A) (very small).
(B) de-Broglie wavelength associated with
28. (A) macroscopic particles is extremely small and
Mn(25) [Ar]3d5, 4s2 n=5 so, difficult to observe.
Ti(22) [Ar]3d2, 4s2 n=2 (C) de-Broglie wavelength associated with
3 2
V(23) [Ar]3d , 4s n=3 h
2 1 electron can be calculated by using  =
Al(13) [Ne]3s , 3p n=1 mv
.
29. (C) (D) KEf = 5 + 20 = 25 eV.
Radial node (n –  – 1) = 2 150 150
 = = = 6 Å.
KE f 25
 = 0, n = 3

34. (A)
30. (C)
d z 2 orbital has two lobes along Z axis and a ring
Probability of finding e– is zero implies that
2 = 0 or  = 0 along XY plane.
 ( – 1) = 0  =1
a0 35. (A, B, C)
or r1 = or (2 – 8 + 12) = 0 A : excitation possible only in d-orbitals
2z
and ( – 6)( – 2) = 0 B : Spin multiplicity = 2 |S| + 1; |S|
= total spin
3a 0
 = 6, r = C : V violated Hund`s rule
z
a 3a D : A+ is paramagnetic due to unpaired e–
and  = 2, r = 0 r2 = 0
z z  A, B, C are correct.
 13

36. (A, B, D) 42. (A, C)

The shape of an atomic orbital depends upon Increasing order of wavelength is
Micro waves < Radio waves < IR waves <
azimuthal quantum number
visible waves < UV waves
The orientation of an atomic orbital depends upon The order of Bohr radius is (rn: where n is orbit
the magnetic quantum number number for a given atom ) rn  n2
The energy of an electron in an atomic orbital of r1 < r 2 < r3 < r4
multi-electron atom depends upon principal The order of total energy is (En : where n is orbit
quantum number and azimuthal quantum number number for a given atom) En – 1 n 2
The number of degenerate atomic orbitals of one E1 < E2 < E3 < E4
type depends upon the value of azimuthal The order of velocity of electron in H, He+, Li+,
quantum number Be3+ species in second Bohr orbit is
Be3+ > Li+2 > He+ > H, V Z

37. (A, B, C) 43. (A, B, C)

The number of maxima in any orbital =n – , GS. E.S
(A) 1s2 1s12s1
For 2s orbital, the number of maxima =2 – 0 = 2 (B) [Ne] 3s23p4 [Ne] 3s23P34s1
The number of spherical or radial nodes is equal (C) 1s22s22p6 1s22s2443s2
to n –  – 1  Ne 3s2 3p6 4s3 3d2
(D) 
The number of angular nodes are ‘’ Not possible

3dz2 has 2 angular nodes (= 2) 44. (B, C, D)

nh
Angular momentum =
2π
38. (B, D)
h h
M = +2 is possible for > 2 n=1 =0.5
2π π
39. (B, C, D) 2h h
n=2 =
n > , m = –to + (including Zero), 2π π
4h 2h h
n=4 = =
s = + 1 2or −1 2 2π π 0.5π
45. (B, D)
40. (B, C) Radial distribution function indicates that there is
a higher probability of finding the 3s electron
Cr = [Ar]3d5 4s1 Unpaired electrons = 6 close to the nucleus than for the 3p and 3d orbitals
Mn = [Ar]3d5 4s2 Unpaired electrons = 5 For single electron atom, energy of orbital
depends on “n” values only
Mn2+ = [Ar]3d5 4s 2 Unpaired electrons = 5 At the node, the value of the radial function
Fe2+ [Ar] 3d64s° Unpaired electrons = 4 changes from positive to negative
Radial wave function depends upon the quantum
numbers n & .
41. (A, C)
All electromagnetic radiation travel with speed 46. (A, B, C, D)
of light in vacuum. No. of lines = (5 – 1) + (5 – 2) + (5 – 3) + (5 – 4)
=10
Energy of photon of UV light is higher than that
No. of lines in UV (lyman) = 5 – 1 = 4
of yellow light. No. of lines in Visible (Balmer) = 5 – 2 = 3
He+ and H have similar spectrum. No. of lines in IR (Paschen) = 5 – 3 = 2
The total energy of an electron in unelectronic No. of lines in Brackett = 5 – 4 = 1
species is lesser than zero (–13.6Z2ev/atom) No. of lines in P-fund = 5 – 5 = 0
 14

47. (A, B, C, D) 52. (A-R; B-S; C-Q; D-P)

2 2
n n Fe3+ : [Ar] 3d4,4s0
rn, z  , Un,z  – 2
Z Z Number of unpaired electrons in Fe3+
Z Z2 = 4,
Vn,z  , K n,z  2 P :1s2 2s2 2p63s23p3
n n
1
2 rn, z  n   n  n3
2
Number of electrons with ml = 0 and ms= + in
Tn, z =      2 2
V  Z  z  Z an atom of phosphorus = 5
PE Number of sub-shell in third energy level =3
T.E = KE + PE; = −KE
2 Number of node in 3s = n – 1= 2
U1,2  (22 12 )  53. (A-S; B-R; C-Q; D-P)
= –2  2 2  = −8
K1,1  (1 1 )  Radius of orbit in which electron is moving in 2nd
4
r2,1
=
4 V
= 8 , 1,3 =
(3 1) = 9 orbit of Be+3 ion is = 0.529 Å ×
4
=0. 529 Å
r1,2 1 2 V3,1 (1 3) Total energy of electron in 1st orbit in Li+2 ion
T1,2 (1 2 ) 1
3 2
9
= = = –13.6 × eV
T2,2 ( 23 22 ) 8 1
Velocity of electron in 3nd orbit in H-atom
48. (A, B, C, D)
1
Energy of photon is related with wave number E = hcv = 2.188 ×106 × m/sec
Mathematical expression of Heisenberg 3
h De-broglie wavelength of electron
uncertainty principle is x.p 
4 150 150 22 o 150 o
=  2 A= A
1 1 E(Volt) 13.6 2 13.6
v = 109677  2 − 2  is called as Rydberg formula
 n1 n 2  54. (A-S; B-R; C-Q; D-Q)
de-Broglie relation is  =
h (A) -orbital
p  r = 0,   0 and 3 radial nodes  4s
49. (A) (B) 3 radial nodes (s, p, d)  4s, 5px 6dxy
The photoelectric effect supports quantum nature (C) Angular probability is dependent of  and 
of light because – for 5py, 6dxy
There is a minimum frequency of light below (D) At least one angular node  5px(1); 6dxy(2)
which no photoelectrons are emitted 55. (A–q, s, t) ; (B–p, s, t) ; (C–p, s) ; (D – q, r, t)
50. (A, C) 65 2 2 6 2 6 10 2
30Zn = 1s , 2s , 2p , 3s , 3p , 3d , 4s
Shape of dz2 orbital contains a lobe along z-axis Total number of orbitals with m = 0
and a ring in xy plane. i.e. 1+1+1+1+1+1+1 = 7
2 2 6 2
51. (A-R; B-S; C-P; D-Q) 12Mg = 1s , 2s , 2p , 3s
A : For Lyman series,  for second line (3 → 1) s-orbitals have  = 0. So, number of electrons
 1 1  8R
= R(1)2 =  2 – 2  = (R). =2+2+2=6
1 3  9 35 2 2 6 2
17Cl = 1s , 2s , 2p , 3s , 3p
5

B : For Balmer series,  for second line (4 → 2) Max. no. of electron with  + m = 0 will be :
 1 1  3R
= R(1)2  2 – 2  = (S). For s-orbitals, no. of electrons = 2 + 2 + 2 = 6
 2 4  16 For p-orbitals, max. no. of electrons = 2 + 2 = 4
C : In a sample of H-atom for 5 → 2 transition, So, max. total electrons = 6 + 4 = 10
maximum number of spectral lines observed 20 2 2 6
10Ne = 1s , 2s , 2p
(5 – 2)(5 – 2 +1)
= = 6 (P). 5 electrons will have anticlockwise spin.
2 Number of unpaired electrons in 25Mn2+ ion = 1s2,
D : In a single isolated H-atom for 3 → 1 2s2, 2p6, 3s2, 3p6, 3d5 = 5
transition, maximum number of spectral
Number of fully filled orbitals in 18Ar atom = 1s2,
lines observed = 2 (3 → 2, 2 → 1) (Q).
2s2, 2p6, 3s2, 3p6 = 1 + 1 + 3 + 1 + 3 = 9
 15

56. 58.
(i) (A) (i) (A)
E = E3 − E1 = hc
h h
x = ; xp = = 6 10−34  3 108 1.1  107  (8 9)
4 m 4
(6 − 3)(4)
h h mh =6
; p = ; p = 2
4 m 4 4 (ii) (C)
(ii) (C) Maximum number of different types of photons
(n 2 − n1 )(n 2 − n1 + 1) (6 − 3)(4)
D.B. =
150
A = 5A∣ = = =6
6 2 2
59.
h h h
and x·p  ;p = or p = 2  (i) (D)
4  
Magnetic moment  = n(n + 2)
h h
 x· 2   (A) Fe2+ 3d64s0 n=4
 4 (B) Mn2+ 3d54s0 n=5
1 10−9 1 2.5 (C) Cr3+ 3d3 4s0 n=3
  2       10−10
  4 4 (D) V3+ 3d2 4s0 n=2
(ii) (C)
  0.625A  = n(n + 2) = 3.873
57. n=3
(i) (A) Mn 3d5 4s2
1g-ion of He+ =1 mole of He+ = NA ion 50% ions Mn4+ 3d3 4s0
60.
in 3rd
(I) (C)
= NA × (II) (B)
(ii) (B) (III) (B)
NA  1 1  N
(E)3→1 = (54.4)  – 2  , for A ions 61. (4)
2 1 3 
2
2 By photoelectric effect. h = h0 + KE
4  N0  KE1 = h(1–0)
falling to ground state = 54.4  eV .....(1)
9
KE2 = h(2–0)= KE1/2 ......(2)
N 1 1  N
and (E)3→1 = (54.4) A  1 – 2  , for A Dividing equation (2) by (1) we have
4 1 2  4
2 − 0 1
ions falling to ground state =
1 − 0 2
= 6 × 10–3 × 3 × 108 × 1.1 × 107 × (8/9)
–18
2.0 × 1016 –20 = 1.6×1016–
= 1.76 × 10
Hence, total energy  = 4 × 1015 Hz

4 3 
= 54.4  N0  +  62. (10)
 9 16 
x = 0.1 × 10–9 m.
91 V = 5.27 × 10–27 ms–1.
= 54.4  6.02 1023  eV
144
h
 x × mV =
= 54.4  6.02 1023 
91
1.6 10–19 J 4
144
 0.1 × 10–9 × m × 5.27 × 10–27 = 0.527 × 10–34.
= 3.31106 J  m = 0.1 kg. = 100 gm.
 16

63. (11) 67. (6)

In n = 3 shell x=3–1–1=1
1s (3s) y=0
3p (Px, py, pz)
Cr = 1s2 2s2 2p6 3s2 3p6 4s1 3d5
5d (dxy, dyz, dxz, dx2 − y2 , d z 2 )
( + 1) = 6
* S has no nodal plane.
* Each of Px, py, pz has one nodal plane, which  = 2, d orbital  z=5
means a total of three nodal planes.  x + 2y + z = 1 + 0 + 5 = 6
* d z 2 has no nodal plane and each of dxy, dxz, dyz,

dx2 − y2 has two nodal planes which means a total 68. (3)
of eight nodal planes. 2r = n
Hence n = 3, a total of 11 nodal planes are there. n=3

64. (4) 69. orbital angular momentum of electron

For n  3, orbitals with radial nodes = 1 h h h
= ( + 1)  = ( + 1) = 3
are : 2s, 3px, 3py, and 3pz 2 2 x
 =3
65. (30)
Number of orientations = 2 + 1 = 2 × 3 + 1 = 7
Let x% of e– are in 2nd excited state.
Energy emitted when 1 electron return to ground
state from n = 3 = 12.1 eV. 70. (4)
x [Link] = 1 + (1) (3) = 4 eV
Moles of electron in 2nd excited state = 1
100
x h
Energy emitted = 12.1 96 kJ p =
100 2mp (KE)p
Moles of electron in 1st excited state
30 & KE-particle = 20 – (2) (2) = 16 eV
= 1 = 0.3
100
h
 =
2m (KE)
66. (32)
Maximum possible number of electrons in an
p m (KE) 4 16 4
atom with (n +  = 7) = 7s (2) + 6p (6) + 5d (10)  = = =
 mp (KE)p 1 4 1
+ 4f (14) = 32

For more questions, kindly visit the library section: Link for app: [Link]

For more questions, kindly visit the library section: Link for web: [Link]

PW Mobile APP: [Link]

For PW Website: [Link]
For Rough Work